CAS: 68039-49-6; 2,4-Dimethylcyclohex-3-Enecarbaldehyde

相似化合物

37677-14-8 89-81-6 29548-14-9

上下游产品

CAS号1118-58-7 2-甲基-1,3-戊二烯 | CAS号107-02-8 丙烯醛 | CAS号15764-16-6 2,4-二甲基苯甲醛 | CAS号67893-07-6 2-(2,4-dimethyl...

2-(2,4-Dimethylcyclohex-3-En-1-yl)Imidazolidin-4-One 以 乙醇,乙腈 作为反应溶剂,化学反应 1.0H,反应生成 2,4-二甲基-3-环己烯-1-甲醛
参考文献:Imidazolidin-4-Ones 的制备及其作为生物活性挥发性羰基衍生物缓慢释放的水解可裂解前体的评价
标题:Imidazolidin-4-Ones 的制备及其作为生物活性挥发性羰基衍生物缓慢释放的水解可裂解前体的评价
摘要:Imidazolidin-4-Ones 适用于实际应用中作为可水解裂解的前体,用于控制释放芳香醛和酮.通过在碱存在下用市售氨基酸胺处理脂肪族羰基化合物以产生非对映异构体的混合物来制备相应的前体香料.从甘氨酰胺盐酸盐与 (-)-薄荷酮反应中分离的两种非对映异构体通过柱色谱分离.异构体的绝对立体化学由核磁共振光谱确定,并由 X 射线单晶结构分析证实.在酸性条件下和质子溶剂中,两种非对映异构体缓慢异构化而不释放酮.通过从缓冲水溶液和阳离子表面活性剂乳液中的溶剂萃取以及沉积到棉花表面后的动态顶空分析来研究前体的水解.一般来说,酮类比醛类更容易释放.增加 C-5 处取代基的大小会降低溶液中和棉花表面的水解速度.基于甘氨酰胺的 Imidazolidin-4-Ones 比相应的 Oxazolidin-4-Ones 或 Oxazolidines 更有效.溶液中的释放速率,前体结构的疏水性(影响沉积)以及这
DOI:10.1002/ejoc.201200081

专利信息

专利号:US-8440608-B2
优先权日:2004-08-06
标题:Beta-substituted tetrandropyrana (on) s and method for the synthesis and the use thereof
发明人：MANE JEAN; CHANOT JEAN-JACQUES; SCHROEDER MARTIN
权利人:MANE JEAN; CHANOT JEAN-JACQUES; SCHROEDER MARTIN; MANE FILS V
摘要:The invention relates, in particular to a tetrahydropyran(on) compound which is substituted in position beta with respect to a cycle oxygen of formula (I), wherein a substituent R is a linear alkyl radical in C2:C10 including, (CH 3 ) 2 CH— or C 6 H 5 —(CH 2 ) m —, with m=0 or 1, or formula (II), wherein A is —CH 2 — or —CO—, in the form of an odorant and to a method for the synthesis thereof by reducing oxo-ester. The use of the inventive compound in composition such as perfumery compositions in the ordinary sense of the term i.e. topic, in particular cosmetic compositions and care products.

专利号:US-7501536-B2
优先权日:2005-01-19
标题 :Odorant compounds, synthesis method, and uses of said compounds
发明人：JAUNKY PIOTR; MANE JEAN; SCHROEDER MARTIN
权利人:MANE FILS V
摘要:A compound of general formula (I) with or without the double bond illustrated by the dotted line. In formula (I), X is a CHO, CH2OH, CH2OC(O)R or CH(OR)2 group, and R represents a linear or branched C1-C5 alkyl or alkenyl chain. The synthesis method for the compound, and especially the 6,8-dimethyl-non-7-enal (1) prepared by the hydroformylation of the 5,7-dimethyl-octa-1,6-diene is also disclosed, as well as compositions containing the compounds of formula (I). Due to the odorant properties thereof, the compounds are highly useful in perfumery, especially for cosmetic products and household products.

专利号:US-2006223883-A1
优先权日:2005-04-02
标题 :Novel hydroxylated enantiomers of (-) 3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan as perfuming agents derived from a fungal fermentation process.
发明人：RAHMAN ATTAUR; CHOUDHARY MOHAMMAD I; MUSHARRAF SYED G
权利人:RAHMAN ATTAUR; CHOUDHARY MOHAMMAD I; MUSHARRAF SYED G
摘要:(−) 3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan (ambrox) is a strong aromatic compound used widely in a variety of perfumery applications and is highly prized for its musky odor. We report novel polar metabolites of (−)3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan prepared by a novel process of microbial fermentation using a fungi, Fusarium lini , of unique structures that would be difficult to predict opening up the possibilities of their chemical synthesis. The polar metabolites discovered have stronger aromatic characteristics and offer a new highly prized odiferous characteristic quite different from that of the parent compound and thus can be used in the preparation of perfumes, odor-masking and other odor-management applications.

