专利号:US-5693867-A 优先权日:1994-01-11 标 题:Process for isolating tetraphenylborates 发明人:BAUR RUEDIGER; FUCHS HERMANN; MACHOLDT HANS-TOBIAS; GITZEL JOERG; THEISS WILFRIED 权利人:HOECHST AG 摘要:Tetraphenylborates are obtained in an industrially advantageous grade by spray drying an organic, aqueous or organic-aqueous extract of the tetraphenylborates obtainable in the tetraphenylborates synthesis. It is advantageous to treat the specified extract prior to spray drying with pH-controlling auxiliaries and adsorbents to remove byproducts or to limit their formation. The process gives tetraphenylborates in a homogeneous technical grade, i.e. in a narrow particle size distribution and in a particular particle shape, which improves the dispersibility in the medium to be used.
专利号:CN-115087647-A 优先权日:2018-12-07 标 题:For the preparation of 4-(2-Chloro-4-methoxy-5-methylphenyl)-N-[(1S)-2-cyclopropyl-1-(3-fluoro-4-methylphenyl) ) ethyl]-5-methyl-N-prop-2-ynyl-1,3-thiazol-2-amine synthesis method
[参考文献]: Yuriy Zholudov, Et Al. Electrogenerated Chemiluminescence In Systems With Tetraphenylborate Anion As A Co-Reactant. Analyst. 2011 Feb 7;136(3):598-604.
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