CAS: 29875-06-7; Magnesium Chloride (3-Methylphenyl)Methanide (1/1/1)

该化合物是一种有机磁性化合物,通常用作有机合成中的灰色试剂,其主要优点包括碳-碳联结反应中的高回活性,使其对复杂的有机分子的制作具有价值.3-甲基苯基组的存在增强了其在碳基化合物,氯酮和酯的核生殖添加中的稳定性和选择性.这种试剂在水性条件下特别有效,确保敏感反应的一贯性.它与诸如THF和二乙醚等一系列溶剂的兼容性,进一步扩大其在合成化学中的可适用性.建议对惰性大气进行适当处理以保持其功效.

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    专利信息


    专利号:US-2003092064-A1
    优先权日:2001-04-05
    标题 :System for the synthesis of spatially separated libraries of compounds and methods for the use thereof
    发明人：READER JOHN C
    权利人:MILLENNIUM PHARM INC
    摘要:Featured is an apparatus useful for preparing combinatorial libraries of compounds in a parallel fashion so that the individual compounds of the library are spatially separate and the position of each compound of the library in the apparatus is known. Moreover, the apparatus is useful for the preparation of combinatorial libraries of compounds where the library is constructed from three or more building blocks, e.g., three, four, five, six or seven building blocks, resulting in a three, four, five, six or seven dimensional combinatorial library. Also featured are related methods for the preparation of three, four, five, six or seven dimensional combinatorial libraries of compounds using the apparatus of the present invention.

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    合成参考文献


    摘要:Spivey, A. C.; Tseng, C.-C., Science of Synthesis Knowledge Updates, (2010) 1, 28.
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