CAS: 661-36-9; Tetramethylammoniumtetrafluoroborate

该化合物是一种该化合物是一种白色晶状固体,在水和丙烯酸等极地溶剂中高度溶解,TMABF4因其热稳定性,非湿性以及高离子传导性而具有价值,使它在电化学应用(包括电容器和锂离子电池)中成为首选的电解剂,其低核分裂性和对氧化的耐受性增强了其在有机合成中的效用,特别是作为一种逐步转移催化剂.该化合物在恶劣条件下的稳定性以及与各种溶剂的兼容性,有助于其在工业和研究环境中的广泛使用.

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75-57-0 64-20-0 75-58-1

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

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CAS号75-59-2 四甲基氢氧化铵 | CAS号854458-01-8 dimethyl-amine,... | CAS号353-42-4 三氟化硼-二甲醚络合物 | CAS号75-57-0 四甲基氯化铵 | CAS号64-18-6 甲酸 | CAS号541-50-4 3-氧丁酸 | CAS号201230-82-2 carbon monoxide | CAS号67-64-1 丙酮

合成工艺路线路线简述

    📜[2-(Dimethylamino)-1-Methoxy-2-Oxoethylidene]-Dimethylazanium;Tetrafluoroborate,二甲胺 以43%的收率获得产物
    参考文献:Kautlehner W.; Dinkeldein U.; Bredereck H.,Liebigs Ann. Chem.,1979,No 9,1346-1353
    标题:Kautlehner W.; Dinkeldein U.; Bredereck H.,Liebigs Ann. Chem.,1979,No 9,1346-1353

    海关参考信息

    专利信息


    专利号:US-2023286918-A1
    优先权日:2020-07-02
    标 题:Manufacturing process for 3,5-dichloropicolinonitrile for synthesis of vadadustat
    发明人:JURKAUSKAS VALDAS; JUNG YOUNG CHUN; KWON TAESOO; KANNAN ARUNACHALAM; GONDI VIJAYA BHASKER
    权利人:AKEBIA THERAPEUTICS INC
    摘要:Disclosed herein are methods and processes of preparing vadadustat or a pharmaceutically acceptable salts thereof, and intermediates (e.g., a compound of Formula (I), (I-F), (II), or (IV), or a pharmaceutically acceptable salts thereof) useful for the synthesis of vadadustat.

    专利号:US-12435086-B2
    优先权日:2020-04-29
    标题:Synthesis of heterocyclic compounds
    发明人:LIN JACK; WALTERS JASON
    权利人:PLEXXIKON INC
    摘要:Provided herein are intermediates and processes useful for facile synthesis of compounds of Formula 2:wherein R1 is C(O)R2; R2 is alkyl optionally substituted with 1-5 halogens; G is phenyl or a 5-6 membered heteroaryl optionally substituted with 1-2 R3; and each R3 is independently C1-C6 alkyl, CN, C1-C6 alkyl-CN, 3-6 membered cycloalkyl, or 4-6 membered heterocycloalkyl.

    专利号:US-4022672-A
    优先权日:1976-04-02
    标题:Electrochemical synthesis of insecticide intermediates
    发明人:ALVAREZ MANUEL; FISHMAN MORRIS L
    权利人:FMC CORP
    摘要:1,1,1-Trihalo-4-methylpentenes, carrying 2-substituents selected from those conjugate bases of Bronsted acids which are leaving groups in beta eliminations, are reduced electrochemically to 1,1-dihalo-4-methylpentadienes, intermediates in the synthesis of pyrethroid insecticides.

    专利号:US-9267213-B1
    优先权日:2005-03-25
    标题:Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array
    发明人:MAURER KARL; COOPER JOHN J
    权利人:CUSTOMARRAY INC
    摘要:There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.

    专利号:US-4138418-A
    优先权日:1977-03-08
    标题:Process for the preparation of ω,ω-dialkoxycarboxylic acid derivatives
    发明人:WARNING KLAUS; MITZLAFF MICHAEL
    权利人:HOECHST AG
    摘要:ω,ω-Dialkoxycarboxylic acid derivatives I (amides and esters) are prepared by heating ω-alkoxylactams II with hydrogen halide in an alcohol. When using only a catalytical quantity of hydrogen halide, there are obtained the amides, when using a quantity of hydrogen halide which is at least about equimolar, there are obtained the esters of the corresponding ω,ω-dialkoxycarboxylic acids. Since the compounds I are acetals, they may be readily converted into the corresponding ω-formyl compounds. Both the acetals I and the corresponding ω-formyl compounds are valuable intermediates for the synthesis of for example prostaglandins, sexual attractants and antioxidants.

    专利号:US-11518726-B2
    优先权日:2017-10-11
    标题 :Synthesis of bicyclo[2.2.2]octane derivatives
    发明人:HU YUE RACHEL; HEMBRE ROBERT THOMAS; TUSTIN GERALD CHARLES; LIU ZHUFANG; ADAMS STEVEN J
    权利人:EASTMAN CHEM CO
    摘要:Provided is a process for the preparation of certain 1,4-bicyclo[2.2.2]octane derivatives. The new synthetic procedure involves treating 1,4-dimethylene cyclohexane with an oxidizing agent in the presence of a transition metal catalyst to afford an oxo-substituted bicyclo[2.2.2]octane species. This intermediate structure can then be further derivatized. The processes of this disclosure thus affords a novel and simplified means for the commercial production of a wide variety of bicyclo[2.2.2]octane derivatives.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Santana, V. C. S.; Munaretto, L. S.; de Lucca, E. C., Jr., Science of Synthesis Knowledge Updates, (2022) 1, 208.
    摘要:Hou, Z.-W.; Xu, H.-C., Science of Synthesis: Special Topics, (2021) 1, 185.
    摘要:Selt, M.; Waldvogel, S. R., Science of Synthesis: Special Topics, (2021) 1, 258.
    摘要:Folgueiras-Amador, A. A.; Hodgson, J. W.; Brown, R. C. D., Science of Synthesis: Special Topics, (2021) 1, 421.
    摘要:Lam, K.; Leech, M. C.; Lennox, A. J. J., Science of Synthesis: Special Topics, (2021) 1, 444.
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