专利号:US-10010875-B2 优先权日:2014-10-30 标题 :Method for preparing copper-zinc-based catalyst used in synthesis of methanol through CO2 hydrogenation 发明人:YU YANG; HAO AIXIANG; CHEN HAIBO; WEI SHIXIN; YIN YUSHENG; XIE TIANMING; HE JIAN; MAO CHUNPENG; TAN JIEDONG 权利人:CHINA PETROLEUM & CHEM CORP; RES INSTITUTE OF NANJING CHEMICAL INDUSTRY GR; RES INST NANJING CHEMICAL IND GROUP 摘要:Disclosed is a method for preparing a copper-zinc-based catalyst used in synthesis of methanol through CO 2 hydrogenation, and ultrasonic waves are used for control over crystalline phase's composition of a catalyst precursor. Further related to is a catalyst prepared by such a method. An amount of aurichalcite in an active catalyst precursor can be improved through the method, and the specific surface area of the metal copper in a reduced state catalyst is high. The catalyst presents high activity and hydrothermal stability, and promotes high space time yield of methanol in the synthesis of methanol through CO 2 hydrogenation.
专利号:US-2015105479-A1 优先权日:2012-04-24 标 题:Catalytically active body for the synthesis of dimethyl ether from synthesis gas 发明人:SCHÄFER ALEXANDER; FEYEN MATHIAS; PARVULESCU ANDREI-NICOLAE; Müller Ulrich; SCHAACK BERND BASTIAN 权利人:BASF SE 摘要:The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a methanol active component and an acid component comprising a zeolitic material being crystallized by means of one or more alkenyltrialkylammonium cation R 1 R 2 R 3 R 4 N + -containing compounds as structure directing agent. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for the preparation of dimethyl ether from synthesis gas.
专利号:US-2024075466-A1 优先权日:2021-04-09 标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites 发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE 权利人:UMICORE AG & CO KG 摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.
专利号:US-9393555-B2 优先权日:2012-02-15 标题:Catalytically active body for the synthesis of dimethyl ether from synthesis gas 发明人:SCHÄFER ALEXANDER; VON FEHREN THORSTEN; MADON ROSTAM 权利人:BASF SE 摘要:The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a defined particle size distribution. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for preparation of dimethyl ether from synthesis gas.
专利号:US-10618855-B2 优先权日:2016-06-07 标题:Catalyst and method for synthesis of aromatic hydrocarbons through direct conversion of synthesis gas 发明人:PAN XIULIAN; YANG JUNHAO; JIAO FENG; ZHU YIFENG; BAO XINHE 权利人:DALIAN INST CHEM & PHYSICS CAS 摘要:Synthesis of aromatic hydrocarbons from synthesis gas in a fixed bed or a moving bed reactor loaded with a composite catalyst comprising Catalyst Component A and Catalyst Component B mixed via a mechanical mixing mode, wherein the active ingredient of the Catalyst Component A is active metal oxides; and the Catalyst Component B is one or both of ZSM-5 zeolite and metal modified ZSM-5; the pressure of the synthesis gas is 0.1-6 MPa; the reaction temperature is 300-600° C.; and the space velocity is 500-8000 h −1 . The reaction process has a high product yield and selectivity, with the selectivity of aromatics reaching 50-85%, while the selectivity of the methane byproduct is less than 15%.
专利号:US-9610568-B2 优先权日:2012-02-15 标题 :Catalytically active body for the synthesis of dimethyl ether from synthesis gas 发明人:SCHÄFER ALEXANDER; VON FEHREN THORSTEN; MADON ROSTAM 权利人:BASF SE 摘要:The invention relates to a catalytically active body for the synthesis of dimethyl ether from synthesis gas. In particular, the invention relates to an improved catalytically active body for the synthesis of dimethyl ether, whereby the components of the active body comprise a defined particle size distribution. Furthermore, the present invention concerns a method for the preparation of a catalytically active body, the use of the catalytically active body and a method for preparation of dimethyl ether from synthesis gas.
参考文献:10.1002/jemt.21041 摘要:Maghraoui S, Ayadi A, Audinot JN, Ben Ammar A, Jaafoura MH, El Hili A, Migeon HN, Tekaya L. Role of parietal and principal gastric mucosa cells in the phenomenon of concentration of aluminum and indium. Microsc Res Tech. 2012 Feb;75(2):182–8. doi: 10.1002/jemt.21041.