CAS: 6954-27-4; [1,1'-Biphenyl]-4,4'-Dithiol

该化合物是一个有机化合物,其特征是其联苯结构,由两个联苯环组成,由一个单一债券连接;在联苯框架的副位置上存在两个硫醇(-SH)组,具有独特的化学特性,包括在氧化后形成脱硫联结的能力;该化合物在室温下一般是固体,在有机溶剂中可能表现出中等溶解性;其硫醇组有可能成为有机合成,材料科学以及协调化学的应用对象;此外,该化合物可参与红氧化反应,使其在各种化学过程中有用;硫原子组的存在还表明在传感器开发或纳米技术领域的潜在应用,其中硫醇组可促进分子与表面的粘结.

结构式图片

相似化合物

19813-90-2 51193-27-2 19813-76-4

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

biphenyl-4,4'-disulfonyl chloride 4,4'-bis-ethylsulfanyl-biphenyl 4,4'-bis-trichloromethylsulfanyl-biphenyl aniline4,4'-bis-ethylsulfanyl-biphenyl biphenyl-4,4'-disulfonyl chloride dimethyl 5,5'-[[1,1'-biphenyl]-4,4'-diylbis(thio)]bis[2,2-dimethylpentanoate] S,S'-bis(10-(1,4,7-tris(trifluoroacetyl)-1,4,7-triazacyclododecyl))-4',4''-dithiobiphenyl

合成工艺路线路线简述

  • 合成目标产物 Biphenyl-4,4'-Dithiol 主要起始原料 4,4'-Dibromobiphenyl
  • (文献来源)合成步骤主要原料 4,4'-Dibromobiphenyl
📜4,4'-Bis-Ethylsulfanyl-Biphenyl置于氨,Sodium体系中,化学反应生成 联苯-4,4'-二硫醇
参考文献:Thioethers. Iii. Preparation Of Aromatic Di-And Tri-Mercapto Compounds By Dealkylation Of Aryl Alkyl Thioethers
标题:Thioethers. Iii. Preparation Of Aromatic Di-And Tri-Mercapto Compounds By Dealkylation Of Aryl Alkyl Thioethers
摘要:
DOI:10.1021/ja01527A045

海关参考信息

专利信息


专利号:US-10150160-B2
优先权日:2014-12-04
标题 :Universal one-pot and up-scalable synthesis of SERS encoded nanoparticles
发明人:PAZOS PÉREZ NICOLÃ?S; MIR DE SIMÓN BERNAT
权利人:MEDCOM ADVANCE S A; MEDCOM ADVANCE S A
摘要:The universal one-pot and up-scalable synthesis of SERS encoded nanoparticles relies on the controlled co-absorption of mercaptoundecanoic acid (MUA) and the Raman code on the metallic surfaces of the nanoparticles. In contrast to most of the reported procedures which typically involve complex steps, the present method has demonstrated to be an easy and fast one-pot approach for the production of SERS-encoded nanoparticles. This versatile strategy allows for the SERS codification of particles with every molecule with affinity toward the metal surface, independently of its chemical nature, as exemplified here in the fabrication of 31 different encoded particles using the same standard procedure. In addition to the easiness of preparation, scalability to the liter regime, stability in aqueous solutions including PBS and chemical diversity, our SERS-encoded particles show considerably higher optical efficiency than those fabricated by using PEG or PVP polymers.

专利号:US-3886201-A
优先权日:1971-11-17
标 题:Perfluoroalkyl esters of mercapto- and thio-carboxylic acids
发明人:FALK ROBERT ALLAN; KLEINER EDUARD KARL
权利人:CIBA GEIGY CORP
摘要:Novel perfluoroalkyl group containing mercaptans and sulfides are disclosed having soil repellent properties if applied to substrates such as textiles, paper and leather and being useful as intermediates for the synthesis of soil repellent polymers. The adducts are obtained by the base or free radical catalyzed addition of hydrogen sulfide or mono- or polymercaptans to perfluoroalkyl group containing esters of fumaric, maleic, citraconic, mesaconic, itaconic, methylene malonic or aconitic acid.

