CAS: 14327-04-9; 1-(Tert-Butyl)-3-Phenylthiourea

该化合物是一种有机化合物,其特征是硫尿素功能组,由碳原子双层粘结成硫磺和单层粘结成氮组成,其结构允许与生物系统的潜在互动,可在药理学方面加以探讨.此外,1-之三-丁基-3-苯基尿拉可能展示具体的生物活动,如在室内温度下对非白色固体的白色抑制剂或细胞过程的调制,使其在有机溶剂中溶解.硫尿运动的存在具有独特的化学再活性,使其在各种应用中有用,包括作为有机合成和生物研究中的试剂.安全数据应当用于处理和使用任何化学物质.

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2724-69-8 15093-36-4 2741-06-2

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    上下游产品

    phenyl isothi°Cyanate tert-butylaminetert-butylamine tert-butyl isothi°Cyanate aniline N-((tert-butylimino)methylene)aniline N-benzothiazol-2-yl-N,N'-di-tert-butyl-N''-phenyl-guanidineN-benzothiazol-2-yl-N,N'-di-tert-butyl-N''-phenyl-guanidine 1,5-Di-tert-butyl-3-phenyl-[1,3,5]triazinane-2-thione 2-hydroxypyridin

    合成工艺路线路线简述

      📜叔丁基异硫氰酸酯,苯胺 反应生成N-叔丁基-N'-苯基硫脲
      参考文献:The Mustard Oil Of Rape Seed,Allylcarbinyl Isothiocyanate,And Synthetic Isomers
      标题:The Mustard Oil Of Rape Seed,Allylcarbinyl Isothiocyanate,And Synthetic Isomers
      摘要:
      Doi:10.1021/ja01612A035

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      主要参考文献

      参考标题:Cerium Ammonium Nitrate-Catalyzed Aerobic Oxidative Coupling Of Dithiocarbamates: Facile Synthesis Of Thioureas And Bis(Aminothiocarbonyl)Disulfides
      作者:Tian-Tian Li,Xiang-Hai Song,Mei-Shuang Wang,Ning Ma
      摘要:Diverse Disubstituted And Trisubstituted Thioureas Were Synthesized By The Condensation Of Dithiocarbamate Tea (Or Dabco) Salts And Amines Using Cerium Ammonium Nitrate (Can) As A Catalyst In High Yields At Room Temperature. It Is A One-Pot Method And It Is Unnecessary To Isolate Isothiocyanates. This Reaction Probably Took Place Through Nucleophilic Addition Of Amines To Isothiocyanates, Which Were Generated By Oxidative Coupling Of Dithiocarbamates And The Following Decomposition Of Bis(Aminothiocarbonyl)Disulfides. When Secondary Amines And Cs2 Served As The Reactants, Bis(Aminothiocarbonyl)Disulfides Were Obtained Via Tandem Nucleophilic Addition/oxidative Coupling Reactions In Moderate To Excellent Yields. In All The Coupling Reactions, The Oxidant Was Air And Can Possibly Acted As An Set Catalyst.

      合成参考文献


      参考文献:10.1007/bf02839714
      摘要:Nagarajan K. Some applications of13CNMR spectroscopy in heterocyclic structure assignments. Proc. Indian Acad. Sci. (Chem. Sci.). 1985 Jul;95(1-2):9–19. doi: 10.1007/bf02839714.
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