CAS: 18027-45-7; Phenyltris(Dimethylsiloxy)Silane

该化合物是一种高性能硅氧烷化合物,具有极强的热稳定性,低挥发性和高抗氧化性,因此适用于半导体制造和高温环境.这种材料可以改善化学品不惰性,减少排气,提高电子装置的可靠性和性能.

结构式图片

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号3277-26-7 1,1,3,3-四甲基二硅氧烷 | CAS号2996-92-1 苯基三甲氧基硅烷 | CAS号1066-35-9 二甲基一氯硅烷 | CAS号98-13-5 苯基三氯硅烷

合成工艺路线路线简述

  • 合成目标产物 Phenyltris(Dimethylsiloxy)Silane 主要起始原料 1,1,3,3-Tetramethyldisiloxane And Trimethoxyphenylsilane
  • (文献来源)合成步骤主要原料 1,1,3,3-Tetramethyldisiloxane 和 Trimethoxyphenylsilane
1,1-Dimethyl-3-Phenyl-3,3-Difluorodisiloxane 反应生成苯基三(二甲基硅氧烷基)硅烷
参考文献:Basenko,S. V.;Gebel,I. A.;Vitkovskij,V. Yu.;Mirskov,R. G.;Voronkov,M+,Izv. An Cccp. Cep. Xim.,(1991) N,S. 1162-1166
标题:Basenko,S. V.;Gebel,I. A.;Vitkovskij,V. Yu.;Mirskov,R. G.;Voronkov,M+,Izv. An Cccp. Cep. Xim.,(1991) N,S. 1162-1166

海关参考信息

专利信息


专利号:US-7605218-B2
优先权日:2004-02-03
标题:Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions
发明人:KELLER TEDDY M; KOLEL-VEETIL MANOJ K
权利人:US NAVY
摘要:A carborane-siloxane compound is provided having the repeat unit n nQ contains any of —SiR 2 —, —SiR 2 —O—, —C≡C—C≡C—, carboranyl, and U′. Each R and R′ is alkyl, aryl, alkylaryl, haloalkyl, haloaryl, or mixtures thereof. Each U′ is derivable from hydrosilation of an alkenyl or alkynyl group. Each T is alkyl, aryl, alkylaryl, haloalkyl, haloaryl mixtures thereof, —(O—SiR′ 2 ) x H, or the repeat unit. Each x and x′ is a positive integer. The compounds may be made be reacting a carborane-siloxane precursor having unsaturated end groups with a siloxane crosslinker in the presence of a hydrosilation catalyst.

专利号:US-9085692-B1
优先权日:2014-02-25
标题 :Synthesis of oligomeric divinyldialkylsilane containing compositions
发明人:LASKOSKI MATTHEW; KELLER TEDDY M; SAAB ANDREW
权利人:LASKOSKI MATTHEW; KELLER TEDDY M; SAAB ANDREW; US GOVERNMENT
摘要:A method of: providing a solution of: a dichloroaromatic compound having an electron-withdrawing group bound to each aromatic ring containing one of the chloride groups; an excess of a dihydroxyaromatic compound; a base; and a solvent; heating the solution to a temperature at which the dichloroaromatic compound and the dihydroxyaromatic compound react to form an aromatic ether oligomer; and reacting the aromatic ether oligomer with a chlorodialkylvinylsilane to form one or more vinyl-terminated compounds having the formula below. The aromatic ether oligomer is a dihydroxy-terminated compound or a dimetallic salt thereof. Water formed during the heating is concurrently distilled from the solution. Each R is an alkyl group, Ar 1 is a residue from the dichloroaromatic compound, Ar 2 is a residue from the dihydroxyaromatic compound, and n is a non-negative integer.

专利号:US-7723420-B2
优先权日:2008-07-25
标 题 :Synthesis and polymerization of oligomeric divinyl-terminated aromatic ether-containing resins
发明人:LASKOSKI MATTHEW; KELLER TEDDY M
权利人:US NAVY
摘要:An oligomer having the formula: n nAr 1 and Ar 2 are each an aromatic group or a bisphenol residue. At least one of Ar 1 and Ar 2 is the aromatic group. The value of m is zero or one, and n is a positive integer. A polymer made by reacting the above oligomer with a crosslinker having at least two silyl hydrogen atoms. A method of: reacting a compound having the formula:n n nwith vinyl(dimethylchloro)silane to form the above oligomer. T is —OH, —Br, or —I.

专利号:US-7238766-B2
优先权日:2004-02-03
标题 :Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions

专利号:US-2007161770-A1
优先权日:2004-02-03
标 题:Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions

专利号:US-2007161771-A1
优先权日:2004-02-03
标 题 :Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions
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合成参考文献


参考文献:10.1021/jp056376m
摘要:Pawlus S, Paluch M, Kaminska E, Ngai KL. Anomalous narrowing of the structural relaxation dispersion of tris(dimethylsiloxy)phenylsilane at elevated pressures. J Phys Chem B. 2006 Apr 20;110(15):7678–81. doi: 10.1021/jp056376m.
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