专利号:US-9896776-B2
优先权日:2011-09-21
标 题 :Chemical and electrochemical synthesis and deposition of chalcogenides from room temperature ionic liquids
发明人:STEVENSON KEITH J; MURUGESAN SANKARAN; KEARNS PATRICK; AKKINENI ARUNKUMAR
权利人:UNIV TEXAS
摘要:Room temperature electrochemical methods to deposit thin films of chalcogenide glasses.

专利号:JP-2006521437-A
优先权日:2003-03-24
标 题 :Process for the synthesis of thiophosphine compounds and polymerizable compositions containing them and their use for the production of ophthalmic lenses

专利号:US-3864310-A
优先权日:1972-01-28
标 题:High performance heterocyclic polymer polymerization via molten lewis acid eutectics
发明人:SAFERSTEIN LOWELL
权利人:CELANESE CORP
摘要:An improved process is provided for the synthesis of high performance heterocyclic polymers wherein the polymerization is conducted in the presence of a molten Lewis Acid eutectic selected for its ability to dissolve the high molecular weight polymer; to remove water produced via the condensation reaction; and to melt substantially below the polymerization reaction temperature.

专利号:US-2017326638-A1
优先权日:2014-12-04
标 题:Universal one-pot and up-scalable synthesis of sers encoded nanoparticles

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: Biman Saikia, Et Al. Hyper-Ige Syndrome With A Novel Stat3 Mutation-A Single Center Study From India. Asian Pac J Allergy Immunol. 2014 Dec;32(4):321-7.
[参考文献]: Delphine Parrot, Et Al. Littoral Lichens As A Novel Source Of Potentially Bioactive Actinobacteria. Sci Rep. 2015 Oct 30:5:15839.
[参考文献]: Jie Zeng, Et Al. A Supramolecular Gel Approach To Minimize The Neural Cell Damage During Cryopreservation Process. Macromol Biosci. 2016 Mar;16(3):363-70.
[参考文献]: Josef Yayan, Et Al. No Development Of Ciprofloxacin Resistance In The Haemophilus Species Associated With Pneumonia Over A 10-Year Study. Bmc Infect Dis. 2015 Nov 13:15:514.
[参考文献]: Michael W Neubrand, Et Al. Self-Assembly Of Aqueous Bilirubin Ditaurate, A Natural Conjugated Bile Pigment, To Contraposing Enantiomeric Dimers And M(-) And P(+) Tetramers And Their Selective Hydrophilic Disaggregation By Monomers And Micelles Of Bile Salts. Biochemistry. 2015 Feb 24;54(7):1542-57.

合成参考文献


参考文献:10.1055/s-0030-1260123
摘要:Christoffers J, Muesmann T, Wickleder M. Preparation of Linear Aromatic Disulfonic Acids: New Linker Molecules for Metal-Organic Frameworks. Synthesis. 2011 Jul 20;2011(17):2775–80. doi: 10.1055/s-0030-1260123.
参考文献:10.1007/978-3-030-69621-4_7
摘要:Aliyev IA, Trofimov BA, Oparina LA. Some Areas of Application of Aromatic Thiols and Their Derivatives. 2021. In: Aromatic Thiols and Their Derivatives.
参考文献:10.1007/978-981-10-8803-2_3
摘要:Tan SF. Self-Assembly of Silver Nanoparticles with Sub-nanometer Separations. 2018. In: Springer Theses.
参考文献:10.1007/978-981-99-6105-4_7
摘要:Ehsan M, Suhag D, Rathore R, Thakur A, Thakur P. Metal Nanoparticles in the Field of Medicine and Pharmacology. 2023. In: Integrated Nanomaterials and their Applications.
参考文献:10.1007/978-3-031-55452-0_10
摘要:Parravicini J. How “Science Should Not Be Done”: Frauds and Distortions. 2024. In: The Foundations of Experimental Physics.
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