CAS: 112-29-8; 1-Bromodecane

相似化合物

112-71-0 112-82-3 112-89-0

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癸烷置于四溴化碳体系中,化学反应 3.0H,反应生成癸基溴
参考文献:Aliphatic Bromination With Tetrabromomethane On Immobilized Copper Complexes
标题:Aliphatic Bromination With Tetrabromomethane On Immobilized Copper Complexes
摘要:New Catalytic Systems With Supported Bromine-And Chlorine-Containing Copper Complexes For Selective Bromination Of Alkanes With Tetrabromomethane Have Been Proposed. Introduction Of Donor Additives (E.G.,Low-Molecular-Weight Alcohols) Into The Reaction Increases The Activity And Stability Of These Catalysts. The Kinetic Features Of The Processes Have Been Investigated. It Has Been Shown That The Dependences Of The Yield Of Bromodecanes On Temperature And Concentration Of Donor Additives Are Both Nonmonotonic In Character. (C) 2015 Elsevier B.V. All Rights Reserved.
Doi:10.1016/j.Molcata.2015.06.022

专利信息

专利号:US-6962963-B2
优先权日:2002-10-18
标题 :Enzymatic synthesis of polymers
发明人：KUMAR RAJESH; WATTERSON ARTHUR C; PARMAR VIRINDER SINGH; KUMAR JAYANT; SAMUELSON LYNNE ANN
权利人:UNIV MASSACHUSETTS
摘要:The invention relates to new methods of enzymatic synthesis of polymers such as polyorganosilicones and polyesters, and new polymers made by these methods.

专利号:US-8192590-B1
优先权日:2008-04-14
标 题:Microwave-assisted formation of sulfonium photoacid generators
发明人：BELFIELD KEVIN D; YANEZ CICERON O
权利人:BELFIELD KEVIN D; YANEZ CICERON O; UNIV CENTRAL FLORIDA RES FOUND
摘要:Efficient method for preparing sulfonium photoacid generators (PAGs) by microwave-assisted reaction of diarylsufides in the presence of alkylaryliodonium salts. Microwave-assisted synthesis of the PAGs is significantly faster, reducing reaction time with less energy consumption. Reaction times using the microwave-assisted synthesis are in a range of from 90 to 420 faster than conventional thermal conditions. The photoacid quantum yields of several salts prepared by the microwave reaction were measured; the photoacid quantum yields of new sulfonium PAGs were in a range from 0.01 to 0.4 times greater than yields from conventional synthesis. Incorporating a nitro group in the structures of the sulfonium salts increased photoacid quantum yield, induced intersystem crossing and increased the efficiency of photoacid generation compounds.

专利号:EP-0468457-B1
优先权日:1990-07-24
标题 :Novel substituted piperidines and their use as inhibitors of cholesterol synthesis
发明人：MCCARTHY JAMES R; BARNEY CHARLOTTE L; WANNAMAKER MARION W
权利人:MERRELL DOW PHARMA
摘要:The present invention relates to a group of compounds which are novel substituted piperidines and which act to inhibit the synthesis of cholesterol in mammals and in fungi.

专利号:US-6469193-B1
优先权日:1999-02-26
标 题 :Efficient synthesis of alkyl carbonates
发明人：JUNG KYUNG WOON
权利人:UNIV SOUTH FLORIDA
摘要:Efficient synthetic methods towards mixed aliphatic carbonates through the three component couplings of aliphatic alcohols, alkyl halides and carbon dioxide in the presence of cesium carbonate and tetrabutylammonium iode (TBAI). Due to their enhanced nucleophilicities, cesium alkoxides are smoothly incorporated into CO 2 , allowing for mild reaction conditions such as ambient temperatures and short reaction durations. Various primary and secondary substrates are compatible under the standard conditions, offering high yields, while chiral templates such as α-hydroxy carbonyls are resistant to racemization.

专利号:WO-2009126118-A1
优先权日:2008-04-10
标题:Unique processable green polymer with a transmissive oxidized state for realization of commerical rgb based electrochromic device applications
发明人：TOPPARE LEVENT KAMIL; GUNBAS GORKEM EMRULLAH; DURMUS ASUMAN
权利人:TOPPARE LEVENT KAMIL; GUNBAS GORKEM EMRULLAH; DURMUS ASUMAN
摘要:In the present invention a method for synthesis of neutral state green polymer PDOPEQ) is developed. The method developed in this invention is characterized by; a) obtaining 2,3-bis(3,4-bis(decyloxy)phenyl)-5,8-dibromoquinoxaline, b) b) obtaining tributyl (2,3-dihydrothieno[3,4-b][l,4]dioxin-5-yl)stannane c) c) Using coupling to attach donor EDOT moieties to the acceptor quinoxaline unit to give the title compound (DOPEQ) in satisfactory yields; d) obtaining neutral state green polymer (PDOPEQ) by using either electrochemical or chemical methods. The polymers synthesized up to date mainly absorb/reflect blue and red colors in the reduced state. Conversely, to obtain a green colored polymer in the reduced state, one should have two absorption bands centered at the blue and red regions of the visible spectrum and moreover, these absorption bands should be manipulated in the same manner at applied potentials.

专利号:US-8975427-B2
优先权日:2010-04-28
标题 :Synthesis of alkyl cyclopentadiene compounds
发明人：HARLAN C JEFF; CAO XIANYI; RIX FRANCIS C
权利人:HARLAN C JEFF; CAO XIANYI; RIX FRANCIS C; UNIVATION TECH LLC
摘要:A method of synthesizing an alkyl cyclopentadiene compound is disclosed. The method includes contacting at least one cyclopentadienyl anion source and at least one alkyl group source to form at least one alkyl cyclopentadiene compound. The method further includes extracting the alkyl cyclopentadiene compound with a hydrocarbon solvent. The alkyl cyclopentadiene compound may be converted to a metallocene catalyst compound.