CAS: 1188-14-3; Triethylgermanium Hydride

该化合物是一种有机金属化合物,其特点是-氢的结合,在合成和材料化学中具有活性作用,其主要优点包括其在有机和有机金属反应中作为减少剂的作用,在有机和有机金属反应中,它有选择地将氢化物转移至电子药中心;该化合物在受控条件下的稳定性及其与各种子质的兼容性,使得它对于在聚合物,半导体和催化系统中精确地结合钛很有价值;三乙基环己酸也作为含有的薄膜沉积的前体,利用其挥发性来进行化学蒸气沉积(CVD)过程;建议由于对湿气和空气的敏感性,在惰性大气中进行适当的处理.

结构式图片

相似化合物

1067-10-3

欧盟法规

ECHA物质C&L通报

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CAS号16853-85-3 氢化铝锂 | CAS号994-28-5 三乙基氯化锗 | CAS号112712-64-8 三(1,2-苯二醇基-O,O')锗酸二钾 | CAS号925-90-6 乙基溴化镁 | CAS号112712-66-0 potassium tris(... | CAS号993-62-4 六乙基二金属锰(IV) | CAS号6727-87-3 lithium,triethy... | CAS号127-19-5 N,N-二甲基乙酰胺(DMAC) | CAS号10177-53-4 chloro(diethyl)... | CAS号74-96-4 溴乙烷 | CAS号1112-60-3 Acetic acid,tri... | CAS号144650-44-2 ethyl 2-triethy... | CAS号144650-43-1 ethyl (E)-3-tri... | CAS号18478-23-4 triethyl-[(2-me... | CAS号26452-74-4 tert-butylperox... | CAS号994-28-5 三乙基氯化锗 | CAS号2538-70-7 Digermoxane,1,1... | CAS号7440-56-4 锗粉 | CAS号1631-46-5 diethylgermane | CAS号464-72-2 苯频哪醇

合成工艺路线路线简述

    📜Alkaline Earth Salt Of/the/ Methylsulfuric Acid置于lithium,乙胺体系中,化学反应生成三乙基氢化锗
    参考文献:Kraus; Flood,Journal Of The American Chemical Society,1932,Vol. 54,P. 1642,1643
    标题:Kraus; Flood,Journal Of The American Chemical Society,1932,Vol. 54,P. 1642,1643

    海关参考信息

    专利信息


    专利号:US-7307177-B2
    优先权日:2004-12-17
    标题:Metallocene complexes, their synthesis and use in catalyst systems for olefin polymerization
    发明人:HUANG LEGAL REPRESENTATIVE JIL; CANICH JO ANN M; COKER CATALINA L
    权利人:EXXONMOBIL CHEM PATENTS INC
    摘要:A metallocene complex is represented by the the formulan n(C p R 5 ) n MX k n nwhere C p (each occurrence) is a cyclopentadienyl group; each of the five R substituents on the or each cyclopentadienyl group is independently selected from hydrogen, C 1 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure, and SiR′ 2 NR″ 2 where each of the two R′ substituents is independently selected from hydrogen, C 1 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R′ substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure, and each of the two R″ substituents is independently selected from C 2 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R″ substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure; n is 1 or 2; M is a metal of valence m from Groups 4 to 11 of the Periodic Table of Elements, k is equal to m minus n and the or each X substituent is a univalent anionic ligand, or two X substituents are joined and bound to the metal atom to form a metallocycle ring, or two X substituents are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand, provided that at least one R substituent on the or one cyclopentadienyl group is SiR′ 2 NR″ 2 , provided that at least one R substituent on at least one C p is SiR′ 2 NR″ 2 and provided that one or the C p may be bridged by a bridging group to another C p group, or a heteroatom containing group, where the bridging group replaces one R group on the C p group(s) or a hydrogen on a heteratom containing group.

    专利号:FR-2740451-A1
    优先权日:1995-10-27
    标题:NEW INTERMEDIARIES FOR THE HEMISYNTHESIS OF TAXANES, THEIR METHODS OF PREPARATION AND THEIR USE IN THE GENERAL SYNTHESIS OF TAXANES

    专利号:CN-1200731-A
    优先权日:1995-10-27
    标题 :Intermediate for semi-synthesis of taxane and preparation method thereof

    专利号:CN-100374428-C
    优先权日:1995-10-27
    标题:Intermediate for semi-synthesis of taxane and preparation method thereof

    专利号:EP-0134324-B1
    优先权日:1983-08-15
    标 题 :Production of ethanol from methanol and synthesis gas

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Spivey, A. C.; Tseng, C.-C., Science of Synthesis Knowledge Updates, (2010) 1, 50.
    摘要:Hlina, J. A., Science of Synthesis Knowledge Updates, (2021) 1, 85.
    摘要:Spivey, A. C.; Tseng, C.-C., Science of Synthesis Knowledge Updates, (2010) 1, 1.
    摘要:Hou, X.-L.; Peng, X.-S.; Yeung, K.-S.; Wong, H. N. C., Science of Synthesis Knowledge Updates, (2011) 2, 295.
    摘要:Marschner, C., Science of Synthesis Knowledge Updates, (2020) 3, 118.
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