CAS: 136816-75-6; (4-(3-(Ethylamino)Pyridin-2-yl)Piperazin-1-yl)(5-Methoxy-1H-Indol-2-yl)Methanone

📜在 1-羟基苯并三唑,盐酸-N-乙基-N'-(3-二甲氨基丙基)碳二亚胺,N,N-二异丙基乙胺,Sodium Hydroxide体系中,用 四氢呋喃,水,N,N-二甲基甲酰胺 用作溶剂,化学反应 18.0H,反应生成阿替韦啶
参考文献:钴催化分子内酰胺化通过氧化诱导还原消除途径合成吲哚
标题:钴催化分子内酰胺化通过氧化诱导还原消除途径合成吲哚
摘要:使用高价钴催化的 C-H 键活化和功能化通常涉及 Co(III)/co(I) 催化循环.由于缺乏与 Co(Iv) 中间体的高反应性和不稳定性相关的证据和挑战,涉及 Co(Iv) 中间体的 C-H 官能化机制研究的报告仍未得到充分探索.在此,我们报道了通过 α-酰胺丙烯酸酯的分子内酰胺化有效合成吲哚-2-羧酸酯,并对反应机理进行了实验和计算研究,其中涉及 Co(Iv) 物质的氧化诱导还原消除.
Doi:10.1021/acscatal.3C05706

专利信息

专利号:US-2006115536-A1
优先权日:2004-11-12
标 题 :Glycerin based synthesis of silver nanoparticles and nanowires
发明人：YACAMAN MIGUEL J; ELECHIGUERRA JOSE L; BURT JUSTIN L; MORONES JOSE R; LOPEZ LETICIA L
权利人:UNIV TEXAS
摘要:The present invention includes compositions and methods for the production of noble metal nanoparticles and nanowires conjugated to polyols or polymers. The present invention allows the incorporation of noble metal nanoparticles to a wide range of products such as body care products to exploit the biocidal properties of silver nanoparticles against bacteria, viruses and fungi.

专利号:WO-2007001453-A9
优先权日:2004-11-15
标 题:Glycerin based synthesis of silver nanoparticles and nanowires
发明人：YACAMAN MIGUEL JOSE; ELECHIGUERRA JOSE LUIS; BURT JUSTIN LOCKHEART; MORONES JOSE RUBEN; LARIOS LETICIA
权利人:UNIV TEXAS; YACAMAN MIGUEL JOSE; ELECHIGUERRA JOSE LUIS; BURT JUSTIN LOCKHEART; MORONES JOSE RUBEN; LARIOS LETICIA
摘要:The present invention includes compositions and methods for the production of noble metal nanoparticles and nanowires conjugated to polyols or polymers. The present invention allows the incorporation of noble metal nanoparticles to a wide range of products such as body care products to exploit the biocidal properties of silver nanoparticles against bacteria, viruses and fungi.

专利号:US-11472706-B2
优先权日:2017-11-30
标 题:Hydroxyapatite composite for use in removal of contaminants from effluents and methods of making
发明人：DELPLANCHE THIERRY; MIMOUNI AZIZ; LE MERCIER THIERRY; KHIRANI SARAH; D'ALENCON LAURIANE; ANTOINETTE YVES; ORTEGO BEATRICE
权利人:SOLVAY
摘要:A composite comprising a hydroxyapatite and at least one additive which is present during hydroxyapatite synthesis. The additive may be embedded or incorporated into or coated onto the hydroxyapatite. The additive preferably increases the hydroxyapatite porosity, e.g., providing a higher pore volume and/or BET surface area than a hydroxyapatite material without additive. The additive preferably comprises an activated carbon, chitosan, hopcalite, clays, zeolites, sulfur, and/or a metal such as Al, Sn, Ti, Fe, Cu, Zn, Ni, Cu, Zr, La, Ce, in the form of metal, salt, oxide, oxyhydroxide, and/or hydroxide. The hydroxyapatite may be calcium-deficient. The composite is in the form of particles having a D50 of at least 20 μm, a BET surface area of at least 120 m2/g; and/or a total pore volume of at least 0.3 cm3/g. An adsorbent material comprising a composite or a blend of composite with a hydroxyapatite without additive, and its use for removal of contaminants such as Hg, Se, As, and/or B from an effluent.

专利号:EP-1817042-A2
优先权日:2004-11-15
标 题:Glycerin based synthesis of silver nanoparticles and nanowires

专利号:CA-2587314-A1
优先权日:2004-11-15
标题 :Glycerin based synthesis of silver nanoparticles and nanowires

专利号:WO-2007001453-A2
优先权日:2004-11-15
标题:Glycerin based synthesis of silver nanoparticles and nanowires