CAS: 120162-55-2; Azimsulfuron

该化合物是一种选择性除草剂,主要用于控制各种作物,特别是稻米和其他谷物作物的宽叶草和某些草,它属于磺酰胺类除草剂,其作用是抑制对植物中基本氨基酸合成至关重要的酶乙酰醚合成,这种抑制导致目标杂草停止生长并最终死亡.亚齐松硫磷的特点是其低施药率高,使其与某些传统除草剂相比,具有环境上有利的选择.它一般是使用先发性或后发性杀草剂,取决于具体的杂草种和作物类型.该化合物一般在正常的环境条件下稳定,但可以在强酸或碱存在的情况下降解.其水和有机溶剂的溶解性允许各种配制类型,包括颗粒和液体浓缩.同许多除草剂一样,适当的处理和应用对于最大限度地减少潜在的环境影响和确保安全至关重要.

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104040-78-0 208465-21-8 98389-04-9

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[欧盟农药活性物质

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O-phenyl N-(4,6-dimethoxypyrimidin-2-yl)carbamate 5-amino-4-cyano-1-methylpyrazole 5-chloro-1-methyl-1H-pyrazole-4-carbonitrile 5-bromo-1-methyl-1H-pyrazole-4-carbonitrile

合成工艺路线路线简述

    📜5-氨基-1-甲基-吡唑-4-甲腈置于sodium Azide,三丁基氯化锡,氨,氢溴酸,氯,Sodium Hydride,溶剂黄146,三乙胺,Potassium Hydroxide,Copper(I) Bromide,Sodium Nitrite体系中,用 水,1,2-二氯乙烷,N,N-二甲基甲酰胺,甲苯,乙腈,Mineral Oil 用作溶剂,化学反应 2.0H,反应生成四唑嘧磺隆
    参考文献: Process Of Preparation Of Azimsulfuron[fr] Procédé De Préparation D'Azimsulfuron
    标题: Process Of Preparation Of Azimsulfuron[fr] Procédé De Préparation D'Azimsulfuron
    摘要:本公开提供了制备阿吉磺隆或其盐,异构体和其他衍生物的方法.该方法涉及使用具有化学式i的化合物(应在此处插入化学式i)与水杨酸或甲酸和氯气或次氯酸钠在氯化溶剂(如二氯甲烷,1,2-二氯乙烷)中,在氯化溶剂中的氯化氢的存在下处理,或者与水杨酸和n-氯琥珀酰亚胺或过氧化氢在环氧乙醚(如四氢呋喃,1,4-二噁烷)中的氯化氢的存在下处理,以获得1-甲基-4-(2-甲基-2H-四唑-5-基)-1H-吡唑-5-磺酰氯;将磺酰氯转化为磺酰胺,并将磺酰胺与苯基(4,6-二甲氧基嘧啶-2-基)氨基甲酸酯处理,以获得阿吉磺隆或其盐,异构体和其他衍生物.

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    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:WO-2021130756-A1
    优先权日:2019-12-25
    标题:Combinations of non-protein amino acids and acetolactate synthase enzyme inhibitors
    发明人:KLIPCAN LIRON; VAN-OSS PINHASI RUTH
    权利人:THE STATE OF ISRAEL MINISTRY OF AGRICULTURE & RURAL DEVELOPMENT AGRICULTURAL RES ORGANIZATION ARO VO
    摘要:The present invention provides compositions and methods for disrupting protein synthesis in plant cells.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

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    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Valle A, Boschin G, Negri M, Abbruscato P, Sorlini C, D'Agostina A, Zanardini E. The microbial degradation of azimsulfuron and its effect on the soil bacterial community. J Appl Microbiol. 2006 Aug;101(2):443-52. doi: 10.1016/j.scitotenv.2016.01.142. Epub 2016 Feb 2. eCollection 2016 Oct 1.
    4: Pusino A, Pinna MV, Gessa C. Azimsulfuron sorption--desorption on soil. J Agric Food Chem. 2004 Jun 2;52(11):3462-6. Epub 2007 Jul 6. doi: 10.1107/S2056989015010968. eCollection 2015 Jul 1.
    7: Singh V, Jat ML, Ganie ZA, Chauhan BS, Gupta RK. Herbicide options for effective weed management in dry direct-seeded rice under scented rice-wheat rotation of western Indo-Gangetic Plains. Crop Prot. 2016 Mar;81:168-176.

    合成参考文献


    摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198
    摘要:Ruiz-Santaella JP, Fisher AJ, De Prado R. Alternative control of two biotypes of Echinochloa phyllopogon susceptible and resistant to fenoxaprop-ethyl. Commun Agric Appl Biol Sci. 2003;68(4 Pt A):403–7.
    参考文献:10.1021/jf049971e
    摘要:Pusino A, Pinna MV, Gessa C. Azimsulfuron sorption--desorption on soil. J Agric Food Chem. 2004 Jun 02;52(11):3462–6. doi: 10.1021/jf049971e.
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