CAS: 850623-71-1; Potassium Trifluoro(4-Nitrophenyl)Borate

该化合物是一种有机体化合物,由于其稳定性和再活性,广泛用于交叉反应,如铃木-米亚乌拉的结合,三氟乙酸化合物组比博罗尼酸增强水解稳定性,减少分解和改善处理;4-硝基苯基混合物是制药和农用化学合成的多种中间体;该化合物对于空气和水分稳定,便利储存和运输特别宝贵;其晶体固态形式确保反应的一贯纯度和量化的便利;4-硝基苯三氟乙酸钾是建造复杂芳烃系统的可靠试剂,在学术和工业应用方面都具有效率.

结构式图片

物理性质

MSDS等安全信息

合成工艺路线路线简述

  • 24067-17-2 = 850623-71-1
    反应条件:1.1 Reagents: Potassium Bifluoride Solvents: Methanol,Water; 30 Min,Rt
    标题:Expanding The Balz-Schiemann Reaction: Organotrifluoroborates Serve As Competent Sources Of Fluoride Ion For Fluoro-Dediazoniation
    作者:Mohy El Dine,Tharwat; Sadek,Omar; Gras,Emmanuel; Perrin,David M.
    参考文献:Chemistry - A European Journal 日期:2018 卷标:24(56) 页码:14933-14937]

    = 850623-71-1
    反应条件:1.1 Reagents: Ethylene Glycol,Potassium Acetate,Diboronic Acid Catalysts: X-Phos,[2′-(Amino-Kn)[1,1′-Biphenyl]-2-Yl-Kc][butylbis(Tricyclo[3.3.1.13,7]Dec-1-Yl)Pho... Solvents: Ethanol; 25 Min,80 °C; 80 °C -> Rt1.2 Reagents: Potassium Bifluoride; 10 Min,0 °C; 20 Min
    标题:A Modified Procedure For The Palladium Catalyzed Borylation/suzuki-Miyaura Cross-Coupling Of Aryl And Heteroaryl Halides Utilizing Bis-Boronic Acid
    作者:Molander,Gary A.; Trice,Sarah L. J.; Tschaen,Brittany
    参考文献:Tetrahedron 日期:2015 卷标:71(35) 页码:5758-5764]

    24067-17-2 = 850623-71-1
    反应条件:1.1 Reagents: Potassium Bifluoride Solvents: Methanol; 10 Min,Rt
    标题:Ag(I)/persulfate-Catalyzed Decarboxylative Coupling Of α-Oxocarboxylates With Organotrifluoroborates In Water Under Room Temperature
    作者:Chang,Sheng; Wang,Jian Feng; Dong,Lin Lin; Wang,Dan; Feng,Bo; Et Al
    参考文献:Rsc Advances 日期:2017 卷标:7(82) 页码:51928-51934]

    24067-17-2 = 850623-71-1
    反应条件:1.1 Reagents: Potassium Fluoride Solvents: Acetonitrile,Water; 0.5 - 5 Min,Rt1.2 Reagents: (+)-Tartaric Acid Solvents: Tetrahydrofuran; 1 Min,Rt; 1 - 5 Min,Rt
    标题:Preparation Of Organotrifluoroborate Salts: Precipitation-Driven Equilibrium Under Non-Etching Conditions
    作者:Lennox,Alastair J. J.; Lloyd-Jones,Guy C.
    参考文献:Angewandte Chemie 日期:2012 卷标:51(37) 页码:9385-9388]

    = 850623-71-1
    反应条件:1.1 Reagents: Potassium Acetate,Diboronic Acid Catalysts: X-Phos,(Sp-4-4)-[2′-(Amino-Kn)[1,1′-Biphenyl]-2-Yl-Kc]Chloro[dicyclohexyl[2′,4′,6′-Tris... Solvents: Ethanol; 4 H,80 °C; 80 °C -> Rt1.2 Reagents: Potassium Bifluoride Solvents: Methanol,Water; 10 Min,0 °C; 20 Min,Rt
    标题:Scope Of The Palladium-Catalyzed Aryl Borylation Utilizing Bis-Boronic Acid
    作者:Molander,Gary A.; Trice,Sarah L. J.; Kennedy,Steven M.; Dreher,Spencer D.; Tudge,Matthew T.
    参考文献:Journal Of The American Chemical Society 日期:2012 卷标:134(28) 页码:11667-11673]

