📜二氯二甲基硅烷置于氯,三氯化铁体系中,化学反应生成(二氯甲基)甲基二氯硅烷 参考文献:The Preparation And Properties Of Some Chloromethylchlorosilanes 标题:The Preparation And Properties Of Some Chloromethylchlorosilanes 摘要: Doi:10.1021/ja01226A057
专利号:US-4289890-A 优先权日:1979-02-12 标 题:Synthesis of chloromethyldisilanes 发明人:GORDON ROY G 权利人:GORDON ROY G 摘要:1,2 Dichloro-1,1,2,2-tetramethyldisilane is synthesized in high yield and good purity starting from a crude mixture of chloromethyldisilanes formed as by-products in the manufacture of silicones. The new method uses less than half as much Grignard reagent as previous methods required. The synthesis can also be used to produce other haloalkyldisilanes such as chloropentamethyldisilane or 1,1,2 trichloro-1,2,2-trimethyldisilane.
参考文献:10.1007/978-1-4020-8174-3_12 摘要:Interrante L, Shen Q. Hyperbranched Polycarbosilanes via Nucleophilic Substitution Reactions. 2009. In: Silicon-Containing Dendritic Polymers. : Springer Netherlands; 2009. 参考文献:10.1023/a:1018577111536 摘要:MARTIN H-, MULLER E, RICHTER R, ROEWER G, BRENDLER E. Conversion process of chlorine containing polysilanes into silicon carbide: Part I Synthesis and crosslinking of poly(chloromethyl)silanes–carbosilanes and their transformation into inorganic amorphous silicon carbide. Journal of Materials Science. 1997 Mar 01;32(5):1381–7. doi: 10.1023/a:1018577111536.