CAS: 81644-55-5; 6-Mercapto-6-Deoxy-ß-Cyclodextrin
该化合物是一种化学修改的环球衍生物,在β-环环环中,C-6位置的单一甘蔗单位中,其功能组具有硫醇(-SH)功能组.这一修改增强了其在需要选择性分子封装和共价同化的应用中的效用.硫醇组可以使金表面,雄性活化化合物或其他硫醇反应性聚变物具有外附性,使其在生物测量,药物交付和纳米技术中具有价值.其β-cyclotexrin核心保留了主座座座-座座干涉特性,允许同步分子识别和功能化.该产品在控制释放系统,表面改造和生物分子不活动联系中特别有用.高纯度和定义良好的结构确保了研究和工业应用中的再生性.
- 英文名称6-Mercapto-6-Deoxy-ß-Cyclodextrin
- 中文名称6-巯基-6-脱氧-β-环糊精
- IUPAC名称6-Mercapto-6-deoxy-β-Cyclodextrin
- 其它别名单(6-巯基-6-去氧)倍他环糊精; Mono-(6-Mercapto-6-Deoxy)-Beta-Cyclodextrin
- CAS编号81644-55-5
- MFCD编号:MFCD31537208
- 分子式:C42H70O34S分子量:1151.05
- 产品CID: 1809344
- 产品分类有机原料→分子砌块→手性化合物→手性砌块
- 相似结构搜索
- InChIKey: KBQFCFNGXZCYMC-FOUAGVGXSA-N
- KBQFCFNGXZCYMC-JXMPPWEANA-N
- 计算化学: 氢键受体数35.0氢键供体数21.0可旋转键数7.0
相似化合物
7585-39-9 69-79-4 528-50-7物理性质
MSDS等安全信息
上下游产品
β-环糊精 β-Cyclodextrin 7585-39-9合成工艺路线路线简述
- 67217-55-4 = 81644-55-5
反应条件:1.1 Reagents: Thiourea Solvents: Dimethylformamide; 2 D,75 °C; 75 °C -> Rt1.2 Solvents: Acetone; 2 H,Rt -> Reflux; Reflux -> Rt1.3 Reagents: Sodium Hydroxide,Sodium Pyrosulfite Solvents: Water; Rt; 30 Min,Rt1.4 Reagents: Hydrochloric Acid Solvents: Water; Ph 31.5 Solvents: Trichloroethylene; 10 Min,Rt
标题:Dendrimeric β-Cyclodextrin/gdiii Chelate Supramolecular Host-Guest Adducts As High-Relaxivity Mri Probes
作者:Martinelli,Jonathan; Et Al
参考文献:Chemistry - A European Journal 日期:2014 卷标:20(35) 页码:10944-10952]
67217-55-4 = 81644-55-5
反应条件:1.1 Reagents: Thiourea Solvents: Methanol,Water; 72 H,Reflux1.2 Reagents: Sodium Hydroxide Solvents: Water; 5 H,50 °C1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 2
标题:Raft Polymerization Of Vinyl Methacrylate And Subsequent Conjugation Via Enzymatic Thiol-Ene Chemistry
作者:Yhaya,Firdaus; Et Al
参考文献:Journal Of Polymer Science 日期:2012 卷标:50(19) 页码:4085-4093]
67217-55-4 = 81644-55-5
反应条件:1.1 Reagents: Thiourea Solvents: Dimethylformamide; 20 Min,100 °C1.2 Solvents: Acetone; Cooled
标题:Efficient Regioselective Functionalizations Of Cyclodextrins Carried Out Under Microwaves Or Power Ultrasound
作者:Martina,Katia; Et Al
参考文献:Tetrahedron Letters 日期:2007 卷标:48(52) 页码:9185-9189]
67217-55-4 = 81644-55-5
反应条件:1.1 Solvents: Methanol,Water; 60 H,Reflux1.2 Reagents: Sodium Hydroxide Solvents: Water; 8 H,50 °C1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 2
标题:Reusable Xerogel Containing Quantum Dots With High Fluorescence Retention
作者:Liang,Xiang-Yong; Et Al
参考文献:Polymers (Basel 日期:2018 卷标:10(3) 页码:310/1-310/14]
67217-55-4 = 81644-55-5 [标题:Reaction Conditions
标题:Structural Versatility In Slide-Ring Gels: Influence Of Co-Threaded Cyclodextrin Spacers
作者:Murakami,Takuya; Et Al
参考文献:Journal Of Polymer Science 日期:2017 卷标:55(7) 页码:1156-1165]
7585-39-9 = 81644-55-5 [标题:Reaction Conditions
标题:Synthetic Assembly Of Two β-Cyclodextrins Through A Trehalose Moiety As A Linker
作者:Ishimaru,Yoshihiro; Et Al
参考文献:Tetrahedron Letters 日期:2021 卷标:78]
7585-39-9 = 81644-55-5
反应条件:1.1 -2.1 Solvents: Methanol,Water; 60 H,Reflux2.2 Reagents: Sodium Hydroxide Solvents: Water; 8 H,50 °C2.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 2
标题:Reusable Xerogel Containing Quantum Dots With High Fluorescence Retention
作者:Liang,Xiang-Yong; Et Al
参考文献:Polymers (Basel 日期:2018 卷标:10(3) 页码:310/1-310/14]
7585-39-9 = 81644-55-5 [标题:Reaction Conditions
标题:One-Pot "Click" Fabrication Of Slide-Ring Gels
作者:Murakami,Takuya; Et Al
参考文献:Macromolecules (Washington 日期:2015 卷标:48(21) 页码:7774-7781
📜Mono<6-(P-Tolylsulfonyl)-6-Deoxy>-β-Cyclodextrin置于硫脲体系中,用 甲醇,水 作为反应溶剂,以50%的收率获得产物6-巯基-6-去氧-β-环糊精
参考文献:Increasing The Persistency Of Stable Free-Radicals: Synthesis And Characterization Of A Nitroxide Based [1]Rotaxane
标题:Increasing The Persistency Of Stable Free-Radicals: Synthesis And Characterization Of A Nitroxide Based [1]Rotaxane
摘要:A Persistent Paramagnetic [1]Rotaxane Based On Beta-Cyclodextrin Showing An Increased Persistency Under Reductive Conditions Has Been Prepared And Characterized For The First Time.
DOI:10.1021/ol800405B
