CAS: 1200-07-3; 3-(4-Bromophenyl)Acrylic Acid

上下游产品

p-amin°Cinnamic acid acetic anhydride 4-bromo-benzaldehyde malonic acid 4-Bromobenzoic acid 4-brom°Cinnamoyl chloride 3-(4-bromophenyl)propanol N-[(E)-2-(4-Bromo-phenyl)-vinyl]-formamide

3-(4-溴苯基)丙-2-烯-1-醇置于potassium Phosphate,二氧化碳,Crh6Mo6O24(3-)*3H3N*3H(1+)体系中,用 二甲基亚砜 用作溶剂,80.0 °C,100.0 Kpa 条件下,反应 24.0H,以81%的收率获得4-溴肉桂酸
参考文献:使用多金属氧酸盐负载的铬(III)催化剂和co2将醇高效氧化为羧酸
标题:使用多金属氧酸盐负载的铬(III)催化剂和co2将醇高效氧化为羧酸
摘要:将醇直接催化氧化为羧酸非常有吸引力,但是尚未建立经济的催化体系.在这里,我们显示纯的无机配体负载的铬化合物(nh 4)3 [crmo 6 O 18(oh)6 ](简化为crmo 6)可用于在存在以下条件下有效地促进此类反应co 2.在几乎所有情况下,各种醇(芳香族和脂肪族)的氧化都可以在温和的条件下完成,相应的羧酸可以高收率实现.铬催化剂1可以重复使用几次,而不会造成活动损失.机理研究和控制反应表明,酸化是通过醛的关键氧化立即进行的.
Doi:10.1039/d0Gc00388C

专利信息

专利号:US-6133409-A
优先权日:1996-12-19
标 题:Process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and αβ-unsaturated carboxylic acid and aldehyde compounds
发明人：SALVINO JOSEPH M; MORTON GEORGE C; MASON HELEN J; LABAUDINIERE RICHARD F
权利人:AVENTIS PHARM PROD INC
摘要:This invention is directed to a process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and alpha , beta -unsaturated carboxylic acid and aldehyde compounds and to polymeric hydroxylamine resin compounds useful therefor.

专利号:EP-0946478-B1
优先权日:1996-12-19
标题 :Process for the solid phase synthesis of aldehydes, ketones and hydroxamic acid compounds
发明人：SALVINO JOSEPH M; MORTON GEORGE C; MASON HELEN J; LABAUDINIERE RICHARD F
权利人:AVENTIS PHARMA INC
摘要:This invention is directed to processes for the solid-phase synthesis of aldehydes, ketones, oximes, amines and hydroxamic acid compounds and to polymeric hydroxylamine resin compounds useful therefor.

专利号:US-6710208-B2
优先权日:1996-12-19
标题 :Process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and α,β-unsaturated carboxylic acid and aldehyde compounds
发明人：SALVINO JOSEPH M; MORTON GEORGE C; MASON HELEN J; LABAUDINIERE RICHARD F
权利人:AVENTIS PHARMA INC
摘要:This invention is directed to a process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and α,β-unsaturated carboxylic acid and aldehyde compounds and to polymeric hydroxylamine resin compounds useful therefor.

专利号:WO-2023061999-A1
优先权日:2021-10-12
标 题 :Process for preparing a phenolic hydrocarbon
发明人：CORNELLA JOSEP; LE VAILLANT FRANCK
权利人:STUDIENGESELLSCHAFT KOHLE GGMBH
摘要:The present invention discloses a distinct mode of action of a nickel catalyst to forge C-0 bonds to unlock the mild utilization of N2O as O-atom transfer reagent in the synthesis of complex phenols from the corresponding aryl halides.

专利号:US-6531470-B1
优先权日:1998-01-23
标题:Oxazolidinone combinatorial libraries, compositions and methods of preparation
发明人：GORDEEV MIKHAIL F; LUEHR GARY W; PATEL DINESH V; NI ZHI-JIE; GORDON ERIC
权利人:UPJOHN CO
摘要:Oxazolidinones and methods for their synthesis are provided. Also provided are combinatorial libraries comprising oxazolidinones, and methods to prepare the libraries. Further provided are methods of making biologically active oxazolidinones as well as pharmaceutically acceptable compositions comprising the oxazolidinones. The methods of library preparation include the attachment of oxazolidinones to a solid support. The methods of compound preparation in one embodiment involve the reaction of an iminophosphorane with a carbonyl containing polymeric support.

专利号:US-10968162-B2
优先权日:2018-03-30
标 题:Method for the synthesis and purification of aryl acid esters
发明人：MARSHALL JANET
权利人:UNIV MIAMI
摘要:The general inventive concepts are directed to the discovery that certain aryl acids can be esterified under particular conditions to provide the resulting ester as a solid that precipitates in good yield from the reaction mixture. The esters may then be isolated and purified with relative ease. Accordingly, a method for the esterification, isolation, and purification of aryl acids is provided.