    = 850623-71-1
    反应条件:1.1 Reagents: Potassium Acetate,Sodium Tert-Butoxide,Diboronic Acid Catalysts: X-Phos,(Sp-4-4)-[2-[2-(Amino-Kn)Ethyl]Phenyl-Kc]Chloro[dicyclohexyl[2′,4′,6′-Tris(1-Met... Solvents: Ethanol; 4 H,Rt -> 80 °C1.2 Reagents: Potassium Bifluoride Solvents: Methanol,Water; Cooled; 10 Min,0 °C; 0 °C -> Rt; 20 Min,Rt
    标题:Palladium-Catalyzed,Direct Boronic Acid Synthesis From Aryl Chlorides: A Simplified Route To Diverse Boronate Ester Derivatives
    作者:Molander,Gary A.; Trice,Sarah L. J.; Dreher,Spencer D.
    参考文献:Journal Of The American Chemical Society 日期:2010 卷标:132(50) 页码:17701-17703]

    = 850623-71-1
    反应条件:1.1 Reagents: Potassium Acetate,1,1,2,2-Diborane(4)Tetramine,N1,N1,N1′,N1′,N2,N2,N2′,N2′-Octamethyl- Catalysts: X-Phos,(Sp-4-4)-[2′-(Amino-Kn)[1,1′-Biphenyl]-2-Yl-Kc]Chloro[dicyclohexyl[2′,4′,6′-Tris... Solvents: Methanol; Rt; 5 Min,Rt; Rt -> 60 °C; 3.5 H,60 °C1.2 Reagents: Potassium Bifluoride Solvents: Methanol,Water; 10 Min,0 °C; 20 Min,Rt
    标题:Palladium-Catalyzed Borylation Of Aryl And Heteroaryl Halides Utilizing Tetrakis(Dimethylamino)Diboron: One Step Greener
    作者:Molander,Gary A.; Trice,Sarah L. J.; Kennedy,Steven M.
    参考文献:Organic Letters 日期:2012 卷标:14(18) 页码:4814-4817]

    24067-17-2 = 850623-71-1
    反应条件:1.1 Reagents: Potassium Fluoride Solvents: Acetonitrile,Water; 2 - 5 Min,Rt1.2 Reagents: (+)-Tartaric Acid Solvents: Tetrahydrofuran; 1 Min,Heated; 10 Min,Rt
    标题:Oxidative Cycloaddition Reactions Of Arylboron Reagents Via A One-Pot Formal Dehydroboration Sequence
    作者:Karandikar,Shubhendu S.; Metze,Bryan E.; Roberts,Riley A.; Stuart,David R.
    参考文献:Chemrxiv 日期:2023 卷标:1 页码:1-11]

    24067-17-2 = 850623-71-1
    反应条件:1.1 Reagents: Potassium Bifluoride Solvents: Methanol,Water; 15 Min,Rt
    标题:Denitrogenative Pd/cu-Catalyzed Suzuki-Type Cross-Coupling Of Aryltrifluoroborates With Arylhydrazine Hydrochlorides In Water Under Room Temperature
    作者:Wang,Guofang; Meng,Mengting; Deng,Liping; Cheng,Kai; Qi,Chenze
    参考文献:Applied Organometallic Chemistry 日期:2018 卷标:32(3)]

    24067-17-2 = 850623-71-1
    反应条件:1.1 Reagents: Potassium Bifluoride Solvents: Methanol,Water; 10 Min,Rt
    标题:Pd-Catalyzed Desulfitative Reaction Of Aryltrifluoroborates With Sodium Arenesulfinates In Water
    作者:Chang,Sheng; Sun,Yong Bing; Zhang,Xiu Rong; Dong,Lin Lin; Zhu,He Yun; Et Al
    参考文献:Applied Organometallic Chemistry 日期:2018 卷标:32(1)

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合成参考文献


摘要:Molander, G. A.; Beaumard, F., Science of Synthesis Knowledge Updates, (2013) 3, 111.
摘要:Molander, G. A.; Beaumard, F., Science of Synthesis Knowledge Updates, (2013) 3, 108.
摘要:Lai, J.; Thomson, B. J.; Sammis, G. M., Science of Synthesis: Modern Strategies in Organofluorine Chemistry , (2024) 1, 39.
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