CAS: 661-11-0; 1-Fluoroheptane

相似化合物

463-11-6 1511-79-1 593-45-3

上下游产品

CAS号111-70-6 正庚醇 | CAS号629-04-9 1-溴庚烷 | CAS号71742-02-4 1-heptyl-2,4,6-... | CAS号24767-82-6 对甲苯磺酸正庚酯 | CAS号4282-40-0 1-碘庚烷 | CAS号1550-50-1 N,N-二甲基四氟乙胺 | CAS号13910-15-1 heptylsulfanylb... | CAS号629-06-1 1-氯庚烷 | CAS号111-68-2 正庚胺 | CAS号4282-40-0 1-碘庚烷 | CAS号18589-29-2 2-Iodoheptane | CAS号629-06-1 1-氯庚烷 | CAS号1001-89-4 2-氯庚烷 | CAS号629-04-9 1-溴庚烷 | CAS号1974-04-5 2-溴庚烷

📜正庚醇置于二乙胺基三氟化硫体系中,用 二氯甲烷 作为反应溶剂,化学反应生成 1-氟庚烷
参考文献:烷基氟化物与三卤化硼或四卤化钛之间的卤素交换反应.从烷基氟化物方便地合成卤代烷
标题:烷基氟化物与三卤化硼或四卤化钛之间的卤素交换反应.从烷基氟化物方便地合成卤代烷
摘要:描述了一种使用市售的三卤化硼和四卤化钛将氟代烷烃转化为其相应的氯代,溴代和碘代烷烃的简单有效的方法.
DOI:10.1016/0022-1139(94)03193-4

专利信息

专利号:US-7767826-B2
优先权日:2007-10-05
标题 :Process for the synthesis of L-(+)-ergothioneine
发明人：TRAMPOTA MIROSLAV
权利人:PHARMATECH INTERNATIONAL INC
摘要:This invention relates to a novel process for the preparation of optically pure L-(+)-ergothioneine. The process for the chemical synthesis of L-ergothioneine comprises steps which consist of reacting L-histidine alkyl ester with an acid halide, chloroformate or pyrocarbonate in the presence of a base, hydrolysis of the alkyl-(S,Z)-2,4,5-triamidopent-4-enoate to obtain a (S)-alkyl 2,5-diamido-4-oxopentanoate, acid catalyzed hydrolysis of the (S)-alkyl 2,5-diamido-4-oxopentanoate followed by reaction with a metal thiocyanate to obtain the thiohistidine, protection of the sulfur of thiohistidine as the tert-butyl thioether, dialkylation of the primary amine to obtain a tertiary amine, quaternization of the tertiary amine, and removal of the protecting group to obtain the desired (S)-3-(2-mercapto-1H-imidazol-5-yl)-2-(trialkylammonio)propanoate (I). This process affords a better yield and is capable of practical application at large scale.

专利号:US-2009093642-A1
优先权日:2007-10-05
标 题 :Process for the synthesis of l-(+)-ergothioneine

专利号:WO-2009045413-A1
优先权日:2007-10-05
标 题 :Process for the synthesis of l-(+)-ergothioneine

专利号:US-7307177-B2
优先权日:2004-12-17
标题:Metallocene complexes, their synthesis and use in catalyst systems for olefin polymerization
发明人：HUANG LEGAL REPRESENTATIVE JIL; CANICH JO ANN M; COKER CATALINA L
权利人:EXXONMOBIL CHEM PATENTS INC
摘要:A metallocene complex is represented by the the formulan n(C p R 5 ) n MX k n nwhere C p (each occurrence) is a cyclopentadienyl group; each of the five R substituents on the or each cyclopentadienyl group is independently selected from hydrogen, C 1 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure, and SiR′ 2 NR″ 2 where each of the two R′ substituents is independently selected from hydrogen, C 1 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R′ substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure, and each of the two R″ substituents is independently selected from C 2 to C 30 substituted or unsubstituted hydrocarbyl, halohydrocarbyl, silylhydrocarbyl or silylhalohydrocarbyl, wherein two adjacent R″ substituents may be joined to form part of a saturated, partially unsaturated or aromatic monocyclic or polycyclic ring structure; n is 1 or 2; M is a metal of valence m from Groups 4 to 11 of the Periodic Table of Elements, k is equal to m minus n and the or each X substituent is a univalent anionic ligand, or two X substituents are joined and bound to the metal atom to form a metallocycle ring, or two X substituents are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand, provided that at least one R substituent on the or one cyclopentadienyl group is SiR′ 2 NR″ 2 , provided that at least one R substituent on at least one C p is SiR′ 2 NR″ 2 and provided that one or the C p may be bridged by a bridging group to another C p group, or a heteroatom containing group, where the bridging group replaces one R group on the C p group(s) or a hydrogen on a heteratom containing group.

专利号:US-7312347-B2
优先权日:2005-09-22
标题 :Substituted optically active disphosphine compound
发明人：FUJIWARA TAKAHIRO; YOKOZAWA TOHRU
权利人:TAKASAGO PERFUMERY CO LTD
摘要:Provided is a method for producing an optically active compound, in more detail, for producing an optically active compound by asymmetric hydrogenation in a high yield and asymmetric yield. The present invention also provides a catalyst for asymmetric synthesis for the above production method, especially a catalyst for asymmetric hydrogenation, containing a transition metal complex. Further, the present invention provides a new diphosphine compound useful as a ligand of the above transition metal complex and a new transition metal complex containing the above diphosphine compound. n The present invention relates to a diphosphine compound represented by the following formula (1): n na transition metal complex using the compound, a catalyst for asymmetric synthesis comprising the above transition metal complex and a method for producing an optically active compound using the above catalyst for asymmetric synthesis.

专利号:US-7754889-B2
优先权日:2004-03-29
标题 :Optically active transition metal-diamine compound and process for producing optically active alcohol with the same
发明人：AMANO AKIRA; IGARASHI DAISUKE; SAYO NOBORU
权利人:TAKASAGO PERFUMERY CO LTD
摘要:The present invention provides a water-soluble transition metal-diamine complex which can be easily separated from reaction products through liquid separation, etc. and is recycleable; an optically active diamine compound constituting the ligand of the complex; and a catalyst for asymmetric synthesis which comprises these. The present invention relates to a water-soluble optically active transition metal-diamine complex represented by the formula (2): n n[wherein R 1 and R 2 each represents hydrogen, a hydrocarbon group, —SO 2 R 13 (wherein R 13 is a hydrocarbon group, substituted amino, etc.), etc.; R 3 to R 12 each represents hydrogen, a hydrocarbon group, alkoxy, substituted amino, etc.; M represents a transition metal; X represents halogen; L represents a ligand; and * indicates an asymmetric carbon atom; provided that at least one of R 3 to R 7 and R 8 to R 12 is substituted amino], a catalyst for asymmetric synthesis containing the complex, and a process for producing an optically active alcohol, which comprises using the catalyst to asymmetrically reduce a ketone.