CAS: 1586-00-1; (2-Benzylphenyl)Methanol

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612-35-1 32832-95-4 5472-13-9

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CAS号612-35-1 2-苄基苯甲酸 | CAS号496-14-0 二氢异苯并呋喃 | CAS号108-86-1 溴苯 | CAS号100-51-6 苯甲醇 | CAS号108-67-8 均三甲苯 | CAS号85-52-9 邻苯甲酰苯甲酸 | CAS号6962-60-3 2-Benzyl benzoi... | CAS号108683-22-3 1-benzyl-2-(met... | CAS号140-11-4 乙酸苄酯 | CAS号104-57-4 甲酸苄酯 | CAS号613-31-0 9,10-二氢蒽 | CAS号612-35-1 2-苄基苯甲酸 | CAS号36374-49-9 2-苄基苯乙酸 | CAS号713-36-0 2-甲基二苯甲烷 | CAS号7510-28-3 2-苯甲基氯苄 | CAS号6196-39-0 1-(2-Benzylphen... | CAS号62551-12-6 2-(2-benzylphen...

📜2-甲基二苯甲酮置于chromium(Vi) Oxide,盐酸,Lithium Aluminium Tetrahydride,硫酸,溶剂黄146,汞,锌体系中,用 乙醚 用作溶剂,化学反应生成2-苄基苯甲醇
参考文献:Chemistry And Stereochemistry Of Benzyl-Benzyl Interactions In Mh+ Ions Of Dibenzyl Esters Upon Chemical Ionization And Collision-Induced Dissociation Conditions
标题:Chemistry And Stereochemistry Of Benzyl-Benzyl Interactions In Mh+ Ions Of Dibenzyl Esters Upon Chemical Ionization And Collision-Induced Dissociation Conditions
摘要:Isobutane Chemical Ionization Mass Spectra Of Dibenzyl Esters Of A Wide Variety Of Aliphatic,Olefinic,Alicyclic And Aromatic Dicarboxylic Acids Exhibit Abundant M/z 181 C14H13+ Ions,Indicating A Highly General Rearrangement Process Involving The Formation Of A New Bond Between The Two Benzyl Groups. An Extensive Collision-Induced Dissociation And Deuterium Labeling Study Suggested That These Ions Are An Almost Equimolar Mixture Of Isomeric Alpha-O-Tolylbenzyl,Alpha-P-Tolylbenzyl And P-Benzylbenzyl Cation Structures,And This Composition Is Identical For All The Diesters Examined This Structural Assignment Of The C14H13+ Ions Suggests A Mechanistic Pathway For Their Generation,Based On The Formation Of The New Bond Between Tbe Benzyl Methylene Group Of The Protonated Benzoxycarbonyl And The Phenyl Ring Of The Otter Ester Moiety Via Pi-(And/or Ion-Neutral) And A-Complexes. Stereoisomeric Diesters Show An Unusual Steric Effect: Trans-Isomers Give Rise To Much More Abundant C14H13+ Ions Than The Cis Counterparts,This Behavior Is Explained By Stabilized Proton-Bridged Structures Of The Mh+ Ions Of The Cis-Isomers. (C) 1997 By John Wiley & Sons,Ltd.
Doi:10.1002/(Sici)1096-9888(199705)32:5<515::Aid-Jms504>3.0.Co;2-B