CAS: 47250-53-3; 3,3'-(Perfluoropropane-2,2-Diyl)Dianiline

该化合物是一种特殊的芳香性芳烃化合物,在两个氨基苯组之间有一个三氟甲基替代乙基联系器,其独特的结构包括多个氟原子,增强了其电子提取特性和化学稳定性,使其在先进的合成应用中具有价值; 存在双氨基功能组,使得多聚胺,聚氨基或环氧树脂合成中具有多功能性再活性,有助于高性能材料的热抗和化学抗药性,该化合物在制药,农用化学品和特殊聚合物中特别有用,其氟基质能够产生可取性,如增加脂性性和代谢稳定性.

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2,2-双(3-硝基苯基)六氟丙烷 2,2-Bis-(3-Nitrophenyl)-Hexafluoropropane 64465-34-5

合成工艺路线路线简述

    📜2,2-双(3-硝基苯基)六氟丙烷 反应生成 2,2-双(3-氨基苯基)六氟丙烷
    参考文献:Giants,Thomas W.;Dougherty,Thomas K.
    标题:Giants,Thomas W.;Dougherty,Thomas K.

    海关参考信息

    专利信息


    专利号:US-7615300-B2
    优先权日:2005-08-30
    标 题 :Development of novel proton-conductive polymers for proton exchange membrane fuel cell (PEMFC) technology
    发明人:BAE CHULSUNG
    权利人:REGENTS UNIVERSITY AND COMMUNI
    摘要:New thermally and chemically stable sulfonic acid-containing polymers are synthesized via post-sulfonation of aromatic polymers. These new polymers provide unique benefits to proton exchange membrane fuel cell technology (“PEMFCâ€?). As a sulfonic acid moiety can be easily installed into an aromatic ring via electrophilic sulfonation, even in the presence of an electron-withdrawing substituent such as —F, rigid polymers consisting of aromatic rings at either the side chain or main chain can be prepared with a wide range of substituents and flexibility in properties. Novel synthetic procedures are provided for synthesis of the polymers.

    专利号:US-9562141-B2
    优先权日:2013-05-23
    标题 :Method of aerogel synthesis
    发明人:RODMAN DAVID L; POE GARRETT D; FARMER BRANDON S; SMITH JOSEPH C
    权利人:NEXOLVE CORP; NEXOLVED CORP
    摘要:The present disclosure provides a method for producing an aerogel, the method comprising reacting at least one acid monomer with at least one diamino monomer in a first solvent under conditions appropriate to form a polyimide polymer; conducting a solvent exchange wherein the first solvent is exchanged for a second solvent, said second solvent having a freezing point, wherein said solvent exchange further comprises (1) submersing the polyimide polymer in the second solvent in a pressure vessel and (2) creating a high pressure environment inside the pressure vessel for a first period of time; cooling the polyimide polymer to a first temperature below the freezing point of the second solvent; and subjecting cooled polyimide polymer to a first vacuum for a second period of time at a second temperature.

    专利号:US-9963578-B2
    优先权日:2013-07-17
    标题 :Black polyimides and synthesis thereof
    发明人:FARMER BRANDON S; POE GARRETT D; RODMAN DAVID L; BRADBURN JR LONNIE F
    权利人:NEXOLVE CORP
    摘要:Black polyimides polymer and a method of synthesizing the same have been developed. The black polyimide polymer includes at least one acid monomer, at least one diamino monomer and a solvent-soluble black dye. The acid and diamino monomers having been reacting in a solvent under suitable conditions to form a polyimide precursor polymer.

    专利号:US-4503254-A
    优先权日:1982-03-24
    标 题:Process for making bis(halophenyl)hexafluoropropanes
    发明人:KELLEGHAN WILLIAM J
    权利人:HUGHES AIRCRAFT CO
    摘要:A new process for preparing diphenyl derivatives of hexafluoropropane containing halogen substituents on the phenyl rings and new halogen-substituted diphenyl derivatives of hexafluoropropane prepared thereby are disclosed. The new compounds of this invention are useful as intermediates for the synthesis of high temperature polymer systems.

    专利号:GB-2137984-A
    优先权日:1983-02-14
    标题:Synthesis of Bis(ethynylphenyl) Compounds

    专利号:EP-2999736-A1
    优先权日:2013-05-23
    标题 :Method of aerogel synthesis

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    合成参考文献


    参考文献:10.1557/proc-214-131
    摘要:Stoakleya DM, St. Clair AK. Insoluble, Low Dielectric Polyimides. MRS Advances. 1990;214():131. doi: 10.1557/proc-214-131.
    参考文献:10.1007/0-306-46919-7_15
    摘要:Matsuura T, Ando S, Sasaki S. Synthesis and Properties of Partially Fluorinated Polyimides for Optical Applications. 2002. In: Fluoropolymers 2. : Kluwer Academic Publishers; 2002.
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