CAS: 18769-05-6; 1,1,3,3-Tetraphenyl-1,3-Divinyldisiloxane

Diphenylvinylsilan置于水,1,8-二氮杂双环[5.4.0]十一碳-7-烯,孟加拉红内酯,六氟化硫体系中,用 乙腈 用作溶剂,20.0 °C,101.33 Kpa 条件下,以37 %的收率获得1,3-二乙烯基四苯基二硅氧烷
参考文献:Sf6 可见光诱导硅烷氧化,高效合成硅氧烷
标题:Sf6 可见光诱导硅烷氧化,高效合成硅氧烷
摘要:已经建立了通过可见光诱导硅烷与 Sf 6氧化合成硅氧烷的方法,具有广泛的底物范围和高效率.
Doi:10.1002/ejoc.202400451

专利信息

专利号:US-11767388-B1
优先权日:2019-09-18
标 题 :Silicon-functionalized rubber
发明人：ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING
权利人:GOODYEAR TIRE & RUBBER
摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.

专利号:US-6384172-B1
优先权日:2001-01-02
标题:Hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof
发明人：DVORNIC PETAR R; HU JIN; MEIER DALE J; NOWAK ROBERT M
权利人:MICHIGAN MOLECULAR INST
摘要:Hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof are prepared by reacting a difunctional or polyfunctional monomer having functional groups of one type (A) without any other functional groups capable of reacting significantly during polymerization, and a difunctional or polyfunctional monomer having functional groups of another type (B) without any other functional groups capable of reacting significantly during polymerization, wherein each A-functional group is reacted with a B-functional group, and wherein at least one of the monomers has a functionality of at least three. The process enables hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof to be prepared at a lower cost than with conventional synthesis processes, and provides greater flexibility in the preparation of a larger variety of different types of hyperbranched polycarbosilanes, polycarbosiloxanes, polycarbosilazenes and copolymers thereof.

专利号:CN-113321810-B
优先权日:2021-06-01
标题:A kind of Q type high refraction phenyl vinyl silicone oil, its synthesis method and application

专利号:CN-107936254-A
优先权日:2017-11-24
标 题:Synthesis method of silicone special resin for LED chip bonding

专利号:US-9187695-B2
优先权日:2012-03-12
标题:Phosphorus—silicon synergistic flame retardants and the preparation method and use thereof
发明人：YANG SHIYONG; SONG TAO; LIU JINGANG
权利人:YANG SHIYONG; SONG TAO; LIU JINGANG; CHINESE ACAD INST CHEMISTRY
摘要:The present invention discloses a phosphorus-silicon synergistic flame retardant and the preparation method and use thereof. The phosphorus-silicon synergistic flame retardant provided by the present invention has a structural general formula shown as formula I. A new type of compound containing phosphorus and silicon is prepared by the present invention using the cheap organic boron catalyst, and employing the addition reaction of diphenyl phosphine oxide and derivatives thereof with silicone containing carbon-carbon double bond. Such compounds have the properties of hydrolytic resistance, easy purification, and low synthesis cost, etc. Phosphorus and silicon elements in the molecular structures of such compounds both can act as the flame retardants solely, and meantime can work synergistically, thereby enduing the common polymeric materials with the excellent flame retardant property.

专利号:CN-104177619-B
优先权日:2014-08-04
标 题 :The synthesis method of organic silicon resin of LED encapsulation core shell structures