📜二苯甲酮吖嗪置于溶剂黄146,铂,Mercury(II) Oxide,苯体系中,化学反应生成 1,1,2,2-四苯基乙烷 参考文献:Azo-Bis-Diphenylmethane And The Decomposition Of Aliphatic Azo Compounds. The Diphenylmethyl Radical1 标题:Azo-Bis-Diphenylmethane And The Decomposition Of Aliphatic Azo Compounds. The Diphenylmethyl Radical1 摘要: DOI:10.1021/ja01614A029
专利号:US-9929363-B2 优先权日:2013-08-05 标题:Composition and synthesis of aggregation-induced emission materials 发明人:TANG BENZHONG; Xie ni; LAM WING YIP 权利人:UNIV HONG KONG SCI & TECH 摘要:The present subject matter relates to compositions containing and synthesis of fluorescent materials e made from tetraphenylethylene (TPE) derivative compounds exhibiting aggregation induced emission (AIE) properties. Further contemplated herein are applications for TPE derivative compounds such as electroluminescent devices since they have a high efficiency, low turn on voltage, and excellent brightness. Additionally, application of TPE derivatives exhibiting AIE properties in various fields such as OLEDs, fingerprinting and forensic technology, and various other biological and industrial sectors are discussed.
专利号:US-2014228554-A1 优先权日:2011-03-18 标 题:Synthesis of new fucose-containing carbohydrate derivatives 发明人:CHAMPION ELISE; DEKANY GYULA; HEDEROS MARKUS; AGOSTON KAROLY 权利人:GLYCOM AS; GLYCOM AS 摘要:A method for the synthesis of a fucooligosaccharide glycosides by reacting a fucosyl donor with H-A-R 1 or a salt thereof, wherein A and R 1 are as defined herein, under the catalysis of an enzyme capable of transferring fucose is provided. The fucooligosaccharid glycoside compounds, or derivatives thereof, their use in the manufacture of human milk oligosaccharides, and a method of manufacture of human milk oligosaccharides, are also provided.
专利号:US-6040480-A 优先权日:1997-04-07 标题 :Asymmetric synthesis of benzoxazinones 发明人:PIERCE MICHAEL E; CHEN CHENG Y; CHOUDHURY ANUSUYA; RADESCA LILIAN A; TAN LUSHI; ZHAO DALIAN 权利人:DU PONT PHARM CO 摘要:The present invention provides novel methods for the asymmetric synthesis of (S)-6-chloro-4-cyclopropylethynyl-4-trifluoromethyl-1,4-dihydro-2H-3,1-benzoxazin-2-one of formula (VI-i) which is useful as a human immunodeficiency virus (HIV) reverse transcriptase inhibitor.
专利号:US-2014303363-A1 优先权日:2011-12-09 标题 :Preparation and Use of Isolactosamine and Intermediates therefor 发明人:HEDEROS MARKUS; RISINGER CHRISTIAN; BOUTET JULIEN; DEKANY GYULA 权利人:GLYCOM AS 摘要:The invention relates to providing isolactosamine (Galβ1-3GlcNH 2 , formula 1) and salts thereof in the form of either anomer or mixture thereof, as well as hydrates or solvates of the free base and salts thereof. The synthesis of isolactosamine and its use in the synthesis of lacto-N-biose containing oligosaccharides are also disclosed.
专利号:US-10968308-B2 优先权日:2017-11-07 标 题 :Preparation method of epoxy compound having alkoxysilyl group, epoxy compound having alkoxysilyl group, composition comprising the same, and use thereof 发明人:CHUN HYUN AEE; KIM YUN JU; PARK SOOK YEON; PARK SU JIN 权利人:KOREA INST IND TECH 摘要:Provided are a preparation method of an epoxy compound having an alkoxysilyl group in which an increase in the epoxy equivalent weight (EEW) of the epoxy compound is minimized because alkoxysilylation occurs through a simple one-step reaction using a hydroxyl group formed during the synthesis of the epoxy compound, an epoxy compound having an alkoxysilyl group prepared by the method, a composition comprising the same, and a use thereof. The method includes the reaction of an epoxy compound having a hydroxyl group with an isocyanate alkoxysilane in the presence of amine-based base catalyst, wherein the epoxy compound having an alkoxysilyl group has a mole ratio of [epoxide group]:[alkoxysilyl group] of n:1 ranging from 2:1 to 10:1, and an EEW increase of the epoxy compound having an alkoxysilyl group is less than 260/n. The epoxy compound has good physical properties when being cured.
专利号:US-7803959-B2 优先权日:2006-04-05 标 题 :Synthesis of aromatic silicon-containing compounds 发明人:COGGAN JENNIFER A; BENDER TIMOTHY P; TOTH ALAN EDWARD JOHN 权利人:XEROX CORP 摘要:Methods are provided for preparing aromatic silicon-containing compounds. The methods include providing an aromatic starting material; reacting the aromatic starting material with a base to form an aromatic salt; and reacting the aromatic salt with a halo-alkylene-silane to form an aromatic silicon-containing compound. Compositions prepared by these methods, protective layers that include hydrolysis and condensation products of such compositions, electrophotographic photoreceptors that include such protective layers, and image forming apparatuses that include such electrophotographic photoreceptors are also provided. In addition, method for preparing electrophotographic photoreceptors that include protective layers including hydrolysis and condensation products of aromatic silicon-containing compounds prepared by the methods for preparing aromatic silicon-containing compounds are provided.
摘要:Chessum, N.; Couty, S.; Jones, K., Science of Synthesis, (2009) 48, 330. 摘要:Zaidlewicz, M.; Krzemiński, M. P.; Dzieleńdziak, A., Science of Synthesis, (2009) 48, 382.