CAS: 15522-59-5; Tetrabutylammonium Tetraphenylborate

该化合物是一种四硝基铵盐,广泛用作电化学应用中的逐步转移催化剂和电解剂,其主要优点包括有机溶剂的高溶性,在各种条件下的稳定性和促进离子提取的效能. TBATBB因其在有机合成中提高反应率和选择性的能力而在非水系统上特别受到重视. 此外,其定义明确的电化学特性使它适合用于参考电极和导电导学研究. 化合物的强大结构确保敏感分析程序受到最小干扰,成为研究和工业应用的可靠选择.

结构式图片

相似化合物

29089-62-1 14637-34-4 25776-12-9

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号1643-19-2 四丁基溴化铵 | CAS号143-66-8 四苯硼钠

合成工艺路线路线简述

  • 合成目标产物 Tetra-N-Butylammonium Tetraphenylborate 主要起始原料 Tetrabutylammonium Bromide And Sodium Tetraphenylboron
  • (文献来源)合成步骤主要原料 Tetrabutylammonium Bromide 和 Sodium Tetraphenylboron
📜四丁基溴化铵,四苯硼钠 以 四氢呋喃 用作溶剂,化学反应 0.17H,以96%的收率获得四正丁基四苯基硼酸铵
参考文献:纳米级,刚性和疏水性阴离子的合成
标题:纳米级,刚性和疏水性阴离子的合成
摘要:大小很重要:发散的树突化策略允许合成前所未有的大,刚性和大体积阴离子(参见图片).可以调整它们的大小,密度和表面化学性质,以获得更多的疏水性,更少的亲核性和更弱的配位阴离子.
Doi:10.1002/anie.201007070

海关参考信息

专利信息


专利号:US-5693867-A
优先权日:1994-01-11
标 题:Process for isolating tetraphenylborates
发明人:BAUR RUEDIGER; FUCHS HERMANN; MACHOLDT HANS-TOBIAS; GITZEL JOERG; THEISS WILFRIED
权利人:HOECHST AG
摘要:Tetraphenylborates are obtained in an industrially advantageous grade by spray drying an organic, aqueous or organic-aqueous extract of the tetraphenylborates obtainable in the tetraphenylborates synthesis. It is advantageous to treat the specified extract prior to spray drying with pH-controlling auxiliaries and adsorbents to remove byproducts or to limit their formation. The process gives tetraphenylborates in a homogeneous technical grade, i.e. in a narrow particle size distribution and in a particular particle shape, which improves the dispersibility in the medium to be used.

专利号:CN-115087647-A
优先权日:2018-12-07
标 题:For the preparation of 4-(2-Chloro-4-methoxy-5-methylphenyl)-N-[(1S)-2-cyclopropyl-1-(3-fluoro-4-methylphenyl) ) ethyl]-5-methyl-N-prop-2-ynyl-1,3-thiazol-2-amine synthesis method

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Yuriy Zholudov, Et Al. Electrogenerated Chemiluminescence In Systems With Tetraphenylborate Anion As A Co-Reactant. Analyst. 2011 Feb 7;136(3):598-604.

合成参考文献


参考文献:10.2116/analsci.18.1047
摘要:Kudo Y, Kobayashi K, Katsuta S, Takeda Y. Ion-transfer polarographic determination of successive formation constants of rubidium and cesium complexes with benzo-15-crown-5 and -18-crown-6 ethers in nitrobenzene. Anal Sci. 2002 Sep;18(9):1047–9. doi: 10.2116/analsci.18.1047.
参考文献:10.1007/978-3-642-48910-5_4
摘要:Vanýsek P. Double Layers at L/L Interface. 1985. In: Lecture Notes in Chemistry.
参考文献:10.1007/s11270-024-07589-1
摘要:Casella C, Vadivel D, Dondi D. The Current Situation of the Legislative Gap on Microplastics (MPs) as New Pollutants for the Environment. Water Air Soil Pollut. 2024 Oct 29;235(12). doi: 10.1007/s11270-024-07589-1.
参考文献:10.1557/s43578-025-01576-w
摘要:Yang H, Li Y, Du S, Yu Z, Zhang Z, Chen Y. A facile and efficient ion sieving system for mono-/mono-valent cations built by using the K+-cross-linked graphene oxide membrane. J. Mater. Res. 2025 Apr 21;40(8):1240–51. doi: 10.1557/s43578-025-01576-w.
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