正戊基溴化镁置于potassium Acetate体系中,用 乙醚 用作溶剂,化学反应 2.5H,反应生成1-辛烯-3-醇乙酸酯 参考文献:Morimoto,Takashi; Machida,Toshinori; Hirano,Masao,Journal Of The Chemical Society. Perkin Transactions Ii,1988,P. 909-914 标题:Morimoto,Takashi; Machida,Toshinori; Hirano,Masao,Journal Of The Chemical Society. Perkin Transactions Ii,1988,P. 909-914
专利号:US-8263774-B2 优先权日:2009-09-03 标题:Quinoline-oxazoline compounds and their use in oxidation synthesis 发明人:SIGMAN MATTHEW SCOTT; MICHEL BRIAN WILLIAM 权利人:SIGMAN MATTHEW SCOTT; MICHEL BRIAN WILLIAM; UNIV UTAH RES FOUND 摘要:A quinoline-oxazoline compound having the formula: n n n n n n n n n n n n where one of X 1 and X 2 is N and the other is C and one of R1, R2 and R3 is Z wherein Z is an oxazoline radical having the formula n n n n n nsuch that when X 1 is N R2 is Z and R1 is absent, and when X 2 is N either R1 or R3 is Z and R2 is absent. R1 and R3 through R12 are independently H or a pendant moiety which does not interfere with coordination of either N in the quinoline compound with a coordination center. These compounds can be complexed with a suitable coordination center such as catalytically active palladium and can be highly useful in catalytically oxidizing alkenes with high regioselectivity.
专利号:US-2014114086-A1 优先权日:2012-10-22 标 题:Clinprost, Isocarbacyclin And Analogs Thereof And Methods Of Making The Same 发明人:CROATT MITCHELL 权利人:UNIV NORTH CAROLINA AT GREENSBORO 摘要:In one aspect, methods of synthesizing clinprost, isocarbacyclin and analogs thereof are described herein which, in some embodiments, permit an abbreviated synthetic pathway in comparison to one or more prior synthetic methods. By providing a compact synthetic scheme, methods described herein can reduce cost, waste and time of clinprost and isocarbacyclin synthesis while facilitating the development and investigation of analogs of these compounds.
专利号:US-4294727-A 优先权日:1979-05-05 标 题 :Perfume composition containing 4,5-dioxa-5-alkyl-tricyclo[7.2.1.0 2,8 ]dodec-10-enes and its use as an odorant 发明人:CONRAD JENS; UPADEK HORST; BRUNS KLAUS 权利人:HENKEL KGAA 摘要:This invention is directed to perfume compositions comprising 4,6-dioxa-5-C1-C8-alkyl or C2-C8-alkenyl-tricyclo[7.2.1.02,8]dodec-10-enes, the use of said tricyclododecenes as an odorant, the synthesis of said tricyclododecenes, and novel tricyclododecenes.