CAS: 2155-94-4; N,N-Dimethylallylamine

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115269-99-3 2424-01-3 1516-27-4

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CAS号7223-38-3 1-二甲基胺-2-丙炔 | CAS号124-40-3 二甲胺 | CAS号106-95-6 烯丙基溴 | CAS号80070-14-0 N-(1-methoxy-1-... | CAS号102990-43-2 N-(2-(dimethyla... | CAS号64-18-6 甲酸 | CAS号107-11-9 丙烯胺 | CAS号282097-60-3 3-dimethylamino... | CAS号107-05-1 氯丙烯 | CAS号124-41-4 甲醇钠 | CAS号105686-38-2 N,N-dimethyl-3-... | CAS号465-65-6 纳洛酮 | CAS号61-50-7 N,N-二甲基色胺 | CAS号3179-63-3 3-二甲氨基-1-丙醇 | CAS号1822-45-3 N,N,N',N'-四甲基-1... | CAS号611-74-5 N,N-二甲基苯甲酰胺 | CAS号556-56-9 烯丙基碘 | CAS号107-05-1 氯丙烯 | CAS号33962-90-2 N,N-dimethylcin... | CAS号35513-04-3 2-(phenyl)-3-(N...

1-二甲基胺-2-丙炔置于哌嗪,氢气体系中,用 乙醇 用作溶剂,100.0 °C,600.01 Kpa 条件下,反应 24.0H,反应生成二甲基烯丙基胺
参考文献:沮丧的路易斯对通过h 2杂种活化作用,金-配体催化炔烃选择性加氢成顺式烯烃
标题:沮丧的路易斯对通过h 2杂种活化作用,金-配体催化炔烃选择性加氢成顺式烯烃
摘要:炔烃的选择性加氢为烯烃是化学工业中重要的合成方法.通常使用包含表面改性剂(例如铅和银)的钯催化剂来完成.在这里,我们报道金纳米颗粒上含氮碱基的吸附导致沮丧的lewis对界面,该界面杂化地激活h 2,从而实现了出乎意料的高氢化活性.如此形成的紧密离子对可以选择性地转移至炔烃,生成顺式异构体;反之亦然.这种行为是由静电相互作用控制的.活性与h 2相关离解能,这取决于配体的碱性及其在氢活化下的重组.高表面占有率和强的au原子-配体相互作用可能会影响活性位点的可及性和稳定性,从而使活性预测成为多参数函数.从机理上讲,发现具有两个杂原子的含氮碱基的促进作用是提高金活性的一种策略.
Doi:10.1021/acscatal.6B03441

专利信息

专利号:US-10005807-B2
优先权日:2013-04-12
标题 :Synthesis of sialylated/fucosylated human milk oligosaccharides
发明人：CHASSAGNE PIERRE; KHANZHIN NIKOLAY; HEDEROS MARKUS JONDELIUS; CHAMPION ELISE; MATWIEJUK MARTIN; DEKANY GYULA
权利人:GLYCOM AS
摘要:An achemo-enzymatic synthesis of oligosaccharides of formula 1 is presented wherein R is selected from —OH, —N 3 and —OR 6 wherein R 6 is selected from allyl optionally substituted by one or more methyl, propargyl optionally substituted by one or more methyl, 2-trimethylsilyl-ethyl, —(CH 2) n —NH 2 and —(CH 2) n —N 3 wherein integer n is to 10, preferably 2 or 3, R is selected from sialyl moiety, —SO 3 H and —CH(R)—COOH wherein R is selected from H, alkyl and benzyl, R 2 is selected from H and fucosyl, R 3 is selected from H and sialyl, R 4 is selected from H and fucosyl, provided that at least one of R 3 and R 4 is H, and A is a divalent carbohydrate linker, having important biological activities and significant commercial value for the pharmaceutical and food industry.

专利号:US-8815351-B2
优先权日:2005-09-15
标 题:Method for attachment of silicon-containing compounds to a surface and for synthesis of hypervalent silicon-compounds
发明人：OWENS JEFFREY R
权利人:OWENS JEFFREY R; US AIR FORCE
摘要:A method for attaching silicon-containing compounds to a surface and for synthesis of hypervalent silicon-compounds is described. Attaching silicon-containing compounds to a surface comprises providing a silicon-containing compound having two or more leaving groups, and a first functional compound comprising at least one nucleophilic group, contacting the silicon-containing compound and the functional compound with a surface of a substrate having nucleophilic sites and exposing the silicon-containing compound, the functional compound and the surface of the substrate to microwave radiation.

专利号:WO-2014167537-A1
优先权日:2013-04-12
标题:Synthesis of sialylated/fucosylated oligosaccharides
发明人：KHANZHIN NIKOLAY; CHASSAGNE PIERRE; HEDEROS MARKUS; CHAMPION ELISE; MATWIEJUK MARTIN; DEKANY GYULA
权利人:GLYCOM AS
摘要:This invention relates to a chemo-enzymatic synthesis of oligosaccharidesof formula 1 wherein R is selected from -OH, -N 3 and -OR 6 wherein R 6 is selected from allyl optionally substituted by one or more methyl, propargyl optionally substituted by one or more methyl, 2-trimethylsilyl-ethyl, -(CH 2 ) n -NH 2 and -(CH 2 ) n -N 3 wherein integer n is to 10, preferably 2 or 3, R 1 is selected from sialyl moiety, -SO 3 H and -CH(R 5 )-COOH wherein R 5 is selected from H, alkyl and benzyl, R 2 is selected from H and fucosyl, R 3 is selected from H and sialyl, R 4 is selected from H and fucosyl, provided that one but only one of R 3 and R 4 is H, and A is selected from a bond and a divalent carbohydrate linker, having important biological activities and significant commercial value for the pharmaceutical and food industry.

专利号:US-5470992-A
优先权日:1992-02-26
标 题:Method for the synthesis of betaines containing≦10 ppm of organically bound chlorine
发明人：GRUNING BURGHARD; FOITZIK WILLI; WEITEMEYER CHRISTIAN; KASEBORN HANS-DIETER
权利人:GOLDSCHMIDT AG TH
摘要:A method for the synthesis of betaines of the general formula ##STR1## by quaternizing the fatty acid amide dialkylamines of the general formula ##STR2## with ω-halogenalkylcarboxylic acids of the formula X-(CH 2 ) y COOH, wherein X is a halogen group, or their salts in aqueous solution, the reaction being carried out within a temperature range of 115° to 180° C., until organically bound chlorine can no longer be detected, the fatty acid amide dialkylamine optionally being quaternized partially or completely in a first step at 80° to 100° C.

专利号:US-2014228554-A1
优先权日:2011-03-18
标 题:Synthesis of new fucose-containing carbohydrate derivatives
发明人：CHAMPION ELISE; DEKANY GYULA; HEDEROS MARKUS; AGOSTON KAROLY
权利人:GLYCOM AS; GLYCOM AS
摘要:A method for the synthesis of a fucooligosaccharide glycosides by reacting a fucosyl donor with H-A-R 1 or a salt thereof, wherein A and R 1 are as defined herein, under the catalysis of an enzyme capable of transferring fucose is provided. The fucooligosaccharid glycoside compounds, or derivatives thereof, their use in the manufacture of human milk oligosaccharides, and a method of manufacture of human milk oligosaccharides, are also provided.

专利号:US-3962291-A
优先权日:1974-09-05
标 题:Total synthesis of 11-alkyl steroids
发明人：GARLAND ROBERT B; PAPPO RAPHAEL
权利人:SEARLE & CO
摘要:A novel total synthesis of 11-alkyl steroids, utilizing readily available and inexpensive raw materials, is described. The resulting products are useful and novel pharmacological agents possessing, for example, selective hormonal properties.