CAS: 25697-56-7; 3-Methylbenzylmercaptan

上下游产品

dithi°Carbamic acid-(3-methyl-benzyl ester) 3-methylbenzyl alcohol (3methylbenzyl)benzyl sulfide (3methylbenzyl)benzyl sulfide 4-(2-fluorophenyl)-1,2,3,6-tetrahydro-1-methylpyridine 4-(2-Fluoro-phenyl)-1-methyl-4-(3-methyl-benzylsulfanyl)-piperidine hexakis-(3-methylbenzylthiomethyl)benzene

📜3-甲基苄溴置于乙二胺体系中,用 二氯甲烷,水,丙酮 用作溶剂,化学反应 4.0H,反应生成3-甲基苯甲硫醇
参考文献:Bf3 介导的 [1,5]-氢化物位移触发环化:硫醚加入游戏
标题:Bf3 介导的 [1,5]-氢化物位移触发环化:硫醚加入游戏
摘要:1,5-氢化物位移触发了 2-(2-(苄硫基)亚苄基)丙二酸酯环化为硫杂色烷,这是首次提出的.三氟化硼作为反应促进剂是这种 C-H 活化成功的关键.量子化学计算表明,所研究的反应通过o-Bf 2-O 螯合物进行的,这已通过 NMR 分析得到证实.
Doi:10.1002/ejoc.202200547

专利信息

专利号:US-5331096-A
优先权日:1992-04-01
标题 :2- and 3-sulfur derivatives of 1,5-iminosugars
发明人：KOSZYK FRANCIS J; MUELLER RICHARD A
权利人:SEARLE & CO
摘要:Novel derivatives of 1-deoxynojirimycin are disclosed which have thio or sulfinyl substituents at C-2 or C-3. These compounds are useful inhibitors of lentiviruses such as visna virus and human immunodeficiency virus. Methods of chemical synthesis of these derivatives and intermediates therefor are also disclosed.

专利号:US-5342951-A
优先权日:1992-04-01
标题:2- and 3-sulfur derivatives of 1,5-iminosugars
发明人：KOSZYK FRANCIS J; MUELLER RICHARD A
权利人:SEARLE & CO
摘要:Novel derivatives of 1-deoxynojirimycin are disclosed which have thio or sulfinyl substituents at C-2 or C-3. These compounds are useful inhibitors of lentiviruses such as visna virus and human immunodeficiency virus. Methods of chemical synthesis of these derivatives and intermediates therefor are also disclosed.

专利号:US-5268482-A
优先权日:1992-04-01
标 题:2- and 3-sulfur derivatives of 1,5-iminosugars
发明人：KOSZYK FRANCIS J; MUELLER RICHARD A
权利人:SEARLE & CO
摘要:Novel derivatives of 1-deoxynojirimycin are disclosed which have thio or sulfinyl substituents at C-2 or C-3. These compounds are useful inhibitors of lentiviruses such as visna virus and human immunodeficiency virus. Methods of chemical synthesis of these derivatives and intermediates therefor are also disclosed.

专利号:US-3624143-A
优先权日:1968-05-10
标题 :Compounds of the class {62 -aralkylthio-substituted-{60 -amino acids
发明人：SHEN TSUNG-YING; WALFORD GORDON L; DORN CONRAD P JR
权利人:MERCK & CO INC
摘要:Beta -Aralkylthio-substituted- Alpha -amino acids and derivatives thereof useful as antiinflammatory agents are described. A process for preparing some of these amino acids by reaction of the corresponding aldehydes or ketones in the Strecker or hydantoin synthesis is shown.

专利号:US-7256177-B2
优先权日:2003-06-17
标题 :Lincomycin derivatives possessing antibacterial activity
发明人：LEWIS JASON G; ANANDAN SAMPATH K; O'DOWD HARDWIN; GORDEEV MIKHAIL F
权利人:VICURON PHARM INC
摘要:Novel lincomycin derivatives are disclosed. These lincomycin derivatives exhibit antibacterial activity. The compounds of the subject invention may exhibit potent activities against bacteria, including Gram positive organisms, and may be useful antimicrobial agents. Methods of synthesis and of use of the compounds are also disclosed.

专利号:US-7361743-B2
优先权日:2004-02-11
标 题 :Lincomycin derivatives possessing antibacterial activity
发明人：LEWIS JASON G; ANANDAN SAMPATH K; O'DOWD HARDWIN; GORDEEV MIKHAIL F; LI LIANSHENG
权利人:PFIZER
摘要:Novel lincomycin derivatives are disclosed. These lincomycin derivatives exhibit antibacterial activity. The compounds of the subject invention may exhibit potent activities against bacteria, including Gram positive organisms, and may be useful antimicrobial agents. Methods of synthesis and of use of the compounds are also disclosed.