CAS: 13476-99-8; Vanadium(Iii) Acetylacetonate

该化合物是一个协调综合体, 其特点是在+3氧化状态下, , 被绑在三个乙酰蕾聚酯中. 该复合体因其在有机溶剂,热稳定性和定义明确的分子结构中的高溶性而具有价值,使其成为材料科学和催化方面的多种前体. 它通常用于化学蒸气沉积(CVD) 和沙凝工艺, 用于生产含有的薄膜和纳米粒子. 它的连续的再活性和纯度也使其适合在化学和聚合催化方面的研究. 化合物在惰性条件下的稳定性进一步增强了其在受控合成应用中的用途.

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CAS号3153-26-2 乙酰丙酮氧钒 | CAS号123-54-6 乙酰丙酮 | CAS号7440-62-2 钒粉 | CAS号7718-98-1 氯化钒 | CAS号1118-67-8 sodium acetylac... | CAS号107440-46-0 bis-μ-(diisopro... | CAS号12035-98-2 氧化钒 | CAS号61260-06-8 2-[methyl-[2-[m... | CAS号3153-26-2 乙酰丙酮氧钒 | CAS号768-95-6 1-金刚烷醇 | CAS号32065-17-1 N,N-双(亚水杨基)邻苯二胺...

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    专利号:US-5166110-A
    优先权日:1989-12-22
    标 题 :Process for the synthesis of ziegler-type catalytic solids or solid constituents of the same
    发明人:BRUN CLAUDE
    权利人:ATOCHEM ELF SA
    摘要:A process is provided for the synthesis of a solid Ziegler catalyst or of a transition metal solid constituent thereof, which entails preparing the solid catalyst or constituent thereof as a suspension in an inert liquid medium by contacting precursors or ingredients of the catalyst or of the constituent in the inert liquid medium in one or more steps, and drying the suspension, and collecting the catalyst or constituent thereof; and wherein the process is conducted in a single multi-function reactor having a longitudinal axis and which can pivot around an axis which intersects perpendicularly with this axis.

    专利号:US-2022081788-A1
    优先权日:2019-12-27
    标题:General method for the synthesis of FeCoNiCu-based high-entropy alloy and their application for electrocatalytic water splitting
    发明人:ZHU HAN; ZHANG SONGGE; CAI JIAN; LI HUILIN; DU MINGLIANG
    权利人:UNIV JIANGNAN
    摘要:The disclosure herein discloses a general method for the synthesis of FeCoNiCu-based high-entropy alloy and their application for electrocatalytic water splitting, belonging to the technical field of preparation of composite materials. The catalytic material for electrolysis of water includes a reaction active material and a support. The reaction active material is FeCoNiCu-based high-entropy alloy nanoparticles such as FeCoNiCuSn, FeCoNiCuMn, FeCoNiCuV or the like. The support is a carbon nanofiber material prepared by electrospinning. The catalytic material for electrolysis of water prepared in the disclosure herein has a high specific surface area, which facilitates diffusion of the electrolyte and desorption of gas. By using the catalytic material for electrolysis of water, hydrogen and oxygen can be produced under alkaline conditions, and the hydrogen production rate under high voltage is much higher than that of a 20% Pt/C electrode. Meanwhile, the carbon nanofibers can effectively protect the high-entropy alloy nanoparticles from erosion of the electrolyte, and endow the catalytic material with good stability.

    专利号:US-2024149253-A1
    优先权日:2021-02-26
    标 题 :Large scale synthesis of oxidative dehydrogenation catalyst
    发明人:GAO XIAOLIANG; SIMANZHENKOV VASILY; SULLIVAN DAVID; DE WIT PERRY; DRAG HANNA; KIM YOONHEE
    权利人:NOVA CHEM INT SA
    摘要:Catalysts and Methods for large-scale production of the catalysts are provided. An exemplary catalyst composition includes molybdenum, vanadium, tellurium, niobium, oxygen. In the catalyst composition, the molar ratio of molybdenum to vanadium is from 1:0.05 to 1:0.60, the molar ratio of molybdenum to tellurium is from 1:0.01 to 1:0.30, and the molar ratio of molybdenum to niobium is from 1:0.01 to 1:0.40. Oxygen is present at least in an amount to satisfy the valency of any present metal oxides, and composition includes less than 1.0 wt. % of sulfur.

    专利号:US-5190498-A
    优先权日:1989-12-22
    标 题 :Magnetic drive system for reactor used in the synthesis of Ziegler-type catalytic solids or solid constituents of the same
    发明人:BRUN CLAUDE
    权利人:ATOCHEM ELF SA
    摘要:A magnetic drive system in a reactor generates rotational and translational motion of the agitator. The magnetic drive system includes a tubular shaft having one end attached to the agitator, and another end. A magnetic annular weight is fitted to the another end. A guide column has an end supported by the reactor body and a free end, the guide column further having a cylindrical bore in which an intermediate part of the tubular shaft slides in a fluid tight manner. A cylindrical guide cap is fluid tightly mounted to the free end of the guide column, the guide cap covering the magnetic annular weight and incorporating a cylindrical guide shaft integral with a bottom of the cap, the tubular shaft sliding coaxially and fluid tightly on the guide shaft. A drive rotor covers the guide cap and has another annular magnetic weight enclosing the guide cap and positioned with respect to the annular weight fitted to the tubular shaft such that a rotational or translational movement of the drive rotor generates a corresponding movement of a tubular shaft and the agitator. A motor is connected to the drive rotor for driving the rotor about an axis coaxial with the axis of the reactor body.

    专利号:US-4722919-A
    优先权日:1986-10-06
    标题 :Synthesis of vanadium/propylene glycol complexes
    发明人:MARQUIS EDWARD T; SANDERSON JOHN R
    权利人:TEXACO INC
    摘要:Complexes made by reacting propylene glycol with a vanadium compound soluble therein at an elevated temperature. Mild stripping of the water subsequent to complex formation is preferred. The ratio of moles of propylene glycol to gram atoms of vanadium in the complex forming reaction ranges from 7:1 to 20:1.

    专利号:US-8816125-B2
    优先权日:2006-12-23
    标 题 :Process for the continuous preparation of (cyclo)aliphatic diisocyanates
    发明人:MICHALCZAK HANS-WERNER; KOHLSTRUK STEPHAN; KRECZINSKI MANFRED; GRUND GERDA; LOMOELDER RAINER
    权利人:MICHALCZAK HANS-WERNER; KOHLSTRUK STEPHAN; KRECZINSKI MANFRED; GRUND GERDA; LOMOELDER RAINER; EVONIK DEGUSSA GMBH
    摘要:The invention relates to a multi-stage process for the continuous, phosgene-free preparation of (cyclo)aliphatic diisocyanates that comprises the conversion of (cyclo)aliphatic diamines into the corresponding (cyclo)alkylene biscarbamates and the thermal cleaving of the latter into the (cyclo)alkylene diisocyanates and alcohol. The urea used in accordance with the invention and also the urea employed for the preparation of urea equivalents (e.g. alkyl carbonates, alkyl carbamates) as a possible precursor for the synthesis of the (cyclo)aliphatic biscarbamates is unconditioned.

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    合成参考文献


    摘要:Kaminsky, W., Science of Synthesis, (2009) 48, 712.
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