CAS: 7567-63-7; 1,3,5-Triethynylbenzene

相似化合物

1785-61-1 766-82-5 6366-06-9

上下游产品

CAS号626-39-1 1,3,5-三溴苯 | CAS号1066-54-2 三甲基硅基乙炔 | CAS号626-44-8 1,3,5-三碘苯 | CAS号191846-86-3 1,3-dibromo-5-e... | CAS号599187-51-6 3,5-bis(trimeth... | CAS号18823-04-6 1,3,5-tris((tri... | CAS号74-86-2 乙炔 | CAS号211739-82-1 1,3,5-tris[2-(4...

1,3,5-三碘苯置于bis-Triphenylphosphine-Palladium(II) Chloride Sodium Hydroxide,Copper(L) Iodide,三乙胺体系中,用 四氢呋喃 作为反应溶剂,化学反应 5.0H,反应生成 1,3,5-三乙炔苯
参考文献:Modular Synthesis Of Benzene-Centered Porphyrin Trimers And A Dendritic Porphyrin Hexamer
标题:Modular Synthesis Of Benzene-Centered Porphyrin Trimers And A Dendritic Porphyrin Hexamer
摘要:Rigid,Star-Shaped D-3-Symmetric Arrays Have Been Synthesized In Which Three Porphyrin Macrocycles Are Attached To The 1,3,And 5 Positions Each Of A Benzene Core Through Linkers Consisting Of Collinear Repetitive Phenylethynyl Units. Using The Same Methodology,A Dendridic Porphyrin Hexamer Having An External Diameter Of Ca. 10 Nm Has Been Also Obtained. By Successive Substitution Of The Three Benzene Positions,Both A Porphyrin Trimer,The Three Linkers Of Which Are Of Different Length,And A Starlike Porphyrin,In Which The Complexed Metal Ions Are Different From Each Other,Have Been Synthesized. The Latter Is The First Example Of A Prochiral Arrangement Of Metal Ions In A D-3-Symmetric Ligand. To Investigate Their Capability Of Forming Ordered Self-Assembled Monolayers On Gold Substrates,Some Of The Porphyrin Trimers And The Dendritic Porphyrin Hexamer Described In This Work Bear Meta-Thioanisole Units At The Apical Positions. Analogously To Similar Multiporphyrin Systems Described In The Literature,In Which,However,The Chromophores Were Arranged Collinearly,The Interaction Between The Chromophores Of The Multiporphyrin Arrays Described In This Work Is Negligible,In The Ground State,While Effective Energy Transfer Takes Place In The Singlet Excited State.
DOI:10.1021/jo980846+

专利信息

专利号:WO-2017137895-A1
优先权日:2016-02-09
标题 :New dendrimeric pyrrolidines, their synthesis and medical use
发明人：CARDONA FRANCESCA; PARMEGGIANI CAMILLA; MATASSINI CAMILLA; GOTI ANDREA; MORRONE AMELIA; CATARZI SERENA; D'ADAMIO GIAMPIERO
权利人:UNIVERSITA' DEGLI STUDI DI FIRENZE; AZIENDA OSPEDALIERO UNIV MEYER
摘要:The subject-matter of the present invention relates to the synthesis of new dendrimeric molecules based on polyhydroxylated pyrrolidines obtained by means of Click Chemistry reactions. The proposed molecules inhibit the enzymes N-acetylgalactosamine-6-sulfatase (GALNS), iduronate-2-sulfatase (IDS), a-mannosidase and β-glucosidase, deficient in lysosomal storage diseases. The presentation of multivalent iminosugars on a scaffold is a prerequisite for the inhibitory activity as the corresponding monomers are not active. The inhibitory activity reported is the basis for the development of the first-ASSC pharmacological chaperones proposed for the treatment of the above mentioned pathologies. Formula (I)

专利号:US-2024067779-A1
优先权日:2021-03-01
标题:Metallopolymers and iclick synthesis thereof
发明人：BETO CHRISTOPHER; SCHANZE KIRK S; VEIGE ADAM S; YANG YAJING
权利人:UNIV FLORIDA; UNIV OF TEXAS SAN ANTONIO
摘要:Provided herein are various metallopolymers and methods of making the same.

专利号:EP-4293078-A1
优先权日:2022-06-14
标题:Method for preparing conjugate porous polymers and uses thereof
发明人：LIRAS TORRENTE MARTA; NARANJO SÃ?NCHEZ TERESA; PALENZUELA REBELLA SANDRA; BARAWI MORÃ?N MARIAM; DE LA PEÑA O´SHEA VICTOR A
权利人:FUND IMDEA ENERGIA
摘要:This invention provides a polymerization method, which yields nanostructured conjugate porous polymers. By applying in a successive manner ultrasound tip conditions and microfluidic techniques to water-organic solvent mixtures in presence of a surfactant, emulsions containing nanomicelles are formed. The polymerization occurs via metal-catalyzed cross-coupling reactions, condensation reactions or light-mediated free-radical reactions and leads to nanostructured conjugate porous polymers with reduced average particle size and narrow particle size dispersity. Such polymers are easy to process, thus, they can be used in a variety of applications, including the synthesis of hybrid organic-inorganic materials as well as in photocatalysis and in the production of thin films.

专利号:WO-2022252071-A1
优先权日:2021-05-31
标题:A synthetic polymeric porous medium with hierarchical multiple layer structure, its design, synthesis, modification, and liquid chromatographic applications
发明人：MAO HUIMING; XU FENG; YANG KE; HU XINMEI; HUANG XUEYING
权利人:SUZHOU SEPAX TECH INC; SEPAX TECH INC
摘要:A synthetic polymeric porous medium with a core-shell (s) hierarchical layer structure, whose core and shell (s) are covalently modified with distinct chemical functional groups or same functional group with different density. Here the methodologies for resin syntheses and core-shell (s) modifications and liquid chromatographic applications of the newly developed resins in the field of analysis and purification of Tween surfactants, virus-like particles (VLP) /vaccines/viral vectors/viruses, antibody, and mRNA are disclosed.

专利号:US-12084554-B2
优先权日:2017-04-10
标 题 :Polyphenylenes, methods, and uses thereof
发明人：HOLDCROFT STEVEN; SKALSKI THOMAS J G; ADAMSKI MICHAEL; BRITTON BENJAMIN; PECKHAM TIMOTHY J
权利人:UNIV FRASER SIMON
摘要:Described herein are anionic phenylene oligomers and polymers, and devices including these materials. The oligomers and polymers can be prepared in a convenient and well-controlled manner, and can be used in cation exchange membranes. Also described is the controlled synthesis of anionic phenylene monomers and their use in synthesizing anionic oligomers and polymers, with precise control of the position and number of anionic groups.

专利号:US-2007069198-A1
优先权日:2003-09-29
标题:Synthesis of phenyl-substituted fluoranthenes by a diesel-alder reaction and the use thereof