CAS: 768-49-0; (2-Methylprop-1-En-1-yl)Benzene

该化合物是一种多用途有机化合物,其特点是不饱和的烷结构,有联苯替代物,其高纯度(>85%)确保合成应用的可靠性能,特别是作为有机合成和聚合反应的中间体.该化合物受终极双重结合和甲基组的不孕不育影响驱动,其反应性对生产特殊化学品,包括香气,药品和功能化聚合物很有价值.在标准储存条件下,其稳定性和与普通有机溶剂的兼容性进一步提高其在实验室和工业环境中的效用.这一产品适合于研究人员和制造商,它们要求准确的化学转化具有一贯质量.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号14898-86-3 R-(+)-2-甲基-1-苯基-1-丙醇 | CAS号34857-28-8 (S)-2-甲基-1-苯基丙-1-醇 | CAS号1196-00-5 (-)-异松蒎醇 | CAS号3290-53-7 (2-甲基烯丙基)苯 | CAS号23040-89-3 Aziridine,2,2-d... | CAS号20907-13-5 1,2-Propanediol... | CAS号769-59-5 3-苯基-2-丁酮 | CAS号123-38-6 丙醛 | CAS号67-64-1 丙酮 | CAS号611-70-1 异丁酰苯

合成工艺路线路线简述

  • 合成目标产物 2-Methyl-1-Phenylpropene 主要起始原料 2-Methyl-1-Phenyl-2-Propanol
  • (文献来源)合成步骤主要原料 2-Methyl-1-Phenyl-2-Propanol
异丁酰苯置于3-戊醇,氧化三氯[(二甲硫醚)三苯基膦氧化物]铼(V)体系中,化学反应 40.0H,以65%的收率获得产物2-甲基-1-苯基丙烯
参考文献:使用醇作为氧-Compounds配合物催化的羰基化合物的脱氧剂
标题:使用醇作为氧-Compounds配合物催化的羰基化合物的脱氧剂
摘要:催化体系3-戊醇/ Reocl 3(sme 2)(opph 3)对于羰基化合物的脱氧非常有效.
DOI:10.1039/c5Gc02777B

海关参考信息

专利信息


专利号:US-2012215002-A1
优先权日:2009-10-09
标 题:Synthesis of optically active intermediate for the preparation of montelukast
发明人:LEFORT LAURENT
权利人:LEFORT LAURENT
摘要:The present invention relates to the synthesis of optically active alcohols by means of enantioselective hydrogenation of ketones in biphasic systems. In particular the present invention relates to the synthesis of an optically active alcohol of general formula (1).

专利号:US-11999757-B2
优先权日:2017-11-01
标 题:Synthesis of boronate ester derivatives and uses thereof
发明人:BOYER SERGE HENRI; HECKER SCOTT J; VERZIJL GERARDUS K M; HERMSEN PETRUS J
权利人:MELINTA SUBSIDIARY CORP
摘要:Disclosed herein are methods for the preparation of boronate derivatives in the synthesis of antimicrobial compounds and uses thereof. Disclosed herein includes method of making a compound of Formula (B) by reducing the ketone group of the keto-ester compound of Formula (A), and the reduction can be performed using a Ruthenium based catalyst system or using an alcohol dehydrogenase bioreduction system.

专利号:US-10669292-B2
优先权日:2014-05-05
标 题 :Synthesis of boronate salts and uses thereof
发明人:HECKER SCOTT; BOYER SERGE
权利人:REMPEX PHARMACEUTICALS INC
摘要:Disclosed herein are boronate intermediates in the synthesis of antimicrobial compounds and the use and preparation thereof. Some embodiments relate to crystalline boronate salt derivatives and their use in the synthesis of therapeutic compounds.

专利号:US-9493594-B2
优先权日:2013-05-22
标 题:Cationic polymerization process for the synthesis of nano-structured polymers containing graphene
发明人:GOFFREDI GINO; LONGO ALDO; VALENTINO OLGA; FELISARI RICCARDO; CASALINI ALESSANDRO
权利人:VERSALIS SPA; VERSALIS SPA
摘要:A cationic polymerization process for the synthesis of nano-structured polymers containing graphene which comprises reacting graphite oxide dispersed in a solvent by means of ultrasounds, with at least one vinyl monomer and at least one vinyl aromatic monomer, in the presence of at least one strong inorganic acid and suitable for activating a cationic polymerization, wherein: —said graphite oxide contains from 5% to 60% by weight of bound oxygen, —said vinyl monomer contains at least one carboxylic group wherein the ratio between oxygen bound to the oxide and carboxylic groups ranges from 1:10 to 10:1 in moles per mole, and—the ratio between said vinyl aromatic monomer and the sum of the quantity of graphite oxide and vinyl monomer containing carboxylic groups ranges from 50% to 99% by weight.

专利号:US-8263784-B2
优先权日:2008-10-30
标 题 :Method for the synthesis of a ramipril intermediate
发明人:DE LANGE BEN; HEEMSKERK DENNIS
权利人:DE LANGE BEN; HEEMSKERK DENNIS; DSM SINOCHEM PHARM NL BV
摘要:The present invention relates to a process for the preparation of octahydrocyclopenta[b]pyrrole-2-carboxylic acid and esters thereof of general formula (1) in the presence of a cobalt and/or nickel comprising catalyst and to the use of compounds of general formula (1) in the synthesis of ramipril.

专利号:US-9315483-B2
优先权日:2007-09-13
标题 :Synthesis of deuterated catechols and benzo[D][1,3]dioxoles and derivatives thereof
发明人:JONES ANDREW D; ZELLE ROBERT E; SILVERMAN I ROBERT
权利人:CONCERT PHARMACEUTICALS INC
摘要:The present invention provides a convenient and efficient process for the synthesis of d 2 -benzo[d][1,3]dioxoles.
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合成参考文献


摘要:Takeda, T.; Tsubouchi, A., Science of Synthesis, (2010) 47, 278.
摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 803.
摘要:Hutskalova, V.; Sparr, C., Science of Synthesis Knowledge Updates, (2022) 1, 19.
摘要:Matsumoto, K.; Katsuki, T.; Arends, I. W. C. E., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 108.
摘要:Matsumoto, K.; Katsuki, T.; Arends, I. W. C. E., Science of Synthesis: Stereoselective Synthesis, (2011) 1, 91.
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