CAS: 556-64-9; Methyl Thiocyanate

该化合物是一种有机化合物,具有分子式C2H3NS的特征.它是一种无色的黄色液体,具有芥子酱或大蒜的微光味,具有芥子或大蒜的相似性.该化合物为极地,具有相对较低的沸点,使该物质挥发性.甲基硫氰酸盐在乙醇和乙醚等有机溶剂中溶解,但在水中溶解性有限.它主要用于合成各种化学品,包括制药和农用化学品,并用作有机化学的再剂.该化合物以其活性为名,特别是核分裂性代用品反应,因为硫氰酸盐组的存在.然而,该化合物也被认为是危险的;如果吸入或摄入,则具有毒性,在处理时应采取适当的安全措施.

结构式图片

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

diazomethane thi°Cyanic acid methanol p-nitrophenyldimethylsulphonium methylsulphateN-Benzoylamino-dithiokohlensaeuremethylester O,O,S-trimethyl phosphorothioate acetyl dithi°Carbamic acid methyl ester (4-bromo-benzoyl)-dithi°Carbamic acid methyl ester

合成工艺路线路线简述

    📜Alkaline Earth Salt Of/the/ Methylsulfuric Acid 反应生成 硫氰酸甲酯
    参考文献:Arndt,Chemische Berichte,1921,Vol. 54,P. 2242
    标题:Arndt,Chemische Berichte,1921,Vol. 54,P. 2242

    海关参考信息

    专利信息


    专利号:US-4774331-A
    优先权日:1986-08-22
    标 题:Process for ortho-cyanation of phenols or phenylamines
    发明人:ADACHI MAKOTO; MATSUMURA HIROMU; SUGASAWA TSUTOMU
    权利人:SHIONOGI & CO
    摘要:A process for ortho-cyanation of phenols or phenylamines which comprises reacting a phenyl compound having a hydroxy group or an optionally substituted amino or cyclic amino group, of which the ortho position is vacant, with trichloroacetonitrile, a C1-C5 alkyl thiocyanate or a C6 - C12 aryl thiocyanate in the presence of a boron trihalide and treating the resultant product with an alkali is provided, and said process is useful in the synthesis of intermediates for medicinals or pesticides.

    专利号:US-4857645-A
    优先权日:1986-11-06
    标 题:Process for introducing a thiocarboxylic ester group at the orthoposition of phenols or phenylamines
    发明人:MAKOTO ADACHI; MATSUMURA HIROMU; SUGASAWA TSUTOMU
    权利人:SHIONOGI & CO
    摘要:A process for introducing thiocarboxylic ester at ortho-position of phenols or phenylamines which comprises reacting a phenyl compound having group or optionally substituted amino or cyclic amino group, of which at least one ortho-position is vacant, with C 1 -C 5 alkyl thiocyanate, C 7 -C 13 aralkyl thiocyanate or C 6 -C 12 aryl thiocyanate in the presence of a boron trihalide and hydrolyzing the resultant product under acidic conditions is provided, and said process is useful in the synthesis of medicinals, pesticides and dyes.

    专利号:US-6689844-B2
    优先权日:2001-05-29
    标题 :Process for synthesis of polymer compositions with reduced halogen content, polymer composition with reduced halogen content as well as use of this composition
    发明人:ROOS SEBASTIAN; BOLLINGER JOSEPH MARTIN; SCHERER MARKUS
    权利人:ROHMAX ADDITIVES GMBH
    摘要:Polymer compositions with reduced living halogen content are used as additive to lubricating oils and are prepared by polymerizing at least one ethylenically unsaturated monomer using a) at least one initiator containing a transferable halogen and b) one or more metal catalysts containing at least one transition metal, in the presence of ligands which can form a coordination compound with the one or more metal catalysts, to obtain a polymer composition having a living halogen content, and after the polymerizing, reacting the polymer composition having a living halogen content with at least one organic nitrogen compound in the presence of a nonpolar solvent, thereby reducing the living halogen content to obtain the polymer composition having a reduced halogen content.

    专利号:US-11117851-B2
    优先权日:2015-08-12
    标题 :Reactor layout for methanol production from low quality synthesis gas
    发明人:MODARRESI HASSAN
    权利人:HALDOR TOPSOE AS
    摘要:A reactor layout for a process of methanol production from low quality synthesis gas, in which relatively smaller adiabatic reactors can be operated more efficiently, some of the inherent disadvantages of adiabatic reactors for methanol production are avoided. This is done by controlling the outlet temperature in the pre-converter by rapid adjustment of the recycle gas, i.e. by manipulating the gas hourly space velocity in the pre-converter.

    专利号:CN-115337961-A
    优先权日:2022-05-26
    标题:A kind of catalyst and its synthetic method for the synthesis of N-allyl thiourethane compounds

    专利号:US-8501954-B2
    优先权日:2008-07-29
    标题:Asymmetric process for making substituted 2-amino-thiazolones
    发明人:CAILLE SEB; CUI SHENG; WANG XIANG; FAUL MARGARET
    权利人:CAILLE SEB; CUI SHENG; WANG XIANG; FAUL MARGARET; AMGEN INC
    摘要:The invention provides two process for synthesizing substituted aminothiazolone compounds as inhibitors of 11-β-hydroxy steroid dehydrogenase type 1. The processes allow the stereoselective synthesis of the desired compounds without the use of stoichiometric amounts of chiral catalysts.

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    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Khartulyari, A.; Maier, M. E., Science of Synthesis Knowledge Updates, (2010) 3, 60.
    摘要:Wu, Y.-J., Science of Synthesis Knowledge Updates, (2012) 2, 302.
    摘要:von Angerer, S., Science of Synthesis Knowledge Updates, (2011) 1, 228.
    摘要:von Angerer, S., Science of Synthesis Knowledge Updates, (2011) 1, 127.
    摘要:Aggarwal, P.; Bebbington, M. W. P., Science of Synthesis Knowledge Updates, (2012) 2, 433.
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