CAS: 13963-58-1; Potassium Hexacyanocobaltate(Iii)

该化合物是一种以+3氧化状态中的钴为特征的协调化合物,这一晶体固态因其稳定性和明确界定的八面形几何而显著,使其在化学研究和催化协调方面变得宝贵,其六环十二烷酸盐(III) 的...

结构式图片

欧盟法规

REACH注册ECHA物质ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    专利信息


    专利号:US-4348370-A
    优先权日:1980-01-08
    标题:Ammonia synthesis with catalyst derived by heating on a support a salt selected from alkali metal, alkaline earth metal, iron and cobalt hexacyanocobaltates and hexacyanoruthenates
    发明人:JOHNSON MARVIN M; TABLER DONALD C; NOWACK GERHARD P
    权利人:PHILLIPS PETROLEUM CO
    摘要:Synthesis of ammonia employing at least one salt selected from alkali metal-, an alkaline earth metal-, iron- and cobalt hexacyanocobaltate and hexacyanoruthenate on a suitable support and then heating the composition to provide it with suitable activity.

    专利号:US-4309311-A
    优先权日:1980-01-08
    标 题 :Ammonia synthesis with catalyst derived by heating on a support a salt selected from alkali metal, alkaline earth metal, iron and cobalt hexacyanocobaltates and hexacyanoruthenates
    发明人:JOHNSON MARVIN M; TABLER DONALD C; NOWACK GERHARD P
    权利人:PHILLIPS PETROLEUM CO
    摘要:Synthesis of ammonia employing at least one salt selected from alkali metal-, an alkaline earth metal-, iron- and cobalt hexacyanocobaltate and hexacyanoruthenate on a suitable support and then heating the composition to provide it with suitable activity.

    专利号:US-2016293932-A1
    优先权日:2015-03-30
    标题 :Synthetic methods for transition metal coordination compounds
    发明人:MOTALLEBI SHAHROKH; RISSET OLIVIA NATHALIE; WESSELLS COLIN DEANE
    权利人:ALVEO ENERGY INC
    摘要:A system and method for controlling particle morphology of transition metal coordination compounds (TMCC). Synthesis of TMCC using one of several chelating agents having carboxylate chemical groups. These carboxylate groups bind to copper during the synthesis of the CuHCF TMCC materials, resulting in controlled particle growth, rather than rapid formation of many small nanoparticles as is the case without any chelating agent present. The materials produced using chelating agents of these embodiments such as these are composed of larger particles, making them easier to process into battery electrodes via standard methods such as slurry mixing and coating. The resulting electrodes retain the good electrochemical cycling performance of the control material synthesized without a chelating agent.

    专利号:US-2023340197-A1
    优先权日:2022-04-22
    标题 :Schiff base incorporated double metal cyanide catalyst for the production of polyether polyols
    发明人:KUMAR UMESH; VERMA AKASH; SHARMA BHAWNA; KUMAR AMOD; SWATI; SENTHILKUMAR THANGARAJ; GANGULY SUDIP KUMAR; RAY ANJAN
    权利人:COUNCIL SCIENT IND RES
    摘要:A double metal cyanide [DMC] catalyst and a method for the synthesis thereof at room temperature is disclosed herein. Various Schiff bases are incorporated as organic complexing agents in the DMC catalysts. The catalysts of the present invention are highly active for the ring opening polymerization (ROP) of epoxides in the presence of different H-functional initiators to produce polyether polyols (PEPO) with a wide range of average molecular weight (Mw) and polydispersity index (PDI).

    专利号:US-2023118672-A1
    优先权日:2017-06-21
    标 题:Substituted poly(alkylene oxide) and surfactant composition
    发明人:XU FENG; AL-ANAZI FLAIYH FARHAN N
    权利人:SABIC GLOBAL TECHNOLOGIES BV
    摘要:A method for the synthesis of a substituted poly(alkylene oxide) comprises reacting a substituted alcohol of formula (1) with an alkylene oxide of formula (2) in the presence of a catalyst and under conditions effective to provide the substituted poly(alkylene oxide) of formula (3) wherein in the foregoing formulas, each R is independently hydrogen, C 1-60 alkyl, or C 3-12 cycloalkyl, ring A is cyclohexane or phenyl, each R 1 is independently hydrogen, methyl, ethyl, propyl, butyl, hexyl, decyl, dodecyl, tetradecyl, or hexadecyl, preferably hydrogen or methyl, and n is 2 to 60.

    专利号:US-8946466-B2
    优先权日:2010-05-18
    标 题 :Method for producing polyether carbonate polyols
    发明人:Gürtler Christoph; Hofmann Jörg; WOLF AUREL; GRASSER STEFAN
    权利人:Gürtler Christoph; Hofmann Jörg; WOLF AUREL; GRASSER STEFAN; BAYER IP GMBH
    摘要:The present invention relates to a process for the preparation of polyether carbonate polyols from one or more H-functional starter substances, one or more alkylene oxides and carbon dioxide in the presence of at least one double metal cyanide catalyst, wherein the cyanide-free metal salt, the metal cyanide salt or both the mentioned salts used for the preparation of the double metal cyanide catalyst contain(s) from 0.3 to 1.8 mol base equivalents (based on 1 mol of the metal cyanide salt used for the synthesis of the catalyst) of alkaline metal hydroxide, metal carbonate and/or metal oxide.
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    主要参考文献

    [参考文献]: D W Concar, Et Al. The Modulation Of Cytochrome C Electron Self-Exchange By Site-Specific Chemical Modification And Anion Binding. Febs Lett. 1986 Sep 29;206(1):15-9.
    [参考文献]: E Ragg, Et Al. Association Constants For Metal Hexacyanide Binding To Cytochrome C. J Inorg Biochem. 1984 Jul;21(3):253-61.
    [参考文献]: Edward E Little, Et Al. Toxicity Of Cobalt-Complexed Cyanide To Oncorhynchus Mykiss, Daphnia Magna, And Ceriodaphnia Dubia. Potentiation By Ultraviolet Radiation And Attenuation By Dissolved Organic Carbon And Adaptive Uv Tolerance. Environ Sci Pollut Res Int. 2007 Jul;14(5):333-7.
    [参考文献]: Shah Raj Ali, Et Al. Interaction Of Ribonucleotides With Metal Hexacyanocobaltate(Iii): A Possible Role In Chemical Evolution. Orig Life Evol Biosph. 2007 Jun;37(3):225-34.
    [参考文献]: W J Fairbrother, Et Al. An Nmr Study Of Anion Binding To Yeast Phosphoglycerate Kinase. Eur J Biochem. 1990 May 31;190(1):161-9.

    合成参考文献


    摘要:Journal of Pharmaceutical Sciences., 52(59), 1963 []
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