4-三氟甲基苯基溴化镁置于三氯化磷体系中,化学反应生成三(4-三氟甲苯基)膦 参考文献:Zhmurova,I.N.; Kirsanov,A.V.,Journal Of General Chemistry Of The Ussr,1966,Vol. 36,P. 1265-1269 标题:Zhmurova,I.N.; Kirsanov,A.V.,Journal Of General Chemistry Of The Ussr,1966,Vol. 36,P. 1265-1269
专利号:US-10889599-B2 优先权日:2018-02-27 标 题:1,1-diborylalkyl-1-metal compounds, preparation method thereof, and their applications toward synthesis of 1,1-diboronate ester compounds 发明人:CHO SEUNG HWAN; LEE YEOSAN 权利人:POSTECH ACAD IND FOUND 摘要:The present invention relates to a 1,1-diborylalkyl-1-metal compound including one metal group together with two identical boron groups at the sp3 carbon center, and its use. Specifically, the present invention relates to development of novel organic reactions, synthesis of functional molecules, and synthesis of new drugs by applying the novel 1,1-diboryl-1-metal substituted alkyl compounds to various molecular libraries which could not be synthesized by conventional methodologies.
专利号:US-9242925-B2 优先权日:2011-08-29 标题:Versatile and stereospecific synthesis of γ,δ-unsaturated amino acids by Wittig reaction 发明人:JUGE SYLVAIN; BAYARDON JEROME; REMOND EMMANUELLE; ONDEL-EYMIN MARIE-JOELLE 权利人:JUGE SYLVAIN; BAYARDON JEROME; REMOND EMMANUELLE; ONDEL-EYMIN MARIE-JOELLE; CENTRE NAT RECH SCIENT; UNIV BOURGOGNE 摘要:The γ,δ-unsaturated α-amino acids of general formula (I). Also, a versatile process for the stereospecific synthesis of said compounds of formula (I), involving a Wittig reaction. Further, intermediate products of general formulae (II) and (III), as shown below, which are involved in the synthesis of compounds (I). n n n n n n n n n n n n Compounds of general formula (I) may be useful as therapeutic substances, or as reagents or intermediates for fine chemistry.
专利号:WO-2018069146-A1 优先权日:2016-10-11 标题 :Method for the synthesis of pheromones 发明人:QUEVAL PIERRE; CAIJO FRÉDÉRIC; ROUEN MATHIEU; TRIPOTEAU FABIEN 权利人:DEMETA 摘要:The present invention relates to a method for synthesising pheromones and pheromone precursors, by means of the metathesis of terminal olefins including one functionalised olefin. The reaction is carried out in the presence of at least one particular catalyst, selected from among complexes of alkylidene ruthenium comprising a 1-aryl-3-cycloalkyl-imidazoline-2-ylidene ligand and mixtures thereof. The method can include an additional step of reducing the unsaturated compound formed.
专利号:US-6656446-B1 优先权日:1999-04-29 标题:Synthesis of hydrogen peroxide 发明人:BECKMAN ERIC J; HANCU DAN 权利人:UNIV PITTSBURGH 摘要:A method for synthesizing hydrogen peroxide comprises the step of: mixing an analog of a secondary alcohol that is soluble with carbon dioxide with a free radical initiator and oxygen in carbon dioxide to generate hydrogen peroxide. Another method of synthesizing hydrogen peroxide comprises the step of: mixing hydrogen, oxygen and a CO 2 -philic catalyst in carbon dioxide phase. The CO 2 -philic catalyst is soluble or miscible in carbon dioxide and is suitable to catalyze the reaction of hydrogen and oxygen to produce hydrogen peroxide. The method also comprises the step of reacting the hydrogen and oxygen to produce hydrogen peroxide.
专利号:US-2019263837-A1 优先权日:2018-02-27 标题:1,1-Diborylalkyl-1-Metal Compounds, Preparation Method Thereof, and Their Applications Toward Synthesis of 1,1-Diboronate Ester Compounds
专利号:WO-0066489-A1 优先权日:1999-04-29 标 题:Synthesis of hydrogen peroxide
参考标题:Ir(III)-Catalyzed Direct C-H Functionalization Of Arylphosphine Oxides: A Strategy For Mop-Type Ligands Synthesis 作者:Zhong Liu,Ji-Qiang Wu,Shang-Dong Yang |发布日期:2017.10.6 摘要:Efficiently Applied To Ir(III)-Catalyzed Direct C-H Functionalization Of Arylphosphine Oxides. Involving C-H Activation, Carbene Insertion, And Tautomerism, This Reaction Proceeds Under Mild Conditions, Thus Proving An Approach To The Synthesis Of Mop-Type Ligand Precursor In A Single Step. The Utility Of This Transformation Has Been Further Demonstrated In Ligand Synthesis As Well As In The Construction
合成参考文献
摘要:Stolley, R. M.; Louie, J., Science of Synthesis Knowledge Updates, (2013) 2, 39. 摘要:Stolley, R. M.; Louie, J., Science of Synthesis Knowledge Updates, (2013) 2, 20. 摘要:Delvos, L. B.; Oestreich, M., Science of Synthesis Knowledge Updates, (2017) 1, 91. 摘要:Okamoto, K.; Ohe, K., Science of Synthesis Knowledge Updates, (2020) 1, 62. 摘要:Lubell, W. D.; St-Cyr, D. J.; Dufour-Gallant, J.; Hopewell, R.; Boutard, N.; Kassem, T.; Dörr, A.; Zelli, R., Science of Synthesis Knowledge Updates, (2013) 1, 309.