CAS: 6731-36-8; 1,1-Di-(Tert-Butylperoxy)-3,3,5-Trimethylcyclohexane

该化合物是一种有机过氧化物,通常用作聚合工艺中的激进启动剂,该化合物的特性是,环环中附着的两个异丁基过氧基组,该环被进一步替换为三个甲基组,造成其不育和稳定性;它一般没有颜色,可变成黄色的液体或固体,视温度和纯度而定;过氧化物功能组的存在使其反应性,特别是在热度下或催化剂的存在下,导致产生自由基质;这种特性在各种工业应用中被利用,包括塑料和树脂的生产;然而,由于其反应性,必须小心处理,因为如果不妥善储存和使用,它可能会造成燃烧和爆炸的危险;此外,在实验室或工业环境中与该物质合作时,必须考虑到其环境影响和安全数据.

结构式图片

欧盟法规

CLHactivityREACH注册ECHA物质ECHA物质C&L通报CoRAP评估清单REACH预注册

上下游产品

CAS号75-91-2 叔丁基过氧化氢 | CAS号873-94-9 3,3,5-三甲基环己酮

合成工艺路线路线简述

    叔丁基过氧化氢,3,3,5-三甲基环己酮置于硫酸体系中,用 水 作为反应溶剂,以63%的收率获得产物1,1-二叔丁基过氧化-3,3,5-三甲基环己烷
    参考文献:Method For The Production Of Organic Peroxides By Means Of A Microreaction Technique
    标题:Method For The Production Of Organic Peroxides By Means Of A Microreaction Technique
    摘要:这项发明提供了一种通过至少一个静态微混合器和执行该过程的装置,高效可靠地制备有机过氧化物,优选地为二烷基过氧化物,过氧化羧酸,过氧化羧酸酯,二酰过氧化物,过氧化碳酸酯,过氧二碳酸酯,酮过氧化物和过氧化物的过氧醚的方法.

    海关参考信息

    专利信息


    专利号:US-9969823-B1
    优先权日:2011-09-01
    标题 :Synthesis and polymerization of vinyl triazolium ionic liquids
    发明人:LUEBKE DAVID; NULWALA HUNAID; MATYJASZEWSKI KRZYSZTOF; ADZIMA BRIAN
    权利人:US ENERGY; THE US DEPARTMENT OF ENERGY
    摘要:Herein, we describe polymerized ionic liquids, demonstrate the synthesis of polymerized ionic liquids, and demonstrate the polymerization of triazolium monomers. One embodiment shows the polymeriazation of the triazolium monomers with bis(trifluoromethanesulfonyl)imide anions. In another embodiment we show the feasibility of copolymerizing with commodity monomers such as styrene using free radical polymerization techniques.

    专利号:US-8933181-B2
    优先权日:2006-10-06
    标题:Branched polymers and methods for their synthesis and use
    发明人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA
    权利人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA; BRIDGESTONE CORP
    摘要:Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.

    专利号:US-7271231-B2
    优先权日:1995-01-24
    标 题 :Polymerization of olefins
    发明人:BROOKHART MAURICE S; JOHNSON LYNDA KAYE; KILLIAN CHRISTOPHER MOORE
    权利人:DU PONT
    摘要:Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear α-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected α-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected α-diimine nickel complexes with ethylene.

    专利号:US-2008274074-A1
    优先权日:2005-11-24
    标题:Method for Controlled Free Radical Polymerization or Copolymerization of Methacrylic and/or Methacrylate Monomers or Exclusively Methacrylic and/or Methacrylate Copolymers
    发明人:COUTURIER JEAN-LUC; GUILLANEUF YOHANN; BERTIN DENIS; GIGMES DIDIOR
    权利人:ARKEMA FRANCE
    摘要:The invention relates to a method for the polymerization of one or more methacrylate and/or methacrylic monomers, for the synthesis of methacrylate or methacrylic polymers or of exclusively methacrylic and/or methacrylate copolymers, comprising a step of bringing said monomer(s) into contact with one at least of the compounds of formula (I) and (II) below: n n n n n n n n n n in which:n R 1 and R 2 may represent a phenyl group, R 3 and R 4 may together form an â•?N-phenyl group, Z represents a group of formula —CR 8 R 9 R 10 , in which R 8 and R 9 may represent methyl groups and R 10 may represent a —COO-phenyl group.

    专利号:US-9867899-B2
    优先权日:2010-05-24
    标题 :Reinforced adhesive complex coacervates and methods of making and using thereof
    发明人:STEWART RUSSELL J
    权利人:UNIV UTAH RES FOUND
    摘要:Described herein is the synthesis of reinforced adhesive complex coacervates and their use thereof. The reinforced adhesive complex coacervates are composed of (a) at least one polycation, (b) at least one polyanion, and (c) a reinforcing component. The adhesive complex coacervates described herein can be subsequently cured to produce strong, cohesive adhesives. The reinforced adhesive complex coacervates have several desirable features when compared to conventional adhesives. The reinforced adhesive complex coacervates are effective in wet or underwater applications. The reinforced adhesive complex coacervates described herein, being phase separated from water, can be applied underwater without dissolving or dispersing into the water. The reinforced adhesive complex coacervates have numerous biological applications as bioadhesives and bioactive delivery devices. In particular, the reinforced adhesive complex coacervates described herein are particularly useful in underwater applications and situations where water is present such as, for example, wet tissues in physiological conditions.

    专利号:US-7807764-B2
    优先权日:2003-08-27
    标 题:Composition and process for the controlled synthesis of block copolymers
    发明人:WERMTER HENDRIK; SIMON DIRK; PFAENDNER RUDOLF
    权利人:CIBA SC HOLDING AG
    摘要:The present invention relates to a polymerizable composition comprising a) at least one ethylenically unsaturated monomer and b) at least one hydroxylamine of high molecular weight, preferably a long chain alkyl substituted hydroxylamine. Further aspects of the present invention are a process for polymerizing ethylenically unsaturated monomers, and the use of high molecular weight hydroxylamines for controlled polymerization.
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    合成参考文献


    摘要:S120 | DUSTCT2024 | Substances from Second NORMAN Collaborative Dust Trial | DOI:10.5281/zenodo.13835254
    摘要:Eisei Shikenjo Hokoku. Bulletin of the Institute of Hygienic Sciences., (110)(42), 1992 []
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