CAS: 6141-27-1; (2S,4S)-4-Methylglutamic Acid
该化合物是一种甲基替代物.这一修改加强了其在精密立体化学学的关键在于肺酸合成和生化研究中的效用.化合物由于能够影响二级结构和结合性互动,因此是设计有相容限制的peptide和酶抑制剂的宝贵建筑构件.其高抗血清纯度能确保实验应用中的再生性.此外,...
- 英文名称(2S,4S)-4-Methylglutamic Acid
- 中文名称(2S,4S)-4-甲基谷氨酸
- IUPAC名称(2S,4S)-2-amino-4-methylpentanedioic acid
- 其它别名(4S)-4-Methyl-L-Glutamic Acid; (2S,4S)-4-Methylglutamic Acid; (2S,4S)-(+)-2-Amino-4-Methylpentanedioic Acid; L-Threo--Methylglutamate; L-Threo--Methylglutamic Acid; Threo-4-Methyl-L-Glutamic Acid; L-Glutamic Acid, 4-Methyl-, (4S)-; (2S,4S)-2-Amino-4-Methylpentanedioicaci
- CAS编号6141-27-1
- MFCD编号:MFCD00142988
- 分子式:C6H11NO4分子量:161.16
- 产品CID: 1596060
- 产品分类有机原料→分子砌块→脂肪链类化合物
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31137-74-3 118758-45-5 105817-04-7物理性质
MSDS等安全信息
上下游产品
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- 合成目标产物 (2S,4S)-4-Methylglutamic Acid 主要起始原料 2-Methyl-4-Oxopentanedioic Acid
- (文献来源)合成步骤主要原料 2-Methyl-4-Oxopentanedioic Acid
📜4-甲基谷氨酸 反应生成 (2S,4S)-4-甲基谷氨酸
参考文献:Resolution And Regioselective Protection Of Glutamic Acid Analogues. I-Resolution Of Diastereomeric α-Boroxazolidone Derivatives.
标题:Resolution And Regioselective Protection Of Glutamic Acid Analogues. I-Resolution Of Diastereomeric α-Boroxazolidone Derivatives.
摘要:Diastereomeric Alpha-Boroxazolidone Gamma-Phenylethylamide (Or Gamma-Phenylethanolamide) Derivatives Of 2-,3-Or 4-Substituted Glutamic Acid Analogues Have Been Separated By Silicagel Chromatography,Resulting,After Deprotection,In A Practical Method For The Resolution Of Most Of These Unnatural Amino Acids.
DOI:10.1016/0957-4166(94)80036-7
海关参考信息
- 2905121000-正丙醇
2912110000-甲醛
2912120000-乙醛
2915110000-甲酸 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
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主要参考文献
参考标题:Synthesis Of Enantio- And Diastereo-Isomerically Pure β- And γ-Substituted Glutamic Acids Via Glycine Condensation With Activated Olefins作者:Yuri N. Belokon,Aleksandr G. Bulychev,Mikhail G. Ryzhov,Sergei V. Vitt,Andrei S. Batsanov,Yuri T. Struchkov,Vladimir I. Bakhmutov,Vasili M. Belikov
摘要:The Glycine Fragment In The Nickel(II) Complex Formed From The Schiff Base Of Glycine And (S)-O[(N-Benzylprolyl)Amino]Benzophenone Undergoes Base-Catalysed Michael Addition In Methanol In The Presence Of Meona To The Activated Olefins Methyl Acrylate, Acrylonitrile, Methyl Methacrylate, Acrolein, And Methyl Trans-Cinnamate. Complexes Of Substituted (S)-Glutamic Acid Or Its Derivatives Were Formed In
合成参考文献
参考DOI号:10.1002/chem.201903725
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