专利号:US-11848117-B2 优先权日:2017-12-06 标题:Thin and uniform silver nanowires, method of synthesis and transparent conductive films formed from the nanowires 发明人:HU YONGXING; LI YING-SYI; YANG XIQIANG; ANG JING SHUN; VIRKAR AJAY 权利人:C3 NANO INC 摘要:Highly uniform and thin silver nanowires are described having average diameters below 20 nm and a small standard deviation of the diameters. The silver nanowires have a high aspect ratio. The silver nanowires can be characterized by a small number of nanowires having a diameter greater than 18 nm as well as with a blue shifted narrow absorption spectrum in a dilute solution. Methods are described to allow for the synthesis of the narrow uniform silver nanowires. Transparent conductive films formed from the thin, uniform silver nanowires can have very low levels of haze and low values of ΔL*, the diffusive luminosity, such that the transparent conductive films can provide little alteration of the appearance of a black background.
专利号:US-11760707-B2 优先权日:2019-11-13 标题 :Process for the synthesis of 2,3,3,3-tetrafluoropropene 发明人:ZHOU CHANGYUE; WANG YONG 权利人:FUJIAN YONGJING TECH CO LTD 摘要:The present invention pertains to a novel process of manufacturing the compound 2,3,3,3-tetrafluoropropene (1234yf). The compound 1234yf is the newest refrigerant with zero OPD (Ozone Depleting Potential) and zero GWP (Global Warming Potential). Thus, the invention relates to a process, involving a carbene generation route, for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), of the compound 243db (2,3-dichloro-1,1,1-trifluoropropane), and optionally of the compound 2-chloro-1,1,1-trifluoropropene (1233xf) via carbene route and compound 243db (2,3-dichloro-1,1,1-trifluoropropane). The invention also relates to a process for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), wherein the compound 243db (2,3-dichloro-1,1,1-trifluoropropane) serves as a starting material, for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf). Further, the invention relates to a process for the manufacture of the compound 2,3,3,3-tetrafluoropropene (1234yf), and of the compound 243db (2,3-dichloro-1,1,1-trifluoropropane), the initial starting materials are selected from the group consisting of com-pound 123 (2,2-dichloro-1,1,1-trifluoroethane), compound 124 (2-chloro-1,1,1,2-tetrafluoroethane), and compound 125 (pentafluoroethane).
专利号:EP-3567040-B1 优先权日:2013-06-24 标 题 :Method for the preparation of intermediates useful for the synthesis of [1,2,4]-triazolo[4,3-a]pyridines
专利号:US-4684724-A 优先权日:1981-12-25 标题:4-Cyano-2-azetidinones and production thereof 发明人:OCHIAI MICHIHIKO; KISHIMOTO SHOJI; MATSUO TAISUKE 权利人:TAKEDA CHEMICAL INDUSTRIES LTD 摘要:4-Cyano-2-azetidinone derivatives represented by the formula ##STR1## wherein R 1 is an amino group which may be acylated or protected, X is a hydrogen atom or a methoxy group and W is a hydrogen atom or a sulfo group, and methods of producing the same, for example, as represented by ##STR2## wherein R 2 is an acylated or protected amino group, Y is a halogen atom or a group having the formula --OCOR 3 , --SCOR 3 or --S(O) n --R 3 (R 3 being a hydrocarbyl group and n an integer 1 or 2), R 4 is an amino group which may be acylated or protected and X is as defined above. Compounds [I] are useful as advantageous intermediates for the synthesis of optically active 4-substituted-2-azetidinone derivatives, and, when W=SO 3 H, [I] are also useful as antimicrobial agents and as beta-lactamase inhibitors.
专利号:EP-3567040-A1 优先权日:2013-06-24 标题 :Method for the preparation of intermediates useful for the synthesis of [1,2,4]-triazolo[4,3-a]pyridines
专利号:US-2021139397-A1 优先权日:2019-11-13 标题:Process for the synthesis of 2,3,3,3-tetrafluoropropene
参考文献:10.1007/s11743-004-0323-9 摘要:González‐Pérez A, Ruso JM, Prieto G, Sarmiento F. The self‐aggregation of sodium perfluorooctanoate in aqueous solution at different temperatures. J Surfact & Detergents. 2004 Oct;7(4):387–95. doi: 10.1007/s11743-004-0323-9. 参考文献:10.1007/s11426-022-1445-2 摘要:Shao J, Li D, Shi J, Ma C, Wang Y, Liu X, Jiang X, Hao M, Zhang L, Liu C, Jiang Y, Wang Z, Zhong Y, Liu SF, Mai Y, Liu Y, Zhao Y, Ning Z, Wang L, Xu B, Meng L, Bian Z, Ge Z, Zhan X, You J, Li Y, Meng Q. Recent progress in perovskite solar cells: material science. Sci. China Chem. 2022 Dec 02;66(1):10–64. doi: 10.1007/s11426-022-1445-2. 参考文献:10.1007/s10854-023-10186-3 摘要:Li J, Xiang P, Tan X, Li B, Zhang K, Zhu Y, Ren Y, Chen X. 3,5-dichlorobenzylamine lead high-performance and stable 2D/3D perovskite solar cells. J Mater Sci: Mater Electron. 2023 Mar;34(9). doi: 10.1007/s10854-023-10186-3. 参考文献:10.1007/s12034-023-03020-3 摘要:Zavahir N, Jayalath IN, Maddumaarachchi M. Effect of cationic surfactant tail length on the emulsion gel polymerization of styrene. Bull Mater Sci. 2023 Aug 26;46(3). doi: 10.1007/s12034-023-03020-3. 参考文献:10.1007/s42452-023-05596-1 摘要:Mbumba MT, Mahona J, Kihedu J, Chang’waro SK, John GR. A-site cation engineering of cesium and MAPb0.5Sn0.5I3 perovskite: the properties and optoelectronic performance analysis using DFT calculations. SN Appl. Sci. 2023 Nov 24;5(12). doi: 10.1007/s42452-023-05596-1.