CAS: 7643-75-6; (2S,4S)-Pentane-1,2,3,4,5-Pentaol

该化合物是一种被归类为多元醇的糖酒精,一种在水中可溶解的白色晶状固体,在包括食品和制药工业在内的各种应用中有用.L-Arabitol是D-arabitol的立体异构体,来自pentose糖L-arabinese,以其低热量含量闻名,并经常用作低热量和无糖产品的糖替代品.该化合物有甜味,但比sucrose要甜.L-Arabitol还因其潜在的健康惠益而得到承认,包括在促进肠道健康和作为生物前期的作用.此外,它还作为某些微生物的碳源,在生物化学和微生物中具有应用,在各种条件下,它是一种有价值的成分.

结构式图片

相似化合物

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上下游产品

CAS号5328-37-0 L-阿拉伯糖 | CAS号28697-53-2 D-阿拉伯糖 | CAS号38029-69-5 alpha-L-Arabino... | CAS号91-09-8 甲基α-D-吡喃木糖 | CAS号87-72-9 L-阿拉伯糖 | CAS号1949-78-6 L-谷胺酸酯 | CAS号527-50-4 L-木酮糖 | CAS号2042-27-5 L-核酮糖 | CAS号5328-37-0 L-阿拉伯糖 | CAS号6018-27-5 DL-阿拉伯糖醇

合成工艺路线路线简述

    📜Dl-Xylose置于氢气体系中,用 水 作为反应溶剂,99.84 °C,5.41 Mpa 条件下,反应 0.58H,反应生成 Dl-阿拉伯糖醇
    参考文献:生物质衍生的含氧化合物的双金属催化剂的水相加氢和加氢脱氧
    标题:生物质衍生的含氧化合物的双金属催化剂的水相加氢和加氢脱氧
    摘要:在各种氧化铝负载的双金属催化剂(pd-Ni,Pd-Co,Pd-Fe,Ru-Ni,Ru-Co,Ru-Fe,Pt-Ni,Pt-Co和pt-Fe)使用高通量反应器(htr).本文的结果表明,双金属催化剂羰基加氢的活性可以比单金属催化剂高110倍.将铁添加到pd催化剂中可提高丙醛,木糖和糠醛的氢化活性.钯1铁3在htr中测试的所有催化剂中,该催化剂对丙醛的aph的反应速率最高.与单金属pd催化剂相比,向pd催化剂中添加fe将木糖氢化的反应速率提高了51倍.然而,在该研究中测试的双金属催化剂没有比单金属ru催化剂对木糖的氢化具有更高的活性.pd 1 Fe 3催化剂对糠醛aph的反应速率最高,是pd催化剂速率的9倍.钯1铁3/ Zr-p,一种双金属双功能催化剂,在每个站点上的活性是连续流反应器中山梨糖醇水相加氢脱氧(hdo)的pd / Zr-p催化剂的14倍.在pd催化剂中添加铁可提高cc裂解反应的
    DOI:10.1039/c3Gc41071D

    海关参考信息

    专利信息


    专利号:US-8367346-B2
    优先权日:2004-05-19
    标 题:Methods for production of xylitol in microorganisms
    发明人:TAYLOR PAUL; WYMER NATHAN; RACINE FRANCIS MICHAEL
    权利人:BIOTECHNOLOGY RES DEV CORP; US OF AMERICA AS REPRESENTED BY SEC OF AGRICULTURE; TAYLOR PAUL; WYMER NATHAN; RACINE FRANCIS MICHAEL
    摘要:The invention provides biosynthetic routes to xylitol production that do not require pure D -xylose for synthesis and that can utilize inexpensive substrates such as hemicellulose hydrolysates.

    专利号:US-9719098-B2
    优先权日:2011-04-05
    标 题:Methods for the improvement of product yield and production in a microorganism through the addition of alternate electron acceptors
    发明人:ARGYROS AARON; SILLERS WILLIAM RYAN; BARRETT TRISHA; CAIAZZA NICKY; SHAW IV ARTHUR J
    权利人:LALLEMAND HUNGARY LIQUIDITY MAN LLC
    摘要:The present invention provides for novel metabolic pathways to reduce or eliminate glycerol production and increase product formation. More specifically, the invention provides for a recombinant microorganism comprising a deletion of one or more native enzymes that function to produce glycerol and/or regulate glycerol synthesis and one or more native and/or heterologous enzymes that function in one or more engineered metabolic pathways to convert a carbohydrate source, such as lignocellulose, to a product, such as ethanol, wherein the one or more native and/or heterologous enzymes is activated, upregulated, or downregulated. The invention also provides for a recombinant microorganism comprising one or more heterologous enzymes that function to regulate glycerol synthesis and one or more native and/or heterologous enzymes that function in one or more engineered metabolic pathways to convert a carbohydrate source to ethanol, wherein said one or more native and/or heterologous enzymes is activated, upregulated or downregulated.

    专利号:CA-2506422-A1
    优先权日:2002-11-22
    标题 :Enzymatic synthesis of polyol acrylates

    专利号:CN-101128469-B
    优先权日:2005-02-25
    标 题:Synthesis of protease inhibitor precursors

    专利号:EP-1565563-B1
    优先权日:2002-11-22
    标题:Enzymatic synthesis of polyol acrylates
    发明人:PAULUS WOLFGANG; HAUER BERNHARD; HAERING DIETMAR; DIETSCHE FRANK
    权利人:BASF SE

    专利号:US-2006030013-A1
    优先权日:2002-11-22
    标题 :Enzymatic synthesis of polyol acrylates

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Singh RK, Tiwari MK, Singh R, Haw JR, Lee JK. Immobilization of L-arabinitol dehydrogenase on aldehyde-functionalized silicon oxide nanoparticles for L-xylulose production. Appl Microbiol Biotechnol. 2014 Feb;98(3):1095-104. doi: 10.1007/s00253-013-5209-y. Epub 2013 Nov 6. 43(10):5351-4. doi: 10.1128/JCM.43.10.5351-5354.2005.
    3: Seiboth B, Metz B. Fungal arabinan and L-arabinose metabolism. Appl Microbiol Biotechnol. 2011 Mar;89(6):1665-73. doi: 10.1007/s00253-010-3071-8. Epub 2011 Jan 7.
    4: Salonen JH, Rimpiläinen M, Lehtonen L, Lehtonen OP, Nikoskelainen J. Measurement of the D-arabinitol/L-arabinitol ratio in urine of neutropenic patients treated empirically with amphotericin B. Eur J Clin Microbiol Infect Dis. 2001 Mar;20(3):179-84. doi: 10.1007/s100960100472.

    合成参考文献


    参考文献:10.1007/s00253-011-3452-7
    摘要:Sakamoto T, Inui M, Yasui K, Tokuda S, Akiyoshi M, Kobori Y, Nakaniwa T, Tada T. Biochemical characterization and gene expression of two endo-arabinanases from Penicillium chrysogenum 31B. Applied Microbiology and Biotechnology. 2011 Jul 12;93(3):1087–96. doi: 10.1007/s00253-011-3452-7.
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