CAS: 637-90-1; 1,2-Epoxy-5-Cyclooctene

该化合物是一种精密的环氧化合物,其特点是环环环有不饱和的八人环和环氧功能组,其独特的结构将环氧的回活动与环球球体的多功能结合起来,使其成为有机合成中有价值的中间体.该化合物在环环状反应,聚合化和作为精密化学品的前体方面特别有用.其松散的环环系系统可增强反应性,在温和条件下进行选择性转换.此外,由于存在过氧化物和烷的功能,可以进行顺序或正反向的修改,从而扩大了其在制药和材料化学应用中的效用.适当的处理由于其潜在的敏感性而值得注意.

结构式图片

相似化合物

286-62-4 106-86-5 1225194-65-9

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

1,5-cis,cis-cyclo°Ctadiene Trans-2-fluor°Cyclo°Ct-5-en-1-ol trans-8-iodo-cyclo°Ct-4-en-1-yl acetate cyclo-°Cta-1,5-diene Cyclo°Ctene oxide nonanetrans-trans-2,5-di-iodo-9-oxabicyclo4.2.1nonane endo,endo-2,6-diiodo-9-oxa-bicyclo[3.3.1]nonane (Z)-°Ct-4-enedial

合成工艺路线路线简述

    📜1,5-Cis,Cis-Cyclooctadiene置于sodium Hydroxide,Sodium Tetrahydroborate,双氧水,Mercury(II) Trifluoroacetate,苯体系中,化学反应生成 5-Hydroxy-1-Cyclooctene,9,10-Dioxabicyclo<3.3.2>Decane,1,5-环辛二烯一氧化物
    参考文献:氧化金属化.第13部分.通过环二烯的过氧化汞合成二环过氧化物
    标题:氧化金属化.第13部分.通过环二烯的过氧化汞合成二环过氧化物
    摘要:9,10-二氧杂双环[3.3.2]癸烷的双巯基衍生物(12)是通过顺式,顺式的过氧汞化反应制得的.-环-八--1,5-二烯,但在反应中也形成了大量的双环醚.双环过氧化物(4)和(5)分别通过还原和溴分解作用从(12)获得.类似地,通过环辛-1,4-二烯的过氧汞化和脱汞制备了8,9-二氧杂双环[5.2.1]癸烷(6)和二溴衍生物(7).建议过氧化物的异构体纯度和同时形成的双环醚均来自平衡控制可逆(全)氧化汞-脱(全)氧化汞.通过环己-1,4-二烯的过氧汞化和溴解反应,已获得[3.2.1]-过氧化物(8)的低收率,但尝试由5,5-二取代的环戊二烯制备[2.2.1]-化合物的方法有失败了.
    DOI:10.1039/p19810000621

    海关参考信息

    专利信息


    专利号:US-3987073-A
    优先权日:1974-04-25
    标 题:Synthesis of tridecadienoic esters
    发明人:ANDERSON RICHARD J; HENRICK CLIVE A
    权利人:ZOECON CORP
    摘要:Synthesis of the sex pheromone, (7Z,11Z/E)-7,11-hexadecadienyl acetate, of the pink bollworm moth, Pectinophora gossypiella, and intermediates therefor.

    专利号:US-3989729-A
    优先权日:1974-04-25
    标题 :Synthesis of 8-oxo-4-cis-octenoic acid ester
    发明人:ANDERSON RICHARD J; HENRICK CLIVE A
    权利人:ZOECON CORP
    摘要:Synthesis of the sex pheromone, (7Z,11Z/E)-7,11-hexadecadienyl acetate, of the pink bollworm moth, Pectinophora gossypiella, and intermediates therefor.

    专利号:US-7105617-B2
    优先权日:2003-02-06
    标题:Metal 8-hydroxyquinoline-functionalized polymers and related materials and methods of making and using the same
    发明人:WECK MARCUS; MEYERS AMY
    权利人:GEORGIA TECH RES INST
    摘要:This invention relates to the synthesis of Mq n -containing monomeric compounds, comprising a polymerizable moiety, an Mq n -moiety, and an optional chemical spacer therebetween, wherein q, in each instance, comprises an 8-hydroxyquinoline residue, M is a metal such as Mg, Zn, Al, Ga, or In, and n is 2 or 3 as the valence of the metal requires. For example, the polymerization of Znq 2 - or Alq 3 -containing monomers, in the presence or absence of a co-monomer, provided a Znq 2 - or Alq 3 -containing polymer, which retained the optical properties of Znq 2 or Alq 3 in solution, respectively. The Mq n -containing polymers may be used in, among other things, the fabrication of light-emitting diodes (LEDs).

    专利号:US-10195599-B2
    优先权日:2013-06-25
    标题:Synthesis of functionalized carbon microspheres and their catalyst activity in C—O and C—N bond formation reactions
    发明人:BIRADAR ANKUSH VENKATRAO; UMBARKAR SHUBHANGI BHALCHANDRA; DONGARE MOHAN KERABA
    权利人:COUNCIL SCIENT IND RES
    摘要:Disclosed herein is a simple process for functionalization/grafting of carbon microspheres obtained from bagasse with various active functional groups onto it and use of the same as catalyst for various organic reactions, having very high selectivity and conversion rate.

    专利号:US-2018229225-A1
    优先权日:2013-06-25
    标 题:Synthesis of functionalized carbon microspheres and their catalyst activity in c-o and c-n bond formation reactions

    专利号:US-3953532-A
    优先权日:1974-04-25
    标题 :4,8-Tridecadien-1-ol,4 cis,8 cis,trans
    发明人:ANDERSON RICHARD J; HENRICK CLIVE A
    权利人:ZOECON CORP
    摘要:Synthesis of the sex pheromone, (7Z,11Z/E)-7,11-hexadecadienyl acetate, of the pink bollworm moth, Pectinophora gossypiella, and intermediates therefor.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: Edmund J Keliher, Et Al. High-Yielding, Two-Step 18F Labeling Strategy For 18F-Parp1 Inhibitors. Chemmedchem. 2011 Mar 7;6(3):424-7.

    合成参考文献


    摘要:Michalak, M.; Gulajski, L.; Grela, K., Science of Synthesis, (2010) 47, 420.
    摘要:Shimizu, M., Science of Synthesis Knowledge Updates, (2010) 3, 45.
    摘要:Kalow, J. A.; Doyle, A. G., Science of Synthesis Knowledge Updates, (2013) 4, 424.
    摘要:Dagousset, G.; Masson, G., Science of Synthesis Knowledge Updates, (2015) 1, 413.
    摘要:Haufe, G., Science of Synthesis Knowledge Updates, (2019) 3, 141.
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