CAS: 100884-80-8; Adamantane-1,3,5,7-Tetracarboxylic Acid

相似化合物

39269-10-8 828-51-3 75534-58-6

上下游产品

tetramethyl adamantane-2,6-dione-1,3,5,7-tetracarboxylate tetramethyl adamantane-1,3,5,7-tetracarboxylate 1-Adamantanecarboxylic acid adamantane-1,3-dicarboxylic acid 1,3,5,7-Tetrabenzoyl-adamantan 1,3,5,7-tetrakis(hydroxymethyl)adamantane 1,3,5,7-tetramethyl-adamantane 1,3,5,7-tetrakis-hydroxymethyl-adamantane

📜1,3,5,7-四苯基金刚烷置于ruthenium(III) Chloride Trihydrate,水,高碘酸体系中,用 四氯化碳,乙腈 用作溶剂,化学反应 168.0H,反应生成1,3,5,7-金刚烷四羧酸
参考文献:发色团倍增使四聚五苯中单线态裂变后的激子离域和三线态扩散成为可能.
标题:发色团倍增使四聚五苯中单线态裂变后的激子离域和三线态扩散成为可能.
摘要:四聚并五苯 (Pt) 已被用来探索激子离域对单线态裂变 (Sf) 的影响.首次在 Sf 后观测到通过分子内三重态扩散的三重态去相关.根据去相关步骤的速率和激活势垒,使用瞬态吸收光谱检查 Pt 及其二聚体等效 Pd 的不同去相关机制(三重态扩散与结构变化).使用四氰基对醌二甲烷(tcnq)猝灭通过 Sf 形成的三重态激子的电荷分离实验表明,增强的系间窜越(即自旋催化)是定量收获 Sf 产物的一个被广泛低估的障碍.强调了去相关三重态的空间分离的重要性,并且提供了去相关三重态对状态由每个分子的两个(t1)状态组成的独立证明.
Doi:10.1002/anie.201907221

专利信息

专利号:US-2022297083-A1
优先权日:2019-08-27
标 题 :Continuous Synthesis Of Porous Coordination Polymers In Supercritical Carbon Dioxide
发明人：RASMUSSEN ELIZABETH G; KRAMLICH JOHN C; NOVOSSELOV IGOR V
权利人:UNIV WASHINGTON
摘要:This disclosure relates generally relates to methods and systems useful for continuous synthesis of materials in super-critical carbon dioxide (sCO 2 ). More particularly, this disclosure relates to methods and systems useful for continuous synthesis of coordination polymers, such as metal-organic frameworks (MOFs) and/or covalent organic frameworks (COFs), in sCO 2 .

专利号:EP-3429963-B1
优先权日:2016-03-17
标题 :Synthesis of transition-metal adamantane carboxylic salts and oxide nanocomposites