CAS: 1449-09-8; (2Ar,3R,5As,5Bs,7Ar,9S,11Ar,12As)-2A,5A,8,8-Tetramethyl-3-((R)-6-Methyl-5-Methyleneheptan-2-yl)Tetradecahydro-1H,12H-Cyclopenta[a]Cyclopropa[e]Phenanthren-9-Ol
该化合物是一种三叶虫类化合物,其特点是环球和环环环结构复杂,是各种植物物种中,特别是Asterazae家族中发现的一种自然产生的物质,该化合物因其作为植物细胞膜完整性和功能重要的植物植物植物合成物的一种前体而作用显著,24-甲基环甲醇的分子结构具有多个立体中心特征,有助于其多种生物活动,它具有潜在的药性,包括防炎和抗氧化作用,使其对医药化学和天然产品研究感兴趣.此外,该化合物在基本油和植物提取物中的存在凸显了其在传统医学中的重要性以及食品和化妆业的潜在应用.该化合物的稳定性和再活性可能受到环境因素的影响,其从天然来源的提取和净化是正在进行的研究的课题.
- 英文名称(2Ar,3R,5As,5Bs,7Ar,9S,11Ar,12As)-2A,5A,8,8-Tetramethyl-3-((R)-6-Methyl-5-Methyleneheptan-2-yl)Tetradecahydro-1H,12H-Cyclopenta[a]Cyclopropa[e]Phenanthren-9-Ol
- 中文名称24-亚甲基环阿屯醇
- IUPAC名称(2aR,3R,5aS,5bS,7aR,9S,11aR,12aS)-2a,5a,8,8-tetramethyl-3-((R)-6-methyl-5-methyleneheptan-2-yl)tetradecahydro-1H,12H-cyclopenta[a]cyclopropa[e]phenanthren-9-ol
- 其它别名24-Methylene Cycloartanol; (9β)-24-Methylene-9,19-Cyclolanostan-3β-Ol; 24-Methylene-9β,19-Cyclolanostan-3β-Ol; 24-Methylenecycloartan-3β-Ol; 4,4,14α-Trimethyl-9β,19-Cyclo-5α-Ergost-24(28)-En-3β-Ol; 9,19-Cyclolanostan-3-Ol, 24-Methylene-, (3β)-; 24-Methylenecycloartan-3β-Ol
- CAS编号1449-09-8
- MFCD编号:MFCD20260722
- FDA UNII编号:FI34181G3X
- 分子式:C31H52O分子量:440.76
- 产品CID: 684660
- 产品分类天然产物 → 萜类
物理性质
MSDS等安全信息
上下游产品
cycloeucalenol methanol cyclobranol is°Cyclosadol (23E)-cyclosadol合成工艺路线路线简述
📜24-Methylenecycloartanyl 2'E,4'E-Decadienoate置于potassium Hydroxide体系中,用 乙醇,氯仿 用作溶剂,化学反应 5.0H,反应生成24-亚甲基环阿屯醇
参考文献:一品红的二萜和三萜
标题:一品红的二萜和三萜
摘要:六个新的ent-Abietane内酯(1-6),三个新酯化四环三萜类化合物(7-9),和七个已知二萜类化合物和三萜类化合物是从根部分离大戟婆罗.通过包括1D和2D NMR的光谱研究,质谱分析,化学转化以及与文献数据的比较阐明了它们的结构.
Doi:10.1021/np900127J
海关参考信息
- 2901210000-乙烯
2901220000-丙烯
2905122000-异丙醇
2905141000-异丁醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-3686235-A
优先权日:1969-10-14
标 题:Class of liquid crystals
发明人：NICHOLAS HAROLD J; KNAPP FURN F JR
权利人:HAROLD J NICHOLAS; FURN F KNAPP JR
摘要:THE CHEMICAL SYNTHESIS AND ISOLATION FROM NATURAL SOURCES OF A NEW CLASS OF CHOLESTERIC AND SMECTIC LIQUID CRYSTALS ARE DESCRIBED. THESE CONSIST OF VARIOUS FATTY ACID ESTERS OF TETRACYLIC TRIERTENES INCLUDING MEMBERS OF THE CLASS OF 9,19-CYCLOPROPANE TRITERPENES. THESE TRITERPENES INCLUDE 9,19-CYCLOLANOST-24-EN-3B-OL(CYCLOARTENOL), 4A,14A,24B-TRIMETHYL-9,19-CYCLOCHOLESTAN-3B-OL, 24E-METHYL-9,19-CYCLOLANOSTAN-3B-OL(24E-METHYL CYCLOARTANOL) AND 24-DIHYDRO LANOSTEROL AND ALL CHEMICALLY RELATED PRODUCTS.
专利号:EP-2886657-A1
优先权日:2013-12-19
标题 :Enzymatic synthesis of phenolic acid esters and steryl phenolates
发明人：NYSTRÖM LAURA; SCHÄR ALINE
权利人:ETH ZUERICH
摘要:The present invention relates to a method for obtaining at least one steryl phenolate from at least one phenolic acid in an enzymatic process using a lipase, wherein in a first step a) the at least one phenolic acid and at least one alcohol R 1 -OH undergo an enzymatic esterification to at least one phenolic acid ester according to reaction scheme (III)n n, and in at least one second step b) the at least one phenolic acid ester and at least one sterol R 2 -OH undergo an enzymatic transesterification using a lipase to at least one steryl phenolate according to reaction scheme (IV)
专利号:ES-2402484-B1
优先权日:2011-10-21
标题 :PROCEDURE TO INCREASE THE SYNTHESIS AND ACCUMULATION OF NATURAL HYDROCARBONS DERIVED FROM THE TERPENOID METABOLISM IN THE EUPHORBIA LATHYRIS PLANT
专利号:WO-2013057356-A1
优先权日:2011-10-21
标题 :Method for increasing the synthesis and accumulation of natural hydrocarbons derived from terpenoid metabolism in the euphorbia lathyris plant
专利号:ES-2402484-A1
优先权日:2011-10-21
标 题:Method for increasing the synthesis and accumulation of natural hydrocarbons derived from terpenoid metabolism in the euphorbia lathyris plant
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
参考文献:10.1007/bf02637687
摘要:Akihisa T, Kawashima T, Takahashi S, Sahashi N, Okamoto T, Niiya I, Tamura T. Sterols and fatty acids of a whisk fernPsilotum nudum. J Americ Oil Chem Soc. 1992 Dec;69(12):1232–5. doi: 10.1007/bf02637687.
参考文献:10.1016/0031-9422(86)88046-3
摘要:Menounos P, Staphylakis K, Gegiou D. The sterols of Nigella sativa seed oil. Phytochemistry. 1986 Jan;25(3):761–3. doi: 10.1016/0031-9422(86)88046-3.
参考文献:10.1248/cpb.44.1255
摘要:AKIHISA T, OINUMA H, YASUKAWA K, KASAHARA Y, KIMURA Y, TAKASE S, YAMANOUCHI S, TAKIDO M, KUMAKI K, TAMURA T. Helianol(3,4-seco-19(10.RAR.9)abeo-8.ALPHA.,9.BETA.,10.ALPHA.-eupha-4,24-dien-3-ol), a Novel Triterpene Alcohol from the Tabular Flowers of Helianthus annuus L. Chem. Pharm. Bull. 1996;44(6):1255–7. doi: 10.1248/cpb.44.1255.
参考文献:10.1248/yakushi1947.105.8_742
摘要:KONDO Y, SUZUKI H, NOZOE S. Two γ-Hydroxybutenolides from the Bark of Phellodendron amurense and Photooxidation of Limonoids. YAKUGAKU ZASSHI. 1985;105(8):742–6. doi: 10.1248/yakushi1947.105.8_742.
参考文献:10.1016/s0031-9422(00)90672-1
摘要:Ulubelen A, Topcu G, Sönmez U, Eris C. Terpenoids from Salvia nemorosa. Phytochemistry. 1994 Mar;35(4):1065–7. doi: 10.1016/s0031-9422(00)90672-1.
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