CAS: 1195-31-9; (R)-4-Isopropyl-1-Methylcyclohex-1-Ene

相似化合物

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上下游产品

dihydromyrcene D-limonene Phosphoric acid diethyl ester (R)-5-isopropyl-2-methyl-cyclohex-1-enyl ester endo-9-bromobornan-2-ol mesylate S,2S,4R)-1-hydroxy-p-menthan-2-ylmercury (1+); chloride(1S,2S,4R)-1-hydroxy-p-menthan-2-ylmercury (1+); chloride carvotanacetone 1-p-menthanyl chloride 1-methyl-4-(1-methylethyl)cyclohexanol

📜Endo-9-Bromobornan-2-Ol Mesylate置于sodium Naphthaleimide体系中,用 四氢呋喃 用作溶剂,化学反应 0.25H,反应生成(+)-对-薄荷-1-烯
参考文献:Synthesis And Absolute Configuration Of The Antiparasitic Furanosesquiterpenes (-)-Furodysin And (-)-Furodysinin. Camphor As A Six-Membered Ring Chiral Pool Template
标题:Synthesis And Absolute Configuration Of The Antiparasitic Furanosesquiterpenes (-)-Furodysin And (-)-Furodysinin. Camphor As A Six-Membered Ring Chiral Pool Template
摘要:The Syntheses Of (-)-Furodysin ((-)-2A) And (-)-Furodysinin ((-)-3A) In Four Steps Starting From (+)-9-Bromocamphor (18) Has Been Accomplished,Thus Establishing The Absolute Configuration Of These And Related Metabolites. This Was Made Possible By The Unexpected Exo Selectivity In The Aldol Condensation Of Camphor-Like Enolates With Aldehydes. This Has Been Found To Be A General Phenomenon In The Camphor System. Further,Anionic Fragmentation Of The C1-C7 Bond Of Camphor Derivatives Has Allowed Access To Synthetic Intermediates Containing Functionalized Six-Membered Rings,Thus Opening Up Avenues From Camphor To A New Class Of Chiral Pool Elements Not Currently Available From Chiral Pool Substances.
Doi:10.1021/jo00001A069