CAS: 5833-47-6; 2,2-Dimethyloxasilinane

该化合物是一个环硅烷化合物, 由六人环状结构组成,在异体循环中带有氧和硅原子. 硅中心二甲基替代能增强它的稳定性,减少反应性,使其适合需要控制水解或热抗力的应用. 该化合物在有机硅化学中特别有用,作为功能化硅氧的前体或聚合合成的构件. 其明确界定的结构和可预测的再活动有利于精确分子设计至关重要的研究和工业过程. 中度条件下的化合物稳定性进一步支持其在专门合成途径中的实用性.

结构式图片

上下游产品

chloro(4-chlorobutoxy)dimethylsilane 1,3-bis(4-hydroxybutyl)tetramethyldisiloxane 4-(dimethylsiloxy)-1-butene 1-Butenol trimethylsilyl ether 1,3-bis(4-hydroxybutyl)tetramethyldisiloxane tetramethyldisiloxanebis4-(methacryloyloxy)butyltetramethyldisiloxane Benzoic acid 4-(chloro-dimethyl-silanyl)-butyl ester (E)-3-Phenyl-acrylic acid 4-(1,1,3,3-tetramethyl-3-{4-[(E)-(3-phenyl-acryloyl)oxy]-butyl}-disiloxanyl)-butyl ester

合成工艺路线路线简述

    📜(3-Butenyloxy)Trimethylsilane置于dihydrogen Hexachloroplatinate,二甲基一氯硅烷体系中,用 异丙醇 作为反应溶剂,化学反应生成 1,1-二甲基-1-硅-2-噁环己烷
    参考文献:Kozlikov,V.L. Et Al.,Journal Of General Chemistry Of The Ussr,1969,Vol. 39,P. 2226-2229
    标题:Kozlikov,V.L. Et Al.,Journal Of General Chemistry Of The Ussr,1969,Vol. 39,P. 2226-2229

    海关参考信息

    专利信息


    专利号:WO-2024245658-A1
    优先权日:2023-05-30
    标 题:Process for the synthesis of tetrahydrocannabinolic acid dimethylsiloxane, and tetrahydrocannabinolic acid dimethylsiloxane
    发明人:COSKY ERIC S
    权利人:TRESCO HOLDING GMBH
    摘要:The invention relates to a novel process for the synthesis of tetrahydrocannabinolic acid dimethylsiloxane and tetrahydrocannabinolic acid dimethylsiloxane.

    专利号:US-9249165-B2
    优先权日:2013-08-30
    标题 :Slurry phase direct synthesis of organohalosilanes from cyclone fines
    发明人:LEWIS KENRICK MARTIN; ZHU YANJUN; MEREIGH ABELLARD T; RAZZANO JOHN; NEELY JOHN DAVID
    权利人:MOMENTIVE PERFORMANCE MAT INC
    摘要:The present invention is directed to a process for the synthesis of organohalosilane monomers, comprising the steps of (1) forming a slurry of cyclone fines, ultra fines and/or spent contact mass in a thermally stable solvent and reacting the agitated slurry with an organohalide of the formula R 1 X in the presence of an additive for a time and at a temperature sufficient to produce organohalosilane monomers having the formulae R 1 SiHX 2 , R 1 2 SiHX, R 1 3 SiX, R 1 SiX 3 , and R 1 2 SiX 2 ; wherein R 1 is a saturated or unsaturated aromatic group, a saturated or unsaturated aliphatic group, alkaryl group, or cycloaliphatic hydrocarbyl group, and X is a halogen; and (2) recovering said organohalosilane monomers.

    专利号:US-7521504-B2
    优先权日:2001-07-24
    标 题:Irreversible immobilization of enzymes into polyurethane coatings
    发明人:RUSSELL ALAN J; DREVON GERALDINE F; WICKS DOUGLAS A; DANIELMEIER KARSTEN
    权利人:UNIV PITTSBURGH
    摘要:A method of irreversibly immobilizing an enzyme in a polyurethane and an enzyme-containing polyurethane having a degree of immobilization of the enzyme of approximately 100%. The synthesis of waterborne polyurethanes in the presence of enzyme has enabled the irreversible attachment of the enzyme to the polymeric matrix. The distribution of immobilized enzyme as well as activity retention are homogeneous within the polyurethane. Decreasing ECC hydrophobicity, via the use of a less hydrophobic polyisocyanate prepolymer during polymerization, significantly enhanced the intrinsic activity of the ECC.

    专利号:US-11738328-B2
    优先权日:2021-04-30
    标题:Single-step synthesis of chemisorption fiber sorbents (CHEFS) for the capture of CO2 and removal of water contaminants
    发明人:GRAY MCMAHAN L; SHI FAN; YI SHOULIANG; WILFONG WALTER CHRIS; WANG QIUMING
    权利人:US ENERGY
    摘要:One or more embodiments relates to method for generating CHEFS having the steps of generating the CHEFS from a dope. One or more embodiments relates to a method for generating CHEFS having amine functional groups having the steps of generating a dope containing a BIAS with amine groups, at least one polymer, and at least one solvent; and forming CHEFS from the dope, wherein the generated CHEFS have no more than 30% amine loss compared to the BIAS.

    专利号:US-2004225153-A1
    优先权日:2003-02-13
    标题 :Synthesis of polyphosphazenes with sulfonimide side groups
    发明人:ALLCOCK HARRY R; HOFMANN MICHAEL A; AMBLER CATHERINE M; MAHER ANDREW E; WOOD RICHARD M; WELNA DANIEL T
    权利人:PENN STATE RES FOUND
    摘要:The invention relates to sulfonimide bearing phenolic compounds and the use of those compounds to produce polyphosphazenes functionalized by one or more of those compounds alone, or in combination with cosubstituents. The invention also relates to blends of sulfonimide functionalized phosphazene polymers with other polymers, membranes formed of the functionalized polymers, and the use of those membranes in devices such as fuel cells.

    专利号:US-10189951-B2
    优先权日:2014-04-25
    标题 :Aliphatic polyimides from a 1:2 molar ration of diamine and unsaturated monoanhydride or unsaturated diacid
    发明人:DUAN YANNAN; AVAKIAN ROGER W
    权利人:POLYONE CORP
    摘要:Aliphatic polyimides are synthesized by a 2:1 molar ratio reaction of an unsaturated monoanhydride or an unsaturated diacid with a diamine. Bio-derived monomers are particularly useful in the synthesis of the aliphatic polyimides.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/s12633-009-9021-3
    摘要:Frampton MB, Zelisko PM. Organosilicon Biotechnology. Silicon. 2009 Jul;1(3):147–63. doi: 10.1007/s12633-009-9021-3.
    参考文献:10.1007/bf00707060
    摘要:Vinogradova LE, Volkova LM, Makarova NN, Petrova IM. IR spectroscopic study of the reaction of dihydroxyorganocyclosiloxanes with 2,2-dimethyl-1-oxa-2-silacyclohexane. Russian Chemical Bulletin. 1995 Jun;44(6):1096–8. doi: 10.1007/bf00707060.
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