CAS: 122406-45-5; 15,35,55,75-Tetra-Tert-Butyl-32,72-Dimethoxy-1,3,5,7(1,3)-Tetrabenzenacyclooctaphane-12,52-Diol

英文名称15,35,55,75-Tetra-Tert-Butyl-32,72-Dimethoxy-1,3,5,7(1,3)-Tetrabenzenacyclooctaphane-12,52-Diol
中文名称1,3-二甲氧基-4-叔丁基杯芳烃
IUPAC名称15,35,55,75-tetra-tert-butyl-32,72-dimethoxy-1,3,5,7(1,3)-tetrabenzenacyclooctaphane-12,52-diol
其它别名1,3-Dimethoxy-4-Tert-Butylcalix(4)Arene; 1,3-Dimethoxy-4-Tert-Butylcalix[4]Arene ; 1,3-Dimethoxy-4-Tert-Butylcalix[4]Arene,; 15,35,55,75-Tetra-Tert-Butyl-32,72-Dimethoxy-1,3,5,7(1,3)-Tetrabenzenacyclooctaphane-12,52-Diol
CAS编号122406-45-5
MFCD编号:MFCD00142526
分子式:C46H60O4分子量:676.98
产品CID: 320998
产品分类化学试剂 → 有机试剂 → 烷烃

相似结构搜索
InChIKey: SDNQRJYYUPMBIV-UHFFFAOYSA-N
InChI=1S/C46H60O4/c1-43(2,3)35-19-27-15-31-23-37(45(7,8)9)25-33(41(31)49-13)17-29-21-36(44(4,5)6)22-30(40(29)48)18-34-26-38(46(10,11)12)24-32(42(34)50-14)16-28(20-35)39(2
计算化学: 氢键受体数4.0氢键供体数2.0可旋转键数6.0

MSDS等安全信息

GHS符号GHS07
警示词Warning
危险描述H315-H319
防范说明P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
安全声明24/25

上下游产品

diazomethane 5,11,17,23-tetra-t-butyl-25,26,27,28-tetrahydroxycalix-4-arene 5,11,17,23-tetra(tert-butyl)-25,26,27,28-tetramethoxycalix[4]arene methyl p-toluene sulfonate 62H74N2O10C62H74N2O10 5,11,17,23-tetrakis-tert-butyl-25,27-dimethoxy-26-trifluoroacetylamin°Carbonyl-28-hydroxycalix[4]arene 5,11,17,23-tetrakis-tert-butyl-25,27-dimethoxy-26-benzoylamin°Carbonyl-28-hydroxycalix[4]arene 5,11,17,23-tetrakis-tert-butyl-25,27-dimethoxy-26-trichloroacetylamin°Carbonyl-28-hydroxycalix[4]arene

合成工艺路线路线简述

合成目标产物 1,3-Dimethoxy-4-Tert-Butylcalix(4)Arene 主要起始原料 Pentacyclo[19.3.1.13,7.19,13.115,19]Octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-Dodecaene-25,26,27,28-Tetrol, 5,11,17,23-Tetrakis(1,1-Dimethylethyl)-, Stereoisomer And Iodomethane
(文献来源)合成步骤主要原料 Pentacyclo[19.3.1.13,7.19,13.115,19]Octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-Dodecaene-25,26,27,28-Tetrol, 5,11,17,23-Tetrakis(1,1-Dimethylethyl)-, Stereoisomer 和 Iodomethane

📜5,11,17,23-Tetra-T-Butyl-25,26,27,28-Tetrahydroxycalix-4-Arene置于sodium Hydroxide,氢化钾体系中,用四氢呋喃用作溶剂,化学反应生成1,3-二甲氧基-4-叔丁基杯芳烃
参考文献:杯[4]芳烃衍生物的还原和氧化反应
标题:杯[4]芳烃衍生物的还原和氧化反应
摘要:25,26,27,28-四甲氧基-对-叔丁基杯[4]芳烃与k的还原裂解导致26,28-二甲氧基-对丁基丁基杯[4]芳烃的形成.25,27-二羟基杯[4]亚芳基与no 2 Bf 4在乙腈中的反应导致其氧化为杯二醌6.
Doi:10.1016/s0040-4039(00)85995-X