CAS: 50594-66-6; Acifluorfen

该化合物是一种选择性除草剂,主要用于控制各种作物中的宽叶草和某些草,属于二苯醚的化合物类别,其特点是能够抑制对叶绿素生物合成至关重要的酶丙烯丙烯丙烯酯氧化酶,这种抑制作用导致有毒的porphin化合物的累积,导致植物死亡.Acifluorfen通常在出现后施用,在大豆和花生等作物中有效.该物质在室温下无色可粉黄黄色固态,在水中可溶性中等,有机溶解剂中溶性较高,其稳定性受环境因素影响,而且一般认为对哺乳动物的毒性较低,尽管可能对水生生物有害.适当的处理和应用对于尽量减少环境影响和确保安全至关重要.

结构式图片

欧盟法规

《欧盟PIC法规》统一分类与标签"欧盟管控危险化学品"ECHA物质工作场所安全标识要求ECHA物质OtherC&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号63734-62-3 3-[2-氯-4-(三氟甲基)... | CAS号50594-67-7 三氟羧草醚甲酯 | CAS号107-06-2 1,2-二氯乙烷 | CAS号19750-95-9 克死螨 | CAS号100-02-7 对硝基苯酚 | CAS号42874-01-1 nitrofluorfen | CAS号35852-58-5 3-氯-4-羟基三氟甲苯 | CAS号610-37-7 5-羟基-2-硝基苯甲酸 | CAS号50594-67-7 三氟羧草醚甲酯 | CAS号19750-95-9 克死螨 | CAS号98-88-4 苯甲酰氯 | CAS号67446-83-7 5-[2-chloro-4-(... | CAS号72178-02-0 氟磺胺草醚 | CAS号77501-90-7 乙羧氟草醚

合成工艺路线路线简述

  • 63734-62-3 = 50594-66-6 + 95899-73-3
    反应条件:1.1 Reagents: Acetic Anhydride Solvents: 1,2-Dichloroethane; Rt -> 50 °C; 50 °C -> 15 °C1.2 Reagents: Sulfuric Acid,Nitric Acid; 2 H,10 - 15 °C; 1 H,10 °C1.3 Solvents: Water
    标题:Purification Of Diphenyl Ether Herbicides
    参考文献:United States]

    63734-62-3 = 50594-66-6 + 95899-73-3 + 1052723-90-6
    反应条件:1.1 Reagents: Sulfuric Acid Solvents: Propionic Acid,Propionic Anhydride; 20 °C; 20 °C -> 36 °C; 36 °C -> 1 °C1.2 Reagents: Nitric Acid; 1 H,1 °C; 1 H,10 °C1.3 Solvents: Water
    标题:Procedure For Aromatic Nitration In Propionic Acid
    参考文献:World Intellectual Property Organization
3-[2-氯-4-(三氟甲基)苯氧基]苯甲酸置于硫酸,硝酸,乙酸酐体系中,用 二氯甲烷,水 作为反应溶剂,化学反应生成 三氟羧草醚
参考文献:Process For Preparing Phenoxybenzoic Acids
标题:Process For Preparing Phenoxybenzoic Acids
摘要:公式为##str1##的苯氧基苯甲酸和酯可以通过将3-羟基苯甲酸的二盐与3-氯-4-卤苯三氟化物反应而制备,其中r为氢或烷基,X为氢或氯.然后可以有选择性地硝化这些苯氧基苯甲酸和酯,得到相应的2-硝基-5-(取代基)苯氧基苯甲酸和酯.也可以先对相应的酸进行硝化,然后与适当的醇酯化来制备硝化酯.

海关参考信息

专利信息


专利号:WO-2024256370-A1
优先权日:2023-06-13
标 题 :Synthesis of glufosinate using an amidase-based process
发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

专利号:US-2025120400-A1
优先权日:2021-12-10
标题:Synthesis of glufosinate using a hydantoinase-based process
发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
权利人:BASF SE
摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

专利号:US-11919928-B2
优先权日:2016-03-16
标题 :Method for producing dihydrotentoxin
发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
权利人:KUMIAI CHEMICAL INDUSTRY CO
摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

专利号:US-2021386068-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

专利号:US-2021352899-A1
优先权日:2018-11-07
标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
发明人:KISTER JEREMY; SATCHIVI NORBERT M
权利人:CORTEVA AGRISCIENCE LLC
摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

专利号:ES-2717283-T3
优先权日:2012-07-24
标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids
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合成参考文献


参考文献:10.1021/es7024356
摘要:Shirzadi A, Simpson MJ, Xu Y, Simpson AJ. Application of saturation transfer double difference NMR to elucidate the mechanistic interactions of pesticides with humic acid. Environ Sci Technol. 2008 Feb 15;42(4):1084–90. doi: 10.1021/es7024356.
参考文献:10.1007/s11103-006-9024-z
摘要:Zhang H, Li J, Yoo JH, Yoo SC, Cho SH, Koh HJ, Seo HS, Paek NC. Rice Chlorina-1 and Chlorina-9 encode ChlD and ChlI subunits of Mg-chelatase, a key enzyme for chlorophyll synthesis and chloroplast development. Plant Mol Biol. 2006 Oct;62(3):325–37. doi: 10.1007/s11103-006-9024-z.
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