专利号:US-9273410-B2 优先权日:2009-01-16 标 题 :Low-temperature synthesis of colloidal nanocrystals 发明人:BARTL MICHAEL H; SIY JACQUELINE T 权利人:BARTL MICHAEL H; SIY JACQUELINE T; UNIV UTAH RES FOUND 摘要:Low-temperature organometallic nucleation and crystallization-based synthesis methods for the fabrication of semiconductor and metal colloidal nanocrystals with narrow size distributions and tunable, size- and shape-dependent electronic and optical properties. Methods include (1) forming a reaction mixture in a reaction vessel under an inert atmosphere that includes at least one solvent, a cationic precursor, an anionic precursor, and at least a first surface stabilizing ligand while stirring at a temperature in a range from about 50° C. to about 130° C. and (2) growing nanocrystals in the reaction mixture for a period of time while maintaining the temperature, the stirring, and the inert-gas atmosphere.
专利号:US-4341706-A 优先权日:1980-10-10 标题 :Process for the preparation of carbapenem antibiotics 发明人:CHRISTENSEN BURTON G; SHIH DAVID H 权利人:MERCK & CO INC 摘要:Disclosed is a process for the synthesis of carbapenem antibiotics I and their pharmaceutically acceptable salts and esters from 1: wherein: R7, R6, R1, R2 and R8 are selected from hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, spirocycloalkyl, cycloalkylalkyl, alkylcycloalkyl, aryl, aralkyl, aralkenyl, aralkynyl, heteroalkyl, heteroaralkyl, heterocyclyl and heterocyclyalkyl.
专利号:US-4460507-A 优先权日:1980-10-10 标题:Process for the preparation of thienamycin 发明人:SHIH DAVID H 权利人:MERCK & CO INC 摘要:Disclosed is a process for the total synthesis of thienamycin from descysteaminylthienamycin 1 ##STR1## via thienamycin sulfoxide 4: ##STR2## R 3 , R°, R' are blocking groups.
专利号:US-4451680-A 优先权日:1982-10-21 标题:Alcohols prepared from olefins and synthesis gas 发明人:KNIFTON JOHN F 权利人:TEXACO INC 摘要:This invention concerns a process of preparing predominantly linear alcohols which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound coupled with one or more bidentate or multidentate, phosphine-containing promoters, dispersed in a low melting quaternary phosphonium salt, and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols.
专利号:US-2006030723-A1 优先权日:2001-09-28 标 题:Process for synthesis of organometallic compounds
专利号:US-2018320286-A1 优先权日:2009-01-16 标 题:Low-temperature synthesis of colloidal nanocrystals