CAS: 598-25-4; 3-Methylbuta-1,2-Diene

该化合物是一种挥发性易燃碳氢化合物,可应用于有机合成和聚合化学,其相融合的狄氏体结构能够产生迪尔斯-阿尔德反应,使其对生产特殊化学品和弹性体具有价值.该化合物的回活动性和低分子重量在受控聚合工艺和精细化学制造方面提供了优势.由于不稳定,需要妥善处理.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号1111-97-3 3-氯-3-甲苯-1-丁炔 | CAS号6214-32-0 1-bromo-3-methy... | CAS号3017-70-7 2-溴-3-甲基-2-丁烯 | CAS号113647-42-0 methyl propargy... | CAS号598-23-2 3-甲基-1-丁炔 | CAS号115-19-5 3-甲基丁炔醇-3 | CAS号594-51-4 2,3-二溴-2-甲基丁烷 | CAS号10288-13-8 1,2-二溴-3-甲基丁烷 | CAS号30758-34-0 2,2-Dimethyl-3-... | CAS号10288-13-8 1,2-二溴-3-甲基丁烷 | CAS号109976-07-0 3-methylbuta-1,... | CAS号109976-08-1 (1,1-Dimethyl-2... | CAS号62199-59-1 3-methylbut-1-y... | CAS号109976-09-2 1,1-bis(dipheny... | CAS号4158-86-5 2,2-二甲基-1,3-二氧戊环-4-酮 | CAS号67-64-1 丙酮 | CAS号1809-02-5 2-chloro-3-meth... | CAS号18804-50-7 2,4-dimethyl°Ct... | CAS号513-35-9 2-甲基-2-丁烯

合成工艺路线路线简述

    📜2-溴-3-甲基-2-丁烯置于氢氧化钾体系中,135.0~140.0 °C,1.27 Mpa 条件下,反应生成 3-甲基-1,2-丁二烯
    参考文献:Pd Deposition Onto The Thermally Roughened Cu(110) Surface
    标题:Pd Deposition Onto The Thermally Roughened Cu(110) Surface
    摘要:We Study The Deposition Of Pd Onto Two Morphologically Distinct Cu(110) Surfaces: The First Being The Surface Prepared By Conventional Ion Bombardment And Anneal Cycles And The Second Being The Thermally Roughened Surface Consisting Of A Well-Defined Surface Morphology Of Large Terraces Terminated By Exclusively Monoatomic Height Steps. We Use The Optical Technique Of Reflection Anisotropy Spectroscopy In Combination With Scanning Tunnelling Microscopy To Characterise The Deposition. We Find That The Morphological Nature Of The Cu(110) Surface Results In A Different Surface Reconstruction For The Same Conditions Of Pd Deposition.
    DOI:10.1002/1521-396X(200112)188:4<1505::Aid-Pssa1505>3.0.Co;2-8

    海关参考信息

    专利信息


    专利号:US-9126995-B2
    优先权日:2011-11-08
    标题:Method for catalytic asymmetric synthesis of optically active isoxazoline compound and optically active isoxazoline compound
    发明人:TOYAMA KEN-ICHI; MORIYAMA YUJI; MATOBA KAZUTAKA; YAOSAKA MANABU; IKEDA EITATSU
    权利人:NISSAN CHEMICAL IND LTD
    摘要:There is provided a method for catalytic asymmetric synthesis of optically active isoxazoline compound and an optically active isoxazoline compound. A method for catalytic asymmetric synthesis of optically active isoxazoline compound of a formula (6) including reacting an α,β-unsaturated carbonyl compound of a formula (1) and a hydroxylamine in a solvent in the presence of a base by adding a chiral phase transfer catalyst. An optically active isoxazoline compound of a formula (13) that can be synthesized by the method.

    专利号:US-2013184465-A1
    优先权日:2010-09-30
    标 题:Process for the synthesis of thio-triazolo-group containing compounds
    发明人:DOCHNAHL MAXIMILIAN; KEIL MICHAEL; GEBHARDT JOACHIM; VOGELBACHER UWE JOSEF; RACK MICHAEL
    权利人:DOCHNAHL MAXIMILIAN; KEIL MICHAEL; GEBHARDT JOACHIM; VOGELBACHER UWE JOSEF; RACK MICHAEL; BASF SE
    摘要:The present invention relates to a process using specific magnesium reagents for providing thio-triazolo group-containing compounds and for the synthesis of precursors therefor. The invention furthermore relates to intermediates and to their preparation.

    专利号:WO-9955664-A1
    优先权日:1998-04-24
    标 题 :Preparation of carbocyclic compounds
    发明人:BECKER MARK W; CHAPMAN HARLAN H; KELLY DAPHNE E; KENT KENNETH M; LEW WILLARD; LOUIE MICHAEL S; MCGEE LAWRENCE R; PRISBE ERNEST J; POSTICH MICHAEL J; ROHLOFF JOHN C; SCHULTZE LISA M; YU RICHARD H; ZHANG LIJUN
    权利人:GILEAD SCIENCES INC; BECKER MARK W; CHAPMAN HARLAN H; KELLY DAPHNE E; KENT KENNETH M; LEW WILLARD; LOUIE MICHAEL S; MCGEE LAWRENCE R; PRISBE ERNEST J; POSTICH MICHAEL J; ROHLOFF JOHN C; SCHULTZE LISA M; YU RICHARD H; ZHANG LIJUN
    摘要:The present invention provides new synthetic methods and compositions. In particular, new methods of preparing intermediates useful in the synthesis of neuraminidase inhibitors and compositions useful as intermediates that are themselves useful in the synthesis of neuraminidase inhibitors are provided.

    专利号:US-6518438-B2
    优先权日:1996-08-23
    标题:Preparation of cyclohexene carboxylate derivatives
    发明人:KENT KENNETH M; KIM CHOUNG U; MCGEE LAWRENCE R; MUNGER JOHN D; PRISBE ERNEST J; POSTICH MICHAEL J; ROHLOFF JOHN C; KELLY DAPHNE E; WILLIAMS MATTHEW A; ZHANG LIJUN
    权利人:GILEAD SCIENCES INC
    摘要:The present invention provides new synthetic methods and compositions. In particular, new methods of preparing intermediates useful in the synthesis of neuraminidase inhibitors and compositions useful as intermediates that are themselves useful in the synthesis of neuraminidase inhibitors are provided.

    专利号:US-5886213-A
    优先权日:1997-08-22
    标题:Preparation of carbocyclic compounds
    发明人:KENT KENNETH M; KIM CHOUNG U; MCGEE LAWRENCE R; MUNGER JOHN D; PRISBE ERNEST J; POSTICH MICHAEL J; ROHLOFF JOHN C; KELLY DAPHNE E; WILLIAMS MATTHEW A; ZHANG LIJUN
    权利人:GILEAD SCIENCES INC
    摘要:The present invention provides new synthetic methods and compositions. In particular, new methods of preparing intermediates useful in the synthesis of neuraminidase inhibitors and compositions useful as intermediates that are themselves useful in the synthesis of neuraminidase inhibitors are provided.

    专利号:US-6204398-B1
    优先权日:1996-08-23
    标题 :Preparation of cyclohexene carboxylate derivatives
    发明人:KENT KENNETH M; KIM CHOUNG U; MCGEE LAWRENCE R; MUNGER JOHN D; PRISBE ERNEST J; POSTICH MICHAEL J; ROHLOFF JOHN C; KELLY DAPHNE E; WILLIAMS MATTHEW A; ZHANG LIJUN
    权利人:GILEAD SCIENCES INC
    摘要:The present invention provides new synthetic methods and compositions. In particular, new methods of preparing intermediates such as those having formulas (I)-(IV), useful in the synthesis of neuraminidase inhibitors and compositions useful as intermediates that are themselves useful in the synthesis of neuraminidase inhibitors are provided.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Aguilar, E.; López, L. A., Science of Synthesis Knowledge Updates, (2014) 2, 54.
    摘要:Petasis, N. A., Science of Synthesis, (2010) 47, 237.
    摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 234.
    摘要:Okamoto, K.; Ohe, K., Science of Synthesis Knowledge Updates, (2020) 1, 29.
    摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 228.
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