CAS: 58469-06-0; N-(2-Hydroxy-4-Methoxyphenyl)Acetamide

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1-(2-hydroxy-4-methoxyphenyl)ethanone 3-methoxy-6-nitro-phenol acetic anhydride 6-methoxy-2-methyl-benzoxazoleN-{4-methoxy-2-[(2S)-oxiran-2-ylmethoxy]phenyl}acetamide N-[4-Methoxy-2-(2-oxiranylmethoxy)phenyl]acetamide N-[2-({(2S)-3-[4-(4-fluorobenzyl)-2-oxo-piperazin-1-yl]-2-hydroxypropyl}oxy)-4-methoxyphenyl]acetamide trifluoroacetate N-(2-{[(2S)-3-(5-chloro-1'H,3H-spiro[1-benzofuran-2,4'-piperidin]-1'-yl)-2-hydroxypropyl]oxy}-4-methoxyphenyl)acetamide

📜4'-甲氧基乙酰苯胺置于dipotassium Peroxodisulfate,Tetrafluoroboric Acid,[ruthenium(II)(η6-1-Methyl-4-Isopropyl-Benzene)(Chloride)(μ-Chloride)]2体系中,用 水,1,2-二氯乙烷,丙酮 作为反应溶剂,化学反应 24.0H,以77%的收率获得产物n-(2-羟基-4-甲氧基苯基)乙酰胺
参考文献:钌(II)催化的1,2,3,4-四氢喹啉的区域选择性c-8羟化反应
标题:钌(II)催化的1,2,3,4-四氢喹啉的区域选择性c-8羟化反应
摘要:已经开发了ru(II)催化的1,2,3,4-四氢喹啉的螯合辅助的高区域选择性c8-羟基化反应.各种1,2,3,4-四氢喹啉经过顺畅的c8-h羟基化反应,并以廉价且安全的k 2 S 2 O 8作为氧化剂和氧源,以高收率和高官能度耐受性提供了相应的产品.选择易于安装和拆卸的n-嘧啶导向基团是催化的关键.机理研究表明六元钌循环中间体参与了催化循环.该方法还可以扩展到其他(杂)芳烃ch键的直接羟基化反应.
DOI:10.1021/acs.Orglett.8B02926

专利信息

专利号:US-2004209877-A1
优先权日:2000-04-13
标 题 :Methods for augmenting immune defenses contemplating the administration of phenolic and indoleamine-like compounds for use in animals ans humans
发明人：SHELBY NANCY J; ROSENFELD MARK J
摘要:Phenolic compounds with a phenolic molecule to which are covalently linked an oxygen-containing group, a nitrogen or another oxygen containing group, and a C 1 -C 4 alkoxy group, obtainable from monocotyledonous plants, or by chemical synthesis, have been found to preserve and/or augment innate immune defenses in humans and animals. Additional chemical compounds of the present invention may include benzoxazinoids-cyclic hydroxyamic acids, lactams, and corresponding glucosides, which may serve as precursors to phenolic compounds. The phenolic compounds and precursors of phenolic compounds of the present invention, at concentrations suitable for human and animal therapeutic use, may be obtained from monocotyledonous plants such as corn in their early growth states which are timely harvested for optimum yield.

专利号:US-7794761-B2
优先权日:2000-04-13
标 题:Methods for inducing anti-anxiety and calming effects in animals and humans
发明人：SHELBY NANCY J; GODFREY MITCHELL T; ROSENFELD MARK J
权利人:SEROCTIN RES & TECHNOLOGY INC
摘要:Phenolic compounds with a phenolic molecule to which are covalently linked an oxygen-containing group, a nitrogen or another oxygen containing group, and a C 1 -C 4 alkoxy group, or their precursor compounds, obtainable from monocotyledonous plants, or by chemical synthesis, have been found to calm and/or reduce anxiety and related behaviors and states in humans and animals. Additional chemical compounds of the present invention may include benzoxazinoids-cyclic hydroxyamic acids, lactams, and corresponding glucosides, which may serve as precursors to phenolic compounds. The phenolic compounds and precursors of phenolic compounds of the present invention, at concentrations suitable for human and animal therapeutic use, may be obtained from monocotyledonous plants such as corn in their early growth states which are timely harvested for optimum yield.