CAS: 2393-18-2; 3-(4-Aminophenyl)Acrylic Acid

上下游产品

CAS号619-89-6 4-硝基肉桂酸 | CAS号162936-33-6 tert-butyl 4-am... | CAS号943-80-6 4-氨基-L-苯丙氨酸 | CAS号556-18-3 4-氨基苯甲醛 | CAS号105-53-3 丙二酸二乙酯 | CAS号953-26-4 4-硝基肉桂酸乙酯 | CAS号7647-01-0 盐酸 | CAS号34633-09-5 4-碘肉桂酸 | CAS号459-32-5 对氟肉桂酸 | CAS号65198-02-9 4-氨基肉桂酸甲酯 | CAS号2393-17-1 3-(4-氨基苯基)丙酸 | CAS号2019-34-3 3-(4-氯苯基)丙酸

📜对硝基肉桂酸置于甲酸,镍体系中,用 甲醇 用作溶剂,化学反应 0.17H,以90%的收率获得胺桂皮酸
参考文献:镍催化的甲酸还原.减少硝基化合物的选择性方法
标题:镍催化的甲酸还原.减少硝基化合物的选择性方法
摘要:摘要 使用甲酸和雷尼镍以非常好的收率将脂肪族和芳香族硝基化合物选择性还原为其相应的氨基衍生物.发现该系统与多种敏感官能团兼容,例如卤素,-Oh,-och3,-Cho,-Coch3,-Coc6H5,-Cooh,-Cooc2H5,-Conh2,-Cn,-Ch=ch-Cooh,-Nhcoch3.不仅可以用 Hcooh 还可以用 Hcoonh4 进行还原.
Doi:10.1080/00397910008087439

专利信息

专利号:US-5527824-A
优先权日:1985-07-22
标题 :Substituted Di-T-Butlyphenols useful for inhibiting leukotriene synthesis
发明人：SCHERRER ROBERT A
权利人:RIKER LABORATORIES INC
摘要:Substituted Di-T-Butylphenols useful for inhibiting the synthesis of leukotrienes are disclosed.

专利号:US-6764842-B2
优先权日:2001-03-28
标题 :Enantioselective bioreduction for the preparation of integrin receptor antagonist intermediates
发明人：STURR MICHAEL G; BOYD RUSSELL FIELDON; GBEWONYO KODZO; NTI-GYABAAH JOSEPH; POLLARD DAVID J; MCWILLIAMS JAMES CHRISTOPHER; TELARI KATHLEEN A
权利人:MERCK & CO INC
摘要:The present invention relates to a novel enantioselective bioreduction using a yeast microorganism for the preparation of the chiral allylic alcohols of structural formula I (R is hydrogen or methyl) which are useful in the asymmetric synthesis of integrin αvβ 3 receptor antagonists.

专利号:RU-2135478-C1
优先权日:1993-04-28
标题:Heterocyclic compounds, method of their synthesis, pharmaceutical composition and method of treatment

专利号:US-8785655-B2
优先权日:2009-02-25
标 题:Ionic liquid solvents
发明人：GATHERGOOD NICHOLAS; PEGOT BRUCE; BEADHAM IAN; GURBISZ MONIKA; GHAVRE MUKUND D; MORRISSEY SAIBH
权利人:GATHERGOOD NICHOLAS; PEGOT BRUCE; BEADHAM IAN; GURBISZ MONIKA; GHAVRE MUKUND D; MORRISSEY SAIBH; UNIV DUBLIN CITY
摘要:A chiral ionic compound comprising an alkyl substituted imidazolium or pyridinium cationic core having an alkyl ester side chain (-alkyl-C(O)O—) directly linked to the core and an associated counter anion, characterized in that the —O— atom of the ester side chain is linked to an alpha, a beta or a gamma hydroxycarboxylic acid functionality via the alpha, beta or gamma hydroxy of the acid functionality and the hydroxycarboxylic acid functionality has at least one asymmetric carbon, or characterized in that an —Nâ•? atom of the alkyl substituted imidazolium or pyridinium cationic core is substituted with an alpha, a beta or a gamma hydroxy group of a alpha, a beta or a gamma hydroxycarboxylic acid functionality and the hydroxycarboxylic acid functionality has at least one asymmetric carbon. The chiral ionic liquids (CILs) may be used as novel solvents, in particular for organic synthesis. The CILs have the potential to induce asymmetry into substrates or catalysts in a variety of organic transformations. A number of the compounds have low antimicrobial and low antifungal toxicities and are aso biodegradable CILs.