专利号:US-2012301956-A1
优先权日:2011-05-26
标 题:Novel hydroxylated enantiomers of (-) 3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan as perfuming agents derived from a fungal fermentation process
发明人：RAHMAN ATTAUR; CHOUDHARY MOHAMMAD IQBAL; MUSHARRAF SYED GHULAM; SAMI AMTUL
权利人:RAHMAN ATTAUR; CHOUDHARY MOHAMMAD IQBAL; MUSHARRAF SYED GHULAM; SAMI AMTUL
摘要:(−)3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan (ambrox) is a strong aromatic compound used widely in a variety of perfumery applications and is highly prized for its musky odor. We report novel polar metabolites of (−)3a,6,6,9a-tetramethylperhydronaphtho[2,1-b]furan prepared by a novel process of microbial fermentation using a fungi, Fusarium lini, of unique structures that would be difficult to predict opening up the possibilities of their chemical synthesis. The polar metabolites discovered have stronger aromatic characteristics and offer a new highly prized odiferous characteristic quite different from that of the parent compound and thus can be used in the preparation of perfumes, odor-masking and other odor-management applications.

专利号:WO-2018192923-A1
优先权日:2017-04-18
标题 :Alpha alkylation of aldehyde with a polycyclic olefin
发明人：QUINTAINE JULIE; MACMILLAN DAVID W C
权利人:FIRMENICH & CIE
摘要:The present invention relates to the field of organic synthesis and more specifically to the alpha alkylation of an aldehyde with a polycyclic olefin followed by a ring opening step in order to provide compound of formula (I) in the form of any one of its stereoisomers or a mixture thereof and wherein R represents a hydrogen atom or C 1-8 linear alkyl group; R 1 , R 2 , R 3 and R 4 represent, when taken separately, independently of each other, a hydrogen atom or a C 1-2 linear alkyl group or a C 3-4 linear or branched alkyl group; or R 2 and R 3 , when taken together, represent a C 4-10 linear, branched or cyclic alkanediyl group and n is 1 or 2.

专利号:US-2025186979-A1
优先权日:2022-02-18
标题 :Catalyst system and process for the preparation of alpha olefins and alpha olefin-containing products from long-chain paraffins
发明人：HANCSÓK JENO; TOMASEK SZABINA; MISKOLCZI NORBERT; HORVÃ?TH DÃ?NIEL ZOLTÃ?N; VALYON JÓZSEF; TUBA RÓBERT; LÓNYI FERENC; NAGYHÃ?ZI MÃ?RTON; VIKÃ?R ANNA; BALLA Ã?RON
权利人:PANNON EGYETEM; HUN REN TERMESZETTUDOMANYI KUTATOKOEZPONT
摘要:Our invention relates to catalysts and their use in the synthesis and conversion of alpha-olefin-containing products, essentially alpha-olefins, primarily from paraffins of renewable origin, having a carbon number of 11-45, and mixtures thereof, which mixtures contain paraffins having a carbon number of 11-45. The main steps of the process are the heterogeneous catalytic dehydrogenation of paraffin with a new zeolite-supported catalyst based on Pt, Pd or Ni, and then the conversion of the resulting olefin-containing product mixture, containing mainly straight-chain internal monoolefins, to lower homologous alpha-olefins—namely, the homogeneous or heterogeneous catalytic ethenolysis by using a ruthenium complex metathesis catalyst (i.e., metathesis using excess ethylene or ethylene metathesis), and/or tandem isomerization and metathesis reactions by using homogeneous or heterogenized homogeneous ruthenium complex metathesis catalyst in combination with a homogeneous or heterogeneous olefin isomerization catalyst (i.e., isomerization metathesis, hereinafter referred to as ISOMET), and/or tandem isomerization and ethylene metathesis by using a homogeneous or heterogenized homogeneous ruthenium complex metathesis catalyst in combination with homogeneous or heterogeneous olefin isomerization catalyst (i.e., isomerization ethylene metathesis, hereinafter referred to as ethylene ISOMET).