CAS: 136440-22-7; 2,2,4-Trimethyl-1-Oxidoimidazol-1-Ium
该化合物是一个环形异环化合物,其特征为一氧化二联环结构,代之以三甲基组和一氧化二氮功能组,该化合物一般无色,可粉黄为固体或液体,视其形态和纯度而定,以其稳定性和溶解性在极地溶剂中闻名,使其在各种化学应用中有用.氧化物组的存在有助于其作为激进清扫剂的潜力及其在有机合成中的再活性.此外,2,2,4-三甲基-2H-imidazole 1-氧化物可能展示生物活动,从而引起对药物和农用化学品使用的兴趣,其独特结构允许化学反应的多种相互作用,使其在研究和工业应用中成为有价值的化合物.应参考安全数据处理和储存,如同所有化学物质一样.
- 英文名称2,2,4-Trimethyl-1-Oxidoimidazol-1-Ium
- 中文名称2,2,4-三甲基-2H-咪唑 1-氧化物
- IUPAC名称2,2,4-trimethyl-1-oxidoimidazol-1-ium
- 其它别名TMIO; 2,2,4-TRIMETHYL-2H-IMIDAZOLE-1-OXIDE; 2,2,4-TRIMETHYL-2H-IMIDAZOLE 1-OXIDE, FO R ESR-SPECTROSCOPY; 2 2 4-TRIMETHYL-2H-IMIDAZOLE-1-OXIDE 9&; TMIO,; TMIO2,2,4-Trimethyl-2H-imidazole-1-oxide
- CAS编号136440-22-7
- MFCD编号:MFCD00168351
- EINECS号:635-055-5
- 分子式:C6H10N2O分子量:126.16
- 产品CID: 567092
- 产品分类分析化学 → 标准品 → 光谱标准品
物理性质
MSDS等安全信息
欧盟法规
ECHA物质C&L通报上下游产品
acetone propanone 1-oxime合成工艺路线路线简述
📜丙酮,2-氧代丙醛-1-肟置于ammonium Acetate,溶剂黄146体系中,化学反应 75.0H,以60%的收率获得2,2,4-三甲基-2H-咪唑 1-氧化物
参考文献:Synthesis Of 2H-Imidazole 1-Oxides And Stable Nitroxyl Radicals Based On Them
标题:Synthesis Of 2H-Imidazole 1-Oxides And Stable Nitroxyl Radicals Based On Them
摘要:2H-Imidazole 1-Oxides Containing An Aldonitrone Group In The Heterocyclic Ring Are Obtained By The Condensation Of Hydroximinomethyl Ketones With Ketones And Ammonium Acetate. Their Oxidation With Lead Dioxide In Methanol Gives Stable Nitroxyl Radicals-5,5-Dimethoxy-3-Imidazoline-1-Oxyls.
Doi:10.1007/bf00960421
专利信息
专利号:RU-1770322-C
优先权日:1988-09-16
标 题:2,2-dialkyl-2h-imidazole-1-oxides as intermediate compounds for synthesis of stable imidazoline radicals and a method of its synthesis
专利号:RU-1770321-C
优先权日:1988-09-16
标 题:Method of 2,2-dialkyl-2h-imidazole-1-oxides synthesis
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
参考文献:10.1007/s00775-019-01650-9
摘要:Timoshnikov VA, Kobzeva T, Selyutina OY, Polyakov NE, Kontoghiorghes GJ. Effective inhibition of copper-catalyzed production of hydroxyl radicals by deferiprone. JBIC Journal of Biological Inorganic Chemistry. 2019 Mar 13;24(3):331–41. doi: 10.1007/s00775-019-01650-9.
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