4-硝基-1-苯氧基-2-(三氟甲基)苯置于tin(Ll) Chloride体系中,化学反应生成2,2'-双(三氟甲基)-4,4'-二氨基苯基醚 参考文献:Aromatic Fluorine Compounds. Vii. Replacement Of Aromatic-Cl And-No2 Groups By-F1,2 标题:Aromatic Fluorine Compounds. Vii. Replacement Of Aromatic-Cl And-No2 Groups By-F1,2 摘要: Doi:10.1021/ja01604A022
专利号:US-2016032052-A1 优先权日:2014-08-01 标 题:Process for manufacturing polyamide 发明人:KATAYAMA TOSHIHIKO; OKADA JUN; KAWASAKI RITSUYA; UMEDA HIDEO 权利人:SUMITOMO BAKELITE CO 摘要:In one or a plurality of embodiments, a process for manufacturing polyamide, with a reduced use of an amide-based solvent in synthesis, is provided. In one or a plurality of embodiments, provided is a process for manufacturing polyamide, including steps (a) to (c): (a) dissolving diacid dichloride in a non-amide-based organic solvent; (b) adding diamine to a solution obtained in the step (a) and reacting the diacid dichloride with the diamine so as to generate polyamide; and (c) adding a trapping reagent capable of trapping hydrochloric acid, at any time at least before the step (b), at the same time of starting the step (b), or during the step (b).
专利号:US-2016075826-A1 优先权日:2014-09-11 标 题:Process for manufacturing polyamide 发明人:SUN LIMIN; ZHANG DONG; JING JIAOKAI; HARRIS FRANK W; OKADA JUN; KATAYAMA TOSHIHIKO; UMEDA HIDEO; KAWASAKI RITSUYA 权利人:AKRON POLYMER SYSTEMS INC; SUMITOMO BAKELITE CO 摘要:In one or a plurality of embodiments, a process for manufacturing polyamide without using PrO (propylene oxide) in synthesis is provided. In one or a plurality of embodiments, provided is a process for manufacturing polyamide, including steps (a) to (c): (a) reacting diacid dichloride monomer with at least two kinds of diamine monomers in a solvent so as to generate polyamide; and (b) removing hydrochloric acid physically out of a reaction system, the hydrochloric acid being generated during the reaction in the step (a); or (c) adding a trapping reagent capable of trapping hydrochloric acid, at any time at least before the step (a), at the same time of starting the step (a), or during the step (a), wherein at least one of the diamine monomers is a diamine monomer containing a carboxyl group, and the trapping reagent does not include propylene oxide.