CAS: 90224-21-8; Magnesium,3-Methanidylheptane,Bromide

该化合物是有机合成中常见的,用于形成碳-碳债券的灰色化剂,这种有机磁性化合物因其在碳化合物的核循环性附加反应中具有反应性,特别具有价值,能够合成二级和三级酒精,2-乙基己基混合物有助于提高溶解性和稳定性,1M浓度确保反应中精确的口数控制,而THF溶剂则有利于处理和符合无水条件,适合用于制药和精细化学应用,在受控条件下提供一贯的通融和组合反应性能,建议在惰性大气中适当储存以保持再活动.

结构式图片

物理性质

MSDS等安全信息

欧盟法规

C&L通报

合成工艺路线路线简述

  • 18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium Solvents: Diethyl Ether; 0 °C; 14 H,Rt
    标题:Color-Tunable Fluorescent Nanoparticles Encapsulating Trialkylsilyl-Substituted Pyrene Liquids
    作者:Taki,Masayasu; Azeyanagi,Saki; Hayashi,Kenzo; Yamaguchi,Shigehiro
    参考文献:Journal Of Materials Chemistry C: Materials For Optical And Electronic Devices 日期:2017 卷标:5(8) 页码:2142-2148]

    18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium Solvents: Diethyl Ether; Rt; 3 H,Reflux
    标题:Improved Predictions Of Organic Photovoltaic Performance Through Machine Learning Models Empowered By Artificially Generated Failure Data
    作者:Miyake,Yuta; Kranthiraja,Kakaraparthi; Ishiwari,Fumitaka; Saeki,Akinori
    参考文献:Chemistry Of Materials 日期:2022 卷标:34(15) 页码:6912-6920]

    18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium,Iodine Solvents: Diethyl Ether
    标题:Drastic Effects Of Fluorination On Backbone Conformation Of Head-To-Head Bithiophene-Based Polymer Semiconductors
    作者:Liao,Qiaogan; Wang,Yulun; Uddin,Mohammad Afsar; Chen,Jianhua; Guo,Han; Et Al
    参考文献:Acs Macro Letters 日期:2018 卷标:7(5) 页码:519-524]

    18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium Solvents: Diethyl Ether; Rt
    标题:Benzoyl Side-Chains Push The Open-Circuit Voltage Of Pcdtbt/pcbm Solar Cells Beyond 1 V
    作者:Lombeck,Florian; Mullers,Stefan; Komber,Hartmut; Menke,S. Matthew; Pearson,Andrew J.; Et Al
    参考文献:Organic Electronics 日期:2017 卷标:49 页码:142-151]

    18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium Solvents: Diethyl Ether; 2 H,Rt
    标题:Synthesis And Characterization Of Novel Semiconducting Polymers Containing Pyrimidine
    作者:Gunathilake,Samodha S.; Magurudeniya,Harsha D.; Huang,Peishen; Nguyen,Hien; Rainbolt,Elizabeth A.; Et Al
    参考文献:Polymer Chemistry 日期:2013 卷标:4(20) 页码:5216-5219]

    18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Tetrahydrofuran; 0 °C; 1 H,Reflux
    标题:Semi-Conductive Micellar Networks Of All-Conjugated Diblock And Triblock Copolymer Blends
    作者:Kim,Junyoung; Chung,Wooyeol; Kim,Dogyun; Kang,Junwoo; Grandes Reyes,Carlos Fitzgerald; Et Al
    参考文献:Chemical Communications (Cambridge 日期:2023 卷标:59(24) 页码:3578-3581]

    18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium Solvents: Tetrahydrofuran; 30 Min,70 °C; 2 Min,70 °C -> Rt
    标题:Synthesis Of Well-Defined Poly(Norbornene) Containing Carbon Nanodots By Controlled Romp
    作者:Bang,Ki-Taek; Choi,Tae-Lim
    参考文献:Journal Of Polymer Science (Hoboken 日期:2020 卷标:58(1) 页码:48-51]

    18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium Solvents: Tetrahydrofuran; Rt -> 70 °C
    标题:Dithieno[3,2-B:2',3'-D]Pyrrole Cored P-Type Semiconductors Enabling 20% Efficiency Dopant-Free Perovskite Solar Cells
    作者:Zhou,Jie; Yin,Xinxing; Dong,Zihao; Ali,Amjad; Song,Zhaoning; Et Al
    参考文献:Angewandte Chemie 日期:2019 卷标:58(39) 页码:13717-13721]

    18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium Solvents: Tetrahydrofuran; 1 H,Reflux
    标题:Highly Efficient Fullerene And Non-Fullerene Based Ternary Organic Solar Cells Incorporating A New Tetrathiocin-Cored Semiconductor
    作者:Krishnan Jagadamma,Lethy; Taylor,Rupert G. D.; Kanibolotsky,Alexander L.; Sajjad,Muhammad Tariq; Wright,Iain A.; Et Al
    参考文献:Sustainable Energy & Fuels 日期:2019 卷标:3(8) 页码:2087-2099]

    18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium,Iodine
    标题:Separation Of Thorium From Rare Earths With High-Performance Diphenyl Phosphate Extractant
    作者:Dong,Yamin; Li,Shun; Su,Xiang; Wang,Yanliang; Shen,Yinglin; Et Al
    参考文献:Hydrometallurgy 日期:2017 卷标:171 页码:387-393]

    18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium Catalysts: Iodine Solvents: Tetrahydrofuran; 45 Min,Reflux; 40 Min,Reflux
    标题:Mixing Behavior In Small Molecule:Fullerene Organic Photovoltaics
    作者:Oosterhout,Stefan D.; Savikhin,Victoria; Zhang,Junxiang; Zhang,Yadong; Burgers,Mark A.; Et Al
    参考文献:Chemistry Of Materials 日期:2017 卷标:29(7) 页码:3062-3069]

    18908-66-2 = 90224-21-8
    反应条件:1.1 Reagents: Magnesium
    标题:Nickel-Catalyzed Alkylative Cross-Coupling Of Anisoles With Grignard Reagents Via C-O Bond Activation
    作者:Tobisu,Mamoru; Takahira,Tsuyoshi; Morioka,Toshifumi; Chatani,Naoto
    参考文献:Journal Of The American Chemical Society 日期:2016 卷标:138(21) 页码:6711-6714

海关参考信息

专利信息


专利号:US-2018351104-A1
优先权日:2012-11-02
标 题:3-substituted tellurophenes and related compounds
发明人：SEFEROS DWIGHT; JAHNKE ASHLEE
权利人:GOVERNING COUNCIL UNIV TORONTO
摘要:Monomeric 3-substituted tellurophene compounds, as well as their use in the synthesis of oligomeric and/or polymeric compounds consisting of two or more tellurophene-2,5-diyl groups which are covalently linked to each other are disclosed, as is the use of said oligomers and polymers in devices such as diodes and solar cells, electrodes and semiconductors.

专利号:US-8329923-B2
优先权日:2010-06-17
标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same
发明人：VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH
权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT
摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).

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合成参考文献


参考文献:10.1055/s-0037-1611739
摘要:Hu B, Baumgarten M. Thiadiazoloquinoxalines. Synlett. 2019 Mar 12;30(10):1111–24. doi: 10.1055/s-0037-1611739.
参考文献:10.1007/s13233-023-00243-5
摘要:Park J, Chetan L, Kim H, Jee J, Gal Y, Jin S. New pyrazine-based π-conjugated polymer for dopant-free perovskite solar cell. Macromol. Res. 2024 Apr 08;32(6):505–13. doi: 10.1007/s13233-023-00243-5.
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