CAS: 21378-21-2; 3-Methylcyclohex-2-Enol

相似化合物

1193-18-6 822-67-3 470-99-5

上下游产品

CAS号1193-18-6 3-甲基-2-环己烯-1-酮 | CAS号591-49-1 1-甲基-1-环己烯 | CAS号71352-17-5 3-methyl-2-(tri... | CAS号75411-49-3 3-methylcyclohe... | CAS号591-48-0 3-甲基-1-环己烯 | CAS号63031-68-5 trimethyl-(6-me... | CAS号930-68-7 环己烯酮 | CAS号51326-26-2 α-bromo-3-methy... | CAS号106491-40-1 3-(2-bromo-1-et... | CAS号22597-21-3 3-METHYLCYCLOHE... | CAS号591-24-2 3-甲基环己酮 | CAS号1193-18-6 3-甲基-2-环己烯-1-酮 | CAS号7443-55-2 trans-3-methylc... | CAS号5454-79-5 Cyclohexanol,3-... | CAS号221635-45-6 7-Oxabicyclo[4.... | CAS号23758-27-2 1-Methyl-2-cycl... | CAS号38309-43-2 7-Oxabicyclo[4.... | CAS号60733-10-0 (S)-3-methyl-2-...

📜3-甲基-1-环己烯置于叔丁基过氧化氢,Potassium Carbonate体系中,用 乙腈 用作溶剂,化学反应 14.0H,以88%的收率获得3-甲基-2-环己烯-1-醇
参考文献:Maghemite Decorated With Ultra-Small Palladium Nanoparticles (γ-Fe2O3-pd): Applications In The Heck-mizoroki Olefination,Suzuki Reaction And Allylic Oxidation Of Alkenes
标题:Maghemite Decorated With Ultra-Small Palladium Nanoparticles (γ-Fe2O3-pd): Applications In The Heck-mizoroki Olefination,Suzuki Reaction And Allylic Oxidation Of Alkenes
摘要:γ-Fe2O3-Pd纳米颗粒用于在更温和的条件下进行heck,Suzuki和烯丙基氧化反应.
Doi:10.1039/c5Gc02264A

专利信息

专利号:US-11958751-B2
优先权日:2022-06-27
标 题:Method of synthesizing materials integrating supernatant recycle
发明人：HODGKINS ROBERT P; KOSEOGLU OMER REFA
权利人:SAUDI ARABIAN OIL CO
摘要:Methods are disclosed for synthesizing materials, including an initial synthesis in the presence of WS-ODSO (which can include a pH-modified WS-ODSO composition, in certain embodiments a neutralized WS-ODSO composition), and one or more subsequent syntheses using supernatant (“mother liquorâ€?) from a previous synthesis of the same or different materials. The synthesized materials in the initial synthesis and in subsequent synthesis can be the same or different inorganic oxide materials including amorphous oxides, crystalline oxides or oxides of metals. The methods advantageously reduce the amount of utility water required for synthesizing a material and reduce the water waste, and reduce the DSO waste from a refinery and discharge into the environment. In certain embodiments the methods reduce the requirements to procure an alkaline reagent required for synthesizing materials. In certain embodiments, supernatant can be recycled over multiple synthesis batches of the same or different type of materia.

专利号:US-6096288-A
优先权日:1998-10-12
标 题 :Synthesis of the cubic mesoporous molecular sieve MCM-48
发明人：ROTH WIESLAW J
权利人:MOBIL OIL CORP
摘要:A method for synthesizing MCM-48 includes combining an inorganic silica reagent, an alkylammonium hydroxide and halide-containing surfactant to form a reaction mixture which is maintained under sufficient conditions to form a crystalline MCM-48 product. In a preferred embodiment, the organic silica reagent and the alkylammonium hydroxide are combined in the agueous medium to form a first reactions mixture and the halide-containing surfactant is then added to the first mixture so as to form a second reaction mixture which is then reacted to form the MCM-48 product. The crystalline MCM-48 material according to the invention can be functionalized by adding aluminum. The crystalline MCM-48 product produced by the process of this invention possesses an X-ray diffraction pattern indicative of a cubic unit cell with Ia3d symmetry.

专利号:US-5585252-A
优先权日:1988-08-30
标 题 :Enantio- and regioselective synthesis of organic compounds using enol esters as irreversible transacylation reagents
发明人：WONG CHI-HUEY; WANG YI-FONG; HENNEN WILIAM J
权利人:SEARLE & CO
摘要:A process for irreversible regio- and stereoselective enzyme catalyzed acylation of alcohols using enol esters as acylating reagents is disclosed. The present invention permits the selective modification of hydroxyl group(s) of chiral and meso alcohols, including sugars, organometallics, and glycosides. The enol freed upon transesterification rapidly tautomerizes to the corresponding volatile aldehyde or ketone thereby preventing the reverse reaction from occurring.

专利号:US-5106750-A
优先权日:1988-08-30
标 题:Enantio- and regioselective synthesis of organic compounds using enol esters as irreversible transacylation reagents
发明人：WONG CHI-HUEY; WANG YI-FONG; HENNEN WILLIAM J; BABIAK KEVIN A; DYGOS JOHN H; NG JOHN S
权利人:SEARLE & CO
摘要:A process for irreversible regio- and stereoselective enzyme catalyzed acylation of alcohols using enol esters as acylating reagents is disclosed. The present invention permits the selective modification of hydroxyl group(s) of chiral and meso alcohols, including sugars, organometallics, and glycosides. The enol freed upon transesterification rapidly tautomerizes to the corresponding volatile aldehyde or ketone thereby preventing the reverse reaction from occurring.

专利号:US-8921261-B2
优先权日:2012-04-10
标题 :Catalyst for synthesizing glycerol carbonate from glycerol, method for producing the catalyst and method for synthesizing glycerol carbonate from glycerol using the catalyst
发明人：LEE MAN SIG; BAEK JAE HO
权利人:KOREA INST OF IND TECHNOLOGY KITECH
摘要:Disclosed are a catalyst for synthesizing glycerol carbonate from glycerol and a method for producing the catalyst. The method includes adding an aqueous NaOH solution, an aqueous KOH solution, or a mixture of an aqueous NH 4 (OH) solution and an aqueous NaOH solution to an aqueous solution of a mixture of zinc nitrate and aluminum nitrate, aging the mixture, filtering and washing the aged mixture to obtain a solid, and calcining the solid under an oxygen, nitrogen or helium atmosphere. The use of the catalyst enables the synthesis of glycerol carbonate from glycerol and urea with high conversion rate, selectivity and yield. Further disclosed is a method for synthesizing glycerol carbonate from glycerol using the catalyst.

专利号:US-5637757-A
优先权日:1995-04-11
标 题 :One-pot synthesis of ring-brominated benzoate compounds
发明人：HILL JOHN E; FAVSTRITSKY NICOLAI A; MAMUZIC RASTKO I; BHATTACHARYA BHABATOSH
权利人:GREAT LAKES CHEMICAL CORP
摘要:A method of preparing tetrabromobenzoate compounds from tetrabromophthalic anhydride by reacting tetrabromophthalic anhydride with alcohol in the presence of a decarboxylation catalyst. The reaction may be carried out in an excess of alcohol, or with a near stoichiometric amount of alcohol by performing the reaction in an inert solvent.