CAS: 76578-12-6; Ethyl 2-(4-((6-Chloroquinoxalin-2-yl)Oxy)Phenoxy)Propanoate

该化合物是一种属于丙氧基苯氧丙胺(FOP)类的选择性的抗除草剂,主要用于控制包括大豆,棉花和甜菜在内的宽叶麻作物中每年和常年的草杂草.Quizalofop通过抑制乙酰-CoA carboxylase(ACCase)的行为,干扰易感草的脂肪酸合成,导致生长抑制和最终植物死亡.其主要优势包括:对多种草草的高效性,低施用率和按原样使用的有利作物安全性.除草剂可以存在于各种配方中,如乳油,以提高稳定性和易应用性.建议适当的抗药性管理以保持长期有效性.

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上下游产品

methyl 2-[4-(6-chloro-2-quinoxalinyloxy)phenoxy]propionate quizalofop ethyl 2,6-dichloroquinoxaline (RS)-2-(4-hydroxyphenoxy)propionic acidD-2-[p-[(6-chloro-2-quinoxalinyl)oxy]phenoxy]propionic acid chloride quizalofop-p-tefuryl quizalofop ethyl

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    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:ES-2717283-T3
    优先权日:2012-07-24
    标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids

    专利号:TW-I655905-B
    优先权日:2012-07-24
    标题 :Contains 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or a derivative thereof and very long chain fatty acid (VLCFA) Synthesis of herbicidal compositions with fatty acid/fat synthesis inhibiting herbicides

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    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: López-Ruiz R, Romero-González R, Martínez Vidal JL, Garrido Frenich A. Behavior of quizalofop-p and its commercial products in water by liquid chromatography coupled to high resolution mass spectrometry. Ecotoxicol Environ Saf. 2018 Aug 15;157:285-291. doi: 10.1016/j.ecoenv.2018.03.094. Epub 2018 Apr 5. doi: 10.1007/s00449-018-1896-1. Epub 2018 Jan 19. doi: 10.1002/ps.4711. Epub 2017 Oct 6. doi: 10.1002/ps.4675. Epub 2017 Sep 11. doi: 10.1002/ps.4673. Epub 2017 Aug 29. doi: 10.1016/j.scitotenv.2017.06.261. Epub 2017 Jul 27. doi: 10.1186/s12934-017-0695-8.
    8: Lubomirsky E, Padró JM, Di Loreto H, Castells CB. Chiral separation of aryloxyphenoxy-propionate herbicides in a permethyl-β-cyclodextrin based column. Influence of temperature and mobile phase composition on enantioselectivity. Electrophoresis. 2017 Aug;38(15):1948-1955. doi: 10.1002/elps.201600528. Epub 2017 May 11. doi: 10.1038/srep46494.
    10: Chawla S, Patel HK, Gor HN, Vaghela KM, Solanki PP, Shah PG. Evaluation of Matrix Effects in Multiresidue Analysis of Pesticide Residues in Vegetables and Spices by LC-MS/MS. J AOAC Int. 2017 May 1;100(3):616-623. doi: 10.5740/jaoacint.17-0048. Epub 2017 Mar 16. doi: 10.1007/s10532-017-9787-8. Epub 2017 Mar 6. doi: 10.1007/s10529-016-2276-z. Epub 2017 Jan 5. doi: 10.1016/j.aquatox.2016.12.011. Epub 2016 Dec 12. doi: 10.1016/j.jhazmat.2016.12.038. Epub 2016 Dec 21. doi: 10.1016/j.saa.2016.12.003. Epub 2016 Dec 15. doi: 10.1002/ps.4501. Epub 2017 Feb 15. Epub 2016 Sep 13. doi: 10.1016/j.jchromb.2016.07.043. Epub 2016 Jul 25. doi: 10.1016/j.chemosphere.2016.02.084. Epub 2016 Mar 9. doi: 10.1002/jssc.201501401. Epub 2016 Apr 13. Erratum in: J Sep Sci. 2016 Aug;39(15):3091.

    合成参考文献


    参考文献:10.1073/pnas.96.23.13387
    摘要:Zuther E, Johnson JJ, Haselkorn R, McLeod R, Gornicki P. Growth ofToxoplasma gondiiis inhibited by aryloxyphenoxypropionate herbicides targeting acetyl-CoA carboxylase. Proc. Natl. Acad. Sci. U.S.A. 1999 Nov 09;96(23):13387–92. doi: 10.1073/pnas.96.23.13387